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A modified halogen-free flame-retardant ABS composition and its preparation method

A technology of composition and ABS resin, which is applied in the field of modified halogen-free flame-retardant ABS composition and its preparation, can solve the problems of decreased mechanical properties of materials, low efficiency of halogen-free flame retardants, large addition amount, etc., and achieves improved chemical performance. The degree of reaction, the effect of improving mechanical properties and flame retardancy, and improving compatibility

Active Publication Date: 2018-05-15
GUANGDONG IND TECHN COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although halogen-free flame retardant ABS has been a research hotspot in the world for many years, due to the low efficiency of halogen-free flame retardants, large additions, and poor compatibility with resins, the mechanical properties of materials are severely reduced, and it has always been a halogen-free flame retardant. Major barriers to widespread market adoption

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] In this embodiment, a modified halogen-free flame-retardant ABS composition, its components and the corresponding parts by weight of each component are as follows:

[0046] ABS resin: 50 parts; flame retardant: 48 parts; compatibilizer: 2 parts (see Table 1 for details).

[0047] Among them, the ABS resin is a terpolymer of acrylonitrile, butadiene and styrene, which is prepared by bulk polymerization; the flame retardant is a prefabricated EVA-wrapped IFRC modified flame retardant; the compatibilizer is maleic anhydride branches.

[0048] The components and the corresponding parts by weight in the EVA-wrapped IFRC modified flame retardant are as follows:

[0049] EVA emulsion: 50 parts; phosphorus flame retardant: 50 parts; coupling agent: 5 parts; dispersant: 1 part; antioxidant: 1 part (see Table 2 for details).

[0050] After preparing the sample of the modified halogen-free flame-retardant ABS composition through the above formula, the material test was carried o...

Embodiment 2

[0052] In this embodiment, a modified halogen-free flame-retardant ABS composition, its components and the corresponding parts by weight of each component are as follows:

[0053] ABS resin: 50 parts; flame retardant: 48 parts; compatibilizer: 2 parts; crosslinking agent: 0.3 parts (see Table 1 for details).

[0054] Among them, the ABS resin is a terpolymer of acrylonitrile, butadiene and styrene, which is prepared by bulk polymerization; the flame retardant is a prefabricated EVA-wrapped IFRC modified flame retardant; the compatibilizer is maleic anhydride Graft; cross-linking agent is dicumyl peroxide (DCP).

[0055] The components and the corresponding parts by weight in the EVA-wrapped IFRC modified flame retardant are as follows:

[0056] EVA emulsion: 50 parts; phosphorus flame retardant: 50 parts; coupling agent: 5 parts; dispersant: 1 part; antioxidant: 1 part (see Table 2 for details).

[0057] After preparing the sample of the modified halogen-free flame-retardant...

Embodiment 3

[0059] In this embodiment, a modified halogen-free flame-retardant ABS composition, its components and the corresponding parts by weight of each component are as follows:

[0060] ABS resin: 50 parts; flame retardant: 48 parts; compatibilizer: 2 parts; crosslinking agent: 0.6 parts (see Table 1 for details).

[0061] Among them, the ABS resin is a terpolymer of acrylonitrile, butadiene and styrene, which is prepared by bulk polymerization; the flame retardant is a prefabricated EVA-wrapped IFRC modified flame retardant; the compatibilizer is maleic anhydride Graft; cross-linking agent is dicumyl peroxide (DCP).

[0062] The components and the corresponding parts by weight in the EVA-wrapped IFRC modified flame retardant are as follows:

[0063] EVA emulsion: 50 parts; phosphorus flame retardant: 50 parts; coupling agent: 5 parts; dispersant: 1 part; antioxidant: 1 part (see Table 2 for details).

[0064] After the sample of the modified halogen-free flame-retardant ABS composi...

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Abstract

The invention discloses a modified halogen-free flame retardant ABS composition which comprises the following components in parts by weight: 50-60 parts of ABS resin, 38-48 parts of flame retardant, 1-3 parts of compatilizer and 0-1 part of crosslinking agent. By adopting the ABS composition, the compatibility of the ABS halogen-free flame retardant material is effectively improved, the mechanical properties and flame retardance of the material are enhanced, and the ABS halogen-free flame retardant material can better adapt to the industrialization and marketization and is particularly applicable to the field of processing and building materials of automobile parts.

Description

technical field [0001] The invention relates to the technical field of preparation of flame-retardant polymer materials, in particular to a modified halogen-free flame-retardant ABS composition and a preparation method thereof. Background technique [0002] ABS plastic has been widely used in the electrical, electronic and automotive industries due to its excellent chemical resistance, mechanical properties and processing properties. However, due to the flammability of ABS, its further and wider application is limited. [0003] In the last ten years, halogenated flame retardants have been successfully used to prepare flame-retardant ABS plastics, but halogenated flame-retardant materials themselves will release toxic hydrogen halide gas during combustion, which is no less harmful than Fire itself is a threat to humans. Therefore, the EU RoHS environmental protection directive issued in 2003 listed a variety of halogenated flame retardants on the list of restricted hazardou...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L55/02C08K9/10C08K3/32C08K5/053B29C47/92B29C48/92
Inventor 赵松喻慧文徐百平孔萍庄文柳杨芳王玫瑰
Owner GUANGDONG IND TECHN COLLEGE
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