A kind of coarse denier porous polyester fiber and its preparation method
A porous polyester and fiber technology, applied in the direction of fiber type, fiber treatment, single-component polyester rayon, etc., can solve the problems of hairiness, short heating time, easy broken filaments, etc., to reduce damage and reduce the surface The effect of improving tension and smoothness
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Embodiment 1
[0053] A method for preparing coarse-denier porous polyester fibers. First, an oil-on oil is prepared. The specific preparation steps are: blending the starter butanol and strong alkali potassium hydroxide, then raising the temperature to 105°C, and then adding and mixing Homogeneous ethylene oxide, [(1,1,2,2-tetrafluoroethoxy)methyl] ethylene oxide and propylene oxide, the amount of butanol is ethylene oxide, [(1,1 , 2,2-tetrafluoroethoxy) methyl] 1‰ of the total mass of ethylene oxide and propylene oxide, the amount of strong base potassium hydroxide is ethylene oxide, [(1,1,2,2 -1‰ of the total mass of -tetrafluoroethoxy)methyl]oxirane and propylene oxide, ethylene oxide, [(1,1,2,2-tetrafluoroethoxy)methyl]epoxide The molar ratio of ethane and propylene oxide is 10:1:20, the polymerization reaction is carried out under the protective atmosphere of nitrogen atmosphere, the reaction pressure is 0.4MPa, and after the relative molecular weight is 1000, the fluorine-containing p...
Embodiment 2
[0067] A method for preparing coarse-denier porous polyester fibers. First, an oil-on oil is prepared. The specific steps are: blending the initiator butanol and strong alkali sodium hydroxide, then raising the temperature to 125° C., and then adding the well-mixed Ethylene oxide, [(1,1,2,2-tetrafluoroethoxy)methyl] ethylene oxide and propylene oxide, the amount of butanol is ethylene oxide, [(1,1,2 , 2-tetrafluoroethoxy) methyl] 5‰ of the total mass of ethylene oxide and propylene oxide, the amount of strong alkali sodium hydroxide is ethylene oxide, [(1,1,2,2-tetra 5‰ of the total mass of fluoroethoxy)methyl]oxirane and propylene oxide, ethylene oxide, [(1,1,2,2-tetrafluoroethoxy)methyl]oxirane The molar ratio of propylene oxide and propylene oxide is 20:3:30, and the polymerization reaction is carried out under the protective atmosphere of an inert gas atmosphere, the reaction pressure is 0.5MPa, and after reaching a relative molecular weight of 4000, neutralization, adsorp...
Embodiment 3
[0080] A method for preparing coarse-denier porous polyester fibers. First, an oil-on oil is prepared. The specific steps are: blending the initiator butanol and strong alkali sodium hydroxide, then raising the temperature to 115°C, and then adding the well-mixed Ethylene oxide, [(1,1,2,2-tetrafluoroethoxy)methyl] ethylene oxide and propylene oxide, the amount of butanol is ethylene oxide, [(1,1,2 , 2-tetrafluoroethoxy) methyl] 2‰ of the total mass of ethylene oxide and propylene oxide, the amount of strong alkali sodium hydroxide is ethylene oxide, [(1,1,2,2-tetra 1.5‰ of the total mass of fluoroethoxy)methyl]oxirane and propylene oxide, ethylene oxide, [(1,1,2,2-tetrafluoroethoxy)methyl]oxirane The molar ratio of propylene oxide and propylene oxide is 12:1:30, and the protective atmosphere is an inert gas atmosphere to carry out polymerization reaction, the reaction pressure is 0.8MPa, and after reaching a relative molecular weight of 3000, neutralization, adsorption, vacuum...
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