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A kind of water-based stripping type magnesium aluminum alloy casting coating and preparation method thereof

A magnesium-aluminum alloy and casting coating technology, which is applied in the direction of coating, etc., can solve the problem that the flexibility and adhesion of the coating do not meet the ideal requirements, the water resistance and solvent resistance of the film layer are not ideal, and the heat resistance and acid resistance of the film layer , poor alkali resistance and other problems, to achieve the effect of high thermochemical stability, high refractoriness, and clear outline

Inactive Publication Date: 2018-05-11
临泽县鼎丰源凹土高新技术开发有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It has good peeling performance, can be peeled off in a large area, and the coating film can be further processed, but the heat resistance, acid resistance and alkali resistance of the film layer are poor, and can only withstand the temperature of 80 ° C, and the low solubility of Acid and alkali corrosion, patent CN201010592499 introduces a water-based coating composition that can peel off the coating protective film, including synthetic resin emulsion, adhesion modifier, pigment and filler, defoamer, dispersant, thickener, preservative, Ethanol and deionized water, but the water resistance and solvent resistance of the film layer prepared by the composition are not ideal, and the flexibility and adhesion of the coating prepared by the above coating composition do not meet the ideal requirements, so it is not suitable for further processing
The coating for magnesium alloy metal mold casting prepared by patent CN103143673 B can effectively solve the problem that magnesium alloy is easy to oxidize and burn, but the coating is suitable for metal mold tools and has higher requirements

Method used

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  • A kind of water-based stripping type magnesium aluminum alloy casting coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1: Preparation of water-based peeling-type magnesium-aluminum alloy casting coating

[0032] Including the following steps:

[0033] (1) Preparation steps of modified attapulgite powder:

[0034] A. Weigh the attapulgite clay with a fineness of 200-400 mesh, put it into distilled water, add hydrochloric acid, treat it at 90°C for 2 hours, and stir for 3 hours to prepare a suspension for later use; wherein, each gram of attapulgite Add 9ml distilled water in the stone clay; Add 0.8ml hydrochloric acid in every gram of attapulgite clay, and the concentration of hydrochloric acid is 1mol / L;

[0035] B. Add composite active agent to the suspension prepared in step A, add dropwise NaOH solution to adjust the pH value of the suspension to 7, then stir for 3 hours to prepare the suspension, and set aside; wherein, add 0.08ml per gram of attapulgite clay Composite active agent; composite active agent is that the volume ratio of epoxy polysiloxane and alkylphenol polyo...

Embodiment 2

[0041] Example 2: Preparation of water-based stripping magnesium-aluminum alloy casting coating

[0042] Including the following steps:

[0043] (1) Preparation steps of modified attapulgite powder:

[0044] See Example 1.

[0045] (2) Preparation steps of water-based peeling type magnesium-aluminum alloy casting coating:

[0046] A. get the modified attapulgite powder 25g prepared by step (1), lithium-based bentonite 5g, nano-zirconia powder 10g, graphite powder 6g, chromite powder 5g and ball mill 3h with a planetary mill at a speed of 188 rev / min , sieved through a 200-mesh fine sieve to obtain the mixture;

[0047] B. Mix the above mixture with 45g of water, add 4g of dispersant, put it into a ball mill and mill it at a speed of 188 rpm for 2h, then add 15g of binder and 0.5g of defoamer, put it into the ball mill again at 188 rpm Min speed ball milling for 3 hours to obtain a water-based peeling magnesium-aluminum alloy casting coating, wherein the dispersant is ammoniu...

Embodiment 3

[0048] Example 3: Preparation of water-based peeling-type magnesium-aluminum alloy casting coating

[0049] Including the following steps:

[0050] (1) Preparation steps of modified attapulgite powder:

[0051] A. Weigh the attapulgite clay with a fineness of 200 mesh and put it into distilled water, add hydrochloric acid and treat it at 80°C for 1 hour, and then stir for 2 hours to prepare a suspension for later use; wherein, each gram of attapulgite clay Add 8ml distilled water in; Add 0.5ml hydrochloric acid in every gram of attapulgite clay, the concentration of hydrochloric acid is 1mol / L;

[0052] B. Add composite active agent to the suspension prepared in step A, add NaOH solution dropwise to adjust the pH value of the suspension to 6, then stir for 2 hours to prepare the suspension, and set aside; wherein, add 0.05ml per gram of attapulgite clay Composite active agent; composite active agent is that the volume ratio of epoxy polysiloxane and alkylphenol polyoxyethyle...

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Abstract

The invention discloses a water-based strippable magnesium aluminum alloy casting coating and a preparation method thereof. The coating is prepared from, by weight, 2-5 parts of lithium base bentonite, 25-30 parts of modified attapulgite powder, 5-10 parts of nanometer zirconia powder, 5-8 parts of graphite powder, 3-5 parts of chromite powder, 10-15 parts of a binder, 2-4 parts of a dispersant, 40-45 parts of deionized water and 0.1-0.5 parts of an antifoaming agent. The coating is coated on the surface of a sand molding die, has good wettability, brushability, permeability and strength, and has good stability, heat insulation property and slag absorbing capability in the magnesium aluminum alloy liquid casting process, a coating layer adhered to the surface of the magnesium aluminum alloy has good strippability when the coating layer is cold, and obtained magnesium aluminum alloy castings have clear contours and bright and clean surfaces.

Description

technical field [0001] The invention belongs to the technical field of paint preparation, and relates to a water-based stripping type magnesium-aluminum alloy casting paint and a preparation method thereof. Background technique [0002] As a lighter metal structure material (density 1.65-1.73g / cm3), magnesium-aluminum alloy has high specific strength, good rigidity, excellent impact resistance and shock absorption performance, and is widely used in aerospace and defense industries, automobiles and electronics industries, etc. fields are widely used. [0003] At present, 90% of magnesium-aluminum alloy castings are formed by die casting, and a few of them are formed by gravity sand casting. Due to the large investment, high technical requirements, poor market adaptability and inability to be used as high-strength force-bearing parts, die-casting restricts its vigorous development; while the traditional sand casting has coarse particles, the surface quality of the obtained ca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D1/00C09D7/65C09D5/20
CPCC09D1/00C09D5/20C09D7/61C09D7/65
Inventor 姚义俊万韬隃刘斌温晓霞刘雯雯杨佳伟张彬张俊阳
Owner 临泽县鼎丰源凹土高新技术开发有限公司