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A kind of nitrated coal tar alcohol-containing fuel and preparation method thereof

A technology of coal tar and nitration, which is applied in the field of fuel oil, can solve problems such as smoke emission, complex chemical composition, and increased cost of coal tar treatment, and achieve the effects of less dust emission, simple preparation process, and low production cost

Active Publication Date: 2016-03-23
GUIZHOU QIANSHENG NEW ENERGY IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

That is, the method of hydrogenation reduction is used to reduce the large molecule of coal tar into low molecular oil, thereby improving the quality of coal tar to a large extent, increasing the combustion calorific value of coal tar, and enabling coal tar to be burned Full combustion reduces the waste of energy; however, due to the harsh conditions of the hydrogenation process and the huge investment in equipment, it is difficult to process a large amount of tar stored in the country; it also makes the processing cost of coal tar relatively high, so most of them directly use coal tar. The primary processing products of tar and coal tar series products are used for combustion applications, and this kind of direct combustion application is difficult to achieve complete combustion, resulting in a large amount of energy waste; , the water body is seriously polluted; and in the process of direct combustion, a large amount of smoke and dust will be discharged, which will cause the heat transfer intensity of the water-cooled wall tube in the combustion furnace and the carbon on the outer surface of the economizer to decrease
In the current prior art, in addition to hydrogenation reduction, there is also an oxygenation method, but there are also relatively harsh conditions for the oxygenation treatment method, mainly using nitration treatment and grafting nitro in coal tar. Among the complex compounds in the process, this process needs to know whether the components in the coal tar can undergo grafting reaction with the nitro group, and then needs to accurately control the technical parameters of the chemical reaction and the time of adding the raw materials, which further improves the control of the coal tar. The difficulty of processing increases the cost of coal tar processing; at the same time, the degree of complete combustion of the obtained fuel is still not high, which will still cause a large amount of smoke and dust emissions, resulting in the loss and waste of raw material energy

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A nitrated coal tar alcohol-containing fuel, the raw material components of the fuel are 360 ​​kg of raw material oil, 3 kg of catalyst, 5 kg of nitric acid solution, 300 kg of alcohol and 8 kg of urea in parts by weight.

[0029] The raw material oil is coal tar.

[0030] Described nitric acid solution is the industrial nitric acid that mass percent composition is 60%; Described alcohol is ethanol;

[0031] Described ethanol is the industrial ethanol that mass percentage composition is 95%;

[0032] The catalyst is magnesium nitrate hexahydrate.

[0033] The preparation method of the nitrated coal tar alcohol-containing fuel is to take raw materials according to the ratio, pump the raw material oil into the reaction kettle, adjust the temperature to -5°C, and add a catalyst therein, wherein the catalyst addition time is 50min. And divide it into 3 additions, turn on the mixer again, adjust the stirring speed of the mixer to be 80r / min, after stirring for 10min, add n...

Embodiment 2

[0036] A nitrated coal tar alcohol-containing fuel, the raw material components of the fuel are 515 kg of raw material oil, 8 kg of catalyst, 60 kg of nitric acid solution, 400 kg of sodium hydroxide solution, and 300 kg of alcohol in parts by weight.

[0037] The raw material oil is the washing oil obtained by primary processing of coal tar as raw material.

[0038] Described nitric acid solution is the industrial nitric acid that mass percent composition is 95%; Described alcohol is methyl alcohol;

[0039] The methanol is industrial methanol with a mass percentage of 95%.

[0040] The catalyst is sodium nitrate.

[0041]The preparation method of the nitrated coal tar alcohol-containing fuel is to take the raw material according to the proportion, pump the raw material oil into the reaction kettle, adjust the temperature to 19°C, and add the catalyst to it, wherein the catalyst addition time is 60min. Divide it into 3 additions, then turn on the mixer, adjust the stirring ...

Embodiment 3

[0044] A nitrated coal tar alcohol-containing fuel, the raw material components of the fuel, in parts by weight, are 515 kg of raw material oil, 8 kg of catalyst, 25 kg of nitric acid solution, 15 kg of sodium hydroxide solution, 255 kg of alcohol, and 5 kg of urea.

[0045] The raw material oil is the anthracene oil which is initially processed from coal tar.

[0046] Described nitric acid solution is the industrial nitric acid that mass percent composition is 70%; Described alcohol is ethanol;

[0047] Described ethanol is the fuel grade ethanol that mass percentage composition is 99.9%;

[0048] Described catalyst is sodium chlorate.

[0049] The preparation method of the nitrated coal tar alcohol-containing fuel is to take the raw material according to the proportion, pump the raw material oil into the reaction kettle, adjust the temperature to 10°C, and add the catalyst to it, wherein the catalyst addition time is 55 minutes to complete the addition, and Divide it into ...

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PUM

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Abstract

The invention relates to the technical field of fuel oil, and in particular relates to a nitrated coal tar alcohol-containing fuel and a preparation method thereof. By proportioning raw oil, a catalyst, a nitric acid solution, an alcohol and urea, combining process parameters in process steps and controlling the adding sequence and time of various raw materials, the performance of raw oil can be accurately modified, then the kinematic viscosity of oil, the water mass percentage and the content of alcohol substances are improved, and the performance of the raw oil is further improved; and moreover, compared with pure alcohol and the conventional alcohol-containing fuels, the nitrated coal tar alcohol-containing fuel provided by the invention has superior kinematic viscosity, is lower in water content and less in smoke dust discharge after burning, and can be completely burnt to a greater extent, the combustion value of the fuel is improved, and the consumption of energy sources is reduced.

Description

technical field [0001] The invention relates to the technical field of fuel oil, in particular to a nitrated coal tar alcohol-containing fuel and a preparation method thereof. Background technique [0002] Coal tar is divided into two categories: high temperature tar and medium and low temperature tar. Those skilled in the art know that coal tar and its pre-processed series products have a theoretical combustion calorific value that is 10-20% lower than that of gasoline and diesel oil. In practical applications, due to the poor combustion conditions, the actual calorific value released is greatly reduced, and some people have made research on this. That is, the method of hydrogenation reduction is used to reduce the large molecule of coal tar into low molecular oil, thereby improving the quality of coal tar to a large extent, increasing the combustion calorific value of coal tar, and enabling coal tar to be burned Full combustion reduces the waste of energy; however, due t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L1/04C10L1/12C10L1/222C10L1/23
Inventor 王根俊徐崇贵蒙亮晓周厚宇钱蕾王小侠
Owner GUIZHOU QIANSHENG NEW ENERGY IND
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