A carbon fuel cell coal-based fuel combined processing device and processing method thereof

Abstract

The invention discloses a combined processing device of a coal-based fuel of a carbon fuel cell and a processing method thereof. The combined processing device disclosed by the invention comprises a coal matrix storage device, a physical cleaning device, a chemical desulphurization device, an electrochemical desulphurization device, a cell fuel collecting device, a coal slurry processing device, a sulphuric acid recovery device and a sulfide recovery device. A PCE combined processing process is provided in the invention; the micro-structure of coal is improved, so that anodic electrochemical reactions are convenient to generate; more than 99% of ash components and volatile components in a coal matrix can be effectively removed; more than 90-95% of total sulphur is removed; requirements of the fuel cell to the carbon purity can be satisfied; the complete set of coal-based fuel cell fuel device is provided; reference of a raw material processing device is provided for future industrial popularization of the fuel cell; and the PCE combined processing process is simple in principle and low in equipment cost and has important significances for solving sulphur poisoning and sulphur pollution of the carbon fuel cell and realizing industrial popularization of the fuel cell.

Description

technical field [0001] The invention relates to the field of direct carbon fuel cell preparation, in particular to a carbon fuel cell coal-based fuel joint processing device and a processing method thereof. Background technique [0002] Fuel cells (fuel cells, FCs) are the fourth-generation power generation technology after thermal power, hydropower and nuclear power. It is considered to be the most promising efficient and clean power generation technology in the 21st century. As a kind of fuel cell, direct carbon fuel cell DCFC can use graphite, activated carbon, coal coke, biomass coke, etc. as fuel. Carbon (carbon derivatives) and oxygen undergo electrochemical reactions to generate electricity directly without gasification. It has the characteristics of high energy conversion efficiency, cleanliness and wide fuel adaptability. The operating temperature of direct carbon fuel cells is between 400 and 1000°C. [0003] Direct Carbon Fuel Cell DCFC uses carbon as fuel and ...

AI Technical Summary

Problems solved by technology

However, the first step is more complicated, which increases the cost of the entire carbon fuel cell itself. The second is that the electrochemical oxidation process occurs in the electrolyte, which easily affects the entire chemical reaction process and destroys the activity of the cathode and anode.

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