Plasma etching method and plasma processing device
A plasma and etching treatment technology, which is applied in the fields of plasma, semiconductor/solid-state device manufacturing, discharge tubes, etc., and can solve the problems of inability to deepen the etching depth and improve the etching selectivity ratio.
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Embodiment
[0060] As an example, after performing the first etching treatment and the second etching treatment on the wafer W, SiCl 4 / He mixed gas or SiCl 4 / He / O 2 The mask 5 was coated with a mixed gas, and the third etching process was performed using the coated mask 5 . At that time, a confirmatory test was carried out regarding the influence of the conditions of the coating process and the time of the third etching on the shape of the hole 200 to be formed. At this time, the diameter of the wafer W is 300 mm, the film thickness of the polysilicon used as the mask 5 is 1200 nm, and the film thickness of the silicon nitride layer 4 is 300 nm. Furthermore, the film thickness of the silicon oxide film layer 3 formed on the wafer W is 3500 nm.
[0061] For the conditions of the plasma treatment during the coating treatment, when using SiCl 4 / He mixed gas, SiCl 4 The flow rate of He is 20 sccm, and the flow rate of He is 100 sccm. In addition, in the SiCl 4 / He / O 2 When the mixe...
Embodiment 5
[0069] Example 5 shows the use of SiCl in the coating process 4 / He mixed gas was applied for 5 seconds, and then SiCl was used 4 / He / O 2 The result of the case where the mixed gas was further subjected to a coating process for 20 seconds. In this case as well, it was confirmed that the aspect ratio was greatly improved compared with the comparative example. In addition, in Example 6, the selection ratio was significantly improved as compared with the comparative example. This is because, SiCl 4 / He / O 2 The formed Si coating film containing O (oxygen) and SiCl 4 The Si coating film formed by / He effectively suppresses the etching of the sidewall.
Embodiment 6
[0070] Example 6 shows the results of the case where the temperature of the wafer W was 200° C. compared to the temperature of the wafer W of Example 1, which was 40° C., but was completely the same as that of Example 1. Also in this case, it was confirmed that the aspect ratio was greatly improved compared with the comparative example. This is because the portion where dimension 2 is narrowed is relatively widened at high temperature, thus being able to etch into a deeper portion of hole 200 . The reason why the dimension 2 becomes wider is that the chemical reaction of radicals is promoted when the temperature of the wafer W is high.
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