A kind of low-odor mineral reinforced polypropylene composite material and preparation method thereof

A composite material and polypropylene technology, applied in the field of low-odor mineral-reinforced polypropylene composite materials and their preparation, can solve the problems of poor VOC removal and difficult compatibility of polypropylene resins, so as to reduce odor and VOC, reduce odor and Dispersive, evenly dispersed effect

Active Publication Date: 2016-08-17
上海日之升科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent CN101255252B discloses a low-emission special material for automotive interiors, using low-molecular-weight carbonates as organic repellants, but it is difficult to be compatible with polypropylene resin, and VOC removal is poor

Method used

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  • A kind of low-odor mineral reinforced polypropylene composite material and preparation method thereof
  • A kind of low-odor mineral reinforced polypropylene composite material and preparation method thereof
  • A kind of low-odor mineral reinforced polypropylene composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0026] This example relates to a low-odor mineral-reinforced polypropylene composite material, the components of which are shown in Table 1. The preparation method of the low-odor mineral reinforced polypropylene composite material of the present embodiment has the following steps:

[0027] 1. Prepare materials according to the components and weight percentages shown in Table 1; wherein, the deodorizing liquid is a mixture of hexamethyldisiloxane and calcium nitrate aqueous solution with a mass ratio of 3:1; the filling mineral is a mass ratio of 1:1 wollastonite and calcium carbonate;

[0028] 2. Put the raw materials other than the deodorant liquid into the high mixer and mix for 2-5 minutes, then discharge; then put the mixed raw materials into the main feeding port of the twin-screw extruder, and feed the deodorant liquid from the side through the centrifugal pump The feed port is metered into, vacuumed, and melted and extruded by a twin-screw machine to produce low-odor ...

Embodiment 2

[0030] This example relates to a low-odor mineral-reinforced polypropylene composite material, the components of which are shown in Table 1. The preparation method of the low-odor mineral reinforced polypropylene composite material of the present embodiment has the following steps:

[0031] 1. Prepare materials according to the components and weight percentage content shown in Table 1; wherein, the deodorizing liquid is a mixture of triethylsilane and calcium molybdate aqueous solution with a mass ratio of 4:1; the filling mineral is barium sulfate;

[0032] 2. Put the raw materials other than the deodorant liquid into the high mixer and mix for 2-5 minutes, then discharge; then put the mixed raw materials into the main feeding port of the twin-screw extruder, and feed the deodorant liquid from the side through the centrifugal pump The feed port is metered into, vacuumed, and melted and extruded by a twin-screw machine to produce low-odor mineral-reinforced polypropylene compo...

Embodiment 3

[0034] This example relates to a low-odor mineral-reinforced polypropylene composite material, the components of which are shown in Table 1. The preparation method of the low-odor mineral reinforced polypropylene composite material of the present embodiment has the following steps:

[0035] 1. Prepare materials according to the components and weight percentages shown in Table 1; wherein, the deodorizing liquid is a mixture of triethylsilane and sodium nitrate aqueous solution with a mass ratio of 5:1; the filling mineral is a mass ratio of 1:1 : 1 talcum powder, wollastonite and glass microspheres;

[0036] 2. Put the raw materials other than the deodorant liquid into the high mixer and mix for 2-5 minutes, then discharge; then put the mixed raw materials into the main feeding port of the twin-screw extruder, and feed the deodorant liquid from the side through the centrifugal pump The feed port is metered into, vacuumed, and melted and extruded by a twin-screw machine to prod...

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Abstract

The invention discloses low-odor mineral reinforced polypropylene composite material and a preparation method thereof. The material is prepared from the following components in percentage by weight: 54-88.5% of polypropylene, 10-40% of filling minerals, 0.5-5% of an odor removing liquid, 0.2-1% of an antioxidant and 0.2-1% of a lubricant. The preparation method comprises the following steps: mixing the raw materials except the odor removing liquid in a high-speed mixer and discharging; putting the mixed raw materials into a main feeding opening of a twin-screw extruder; metering and inputting the odor removing liquid from a side feeding opening by virtue of a centrifugal pump; vacuumizing; carrying out melt extrusion and prilling by virtue of the twin-screw extruder to prepare the low-odor mineral reinforced polypropylene composite material. Compared with the prior art, the low-odor mineral reinforced polypropylene composite material prepared by the reparation method provided by the invention is excellent in mechanical property, low in VOC and environment-friendly and can be widely used in the fields of automobiles, household appliances, sports articles and the like.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a low-odor mineral reinforced polypropylene composite material and a preparation method thereof. Background technique [0002] Mineral reinforced polypropylene is widely used in automobiles, home appliances and other industries due to its excellent mechanical properties, good dimensional stability, high heat resistance, and low cost. However, mineral reinforced polypropylene materials will release some toxic and harmful gases, which not only cause harm to the human body, but also affect the quality of the product. Moreover, with the enhancement of people's awareness of environmental protection and health, the preparation of low-odor mineral-reinforced polypropylene has become a development trend of mineral-reinforced polypropylene. [0003] The odor of mineral-enhanced polypropylene is mainly composed of the following aspects: 1) The odor of the raw material itself, including th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L23/14C08K13/02C08K13/04C08K3/34C08K3/26C08K7/20C08K3/30C08K5/098
CPCC08K3/24C08K3/26C08K3/28C08K3/30C08K3/34C08K5/098C08K5/1345C08K5/526C08K5/5419C08K7/20C08K13/02C08K2003/265C08K2003/287C08K2003/3045C08K2201/003C08K2201/014C08L23/14
Inventor 裘浩成娄小安路海冰沈叶龙
Owner 上海日之升科技有限公司
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