Herbicide compound specially used for removing alternanthera philoxeroides and weeding microemulsion
A technology of herbicides and complexes, applied in the field of pesticides, can solve the problems of difficult degradation, long residual period, short residual period, etc.
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[0034] The preparation method of described octylphenol polyoxyethylene ether sulfonate and heavy alkylbenzene sulfonate mixture comprises:
[0035] The first step, the chlorination of octylphenol polyoxyethylene ether;
[0036] Second step, sulfonation of octylphenol polyoxyethylene ether after chlorination
[0037] In the third step, mix octylphenol polyoxyethylene ether sulfonate and heavy alkylbenzene sulfonate according to (2.5-4): (1-1.5).
[0038] The first step is further specifically adding octylphenol polyoxyethylene ether (OP-4) and pyridine into the reaction vessel at a molar ratio of 1:1, adding thionyl chloride dropwise under constant temperature water bath conditions, chlorine The molar ratio of sulfoxide to octylphenol polyoxyethylene ether was 1.5:1, stirred and reacted at 70°C to 80°C for 2 hours, and chlorooctylphenol polyoxyethylene ether was synthesized.
[0039] The second step is further specifically adding chlorooctylphenol polyoxyethylene ether to wat...
Embodiment 1
[0049] Embodiment 1 octylphenol polyoxyethylene ether sulfonate and heavy alkylbenzene sulfonate mixture
[0050] Mix 10 mol of octylphenol polyoxyethylene ether (OP-4) and 10 mol of pyridine into the reaction vessel, add 15 mol of thionyl chloride dropwise in a constant temperature water bath, stir and react at 80°C for 2 hours, and synthesize chlorooctyl Base phenol polyoxyethylene ether, get the obtained 7.5mol chlorooctylphenol polyoxyethylene ether and join in water, the mass ratio of chlorooctylphenol polyoxyethylene ether and water is 1:1.5, then add 5mol sulfonating agent Sodium sulfite (Na 2 SO 3 ), placed in a high-pressure reactor, and reacted at 150°C for 8 hours under vigorous stirring to obtain a light yellow viscous substance. The crude product was dissolved in a mixture of isopropanol and water with a volume ratio of 2:1, and then extracted with petroleum ether , to remove unreacted raw materials and other oil-soluble impurities, separate the lower layer, dis...
Embodiment 2
[0051] Embodiment 2 Microemulsion 1
[0052] With quinclorac, glyphosate isopropylamine salt 30g, imazethapyr 45g, add dimethyl tetrachloride 10g, surfactant 15g prepared in Example 1, emulsifier diisooctyl sulfonate sodium 250g 150g of cosolvent ethanol, 40g of antifreeze glycerin and 30g of synergist butyristerin were put into the reaction kettle, stirred evenly and completely dissolved, slowly added 800g of water, and continued to mix and stir for 2h to obtain a microemulsion.
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