fuser component composition
A technology of fuser and components, which is applied in the direction of instruments, electric recording technology using charge patterns, coatings, etc., and can solve the problem of expensive process steps of the release layer
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[0051] Exemplary diamines selected for use in the preparation of polyamic acids include 4,4'-bis-(m-aminophenoxy)-biphenyl, 4,4'-bis-(m-aminophenoxy) -diphenylsulfide, 4,4'-bis-(m-aminophenoxy)-diphenylsulfone, 4,4'-bis-(p-aminophenoxy)-benzophenone, 4,4 '-bis-(p-aminophenoxy)-diphenylsulfide, 4,4'-bis-(p-aminophenoxy)-diphenylsulfone, 4,4'-diamino-azobenzene, 4,4'-diaminobiphenyl, 4,4'-diaminodiphenylsulfone, 4,4'-diamino-p-terphenyl, 1,3-bis-(γ-aminopropyl)-tetramethyl yl-disiloxane, 1,6-diaminohexane, 4,4'-diaminodiphenylmethane, 3,3'-diaminodiphenylmethane, 1,3-diaminobenzene, 4, 4'-diaminodiphenyl ether, 2,4'-diaminodiphenyl ether, 3,3'-diaminodiphenyl ether, 3,4'-diaminodiphenyl ether, 1,4-diaminobenzene, 4,4'-diamino-2,2',3,3',5,5',6,6'-octafluoro-biphenyl, 4,4'-diamino-2,2',3,3 ',5,5',6,6'-octafluorodiphenyl ether, bis[4-(3-aminophenoxy)-phenyl]sulfide, bis[4-(3-aminophenoxy)benzene base]sulfone, bis[4-(3-aminophenoxy)phenyl]ketone, 4,4'-bis(3-aminophenoxy)biphenyl...
example I
[0101] A polyamic acid comprising biphenyltetracarboxylic dianhydride / phenylenediamine in a weight ratio of 99.95 to 0.05 (the polyamic acid Phosphate esters of polyimides and alcohols from Kaneka Corporation) ZE -UN(C 8 h 17 -O-P(=O)(OH) 2 and C 10 h 21 -O-P(=O)(OH) 2 mixture, obtained from Stepan Company) composition. After precuring at a temperature of about 125°C to about 250°C followed by final curing at a temperature of about 250°C to about 370°C, polyamic acid from Kaneka Corporation is converted to biphenyltetracarboxylic dianhydride / benzenedi Amine polyimide.
[0102] The composition obtained above was liquid coated on a stainless steel rigid cylindrical mandrel substrate, then pre-cured at a temperature of about 210°C and fully cured at a temperature of 320°C for 60 minutes. The resulting polyimide / alcohol phosphate ester fuser tape self-released from the stainless steel substrate in about 5 seconds, resulting in a 60 micron thick smooth polyimide / alcohol ph...
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