Decorative sheet, decorative resin molded article, and manufacturing method for decorative resin molded article
A technology of resin molding and decorative sheets, which is applied in the direction of decorations, chemical instruments and methods, and synthetic resin layered products, can solve the problems of easy damage to the three-dimensional effect of decorative sheets, and achieve high design, high scratch resistance, High formability effect
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Embodiment 1~6 and comparative example 1~3
[0160] (production of decorative sheets)
[0161] On an ABS resin film (thickness 400 μm) as a base layer, a pattern layer (thickness 5 μm) was formed by gravure printing using an ink containing vinyl chloride-vinyl acetate-acrylic copolymer resin. The pattern of the pattern layer is a wood grain pattern. Next, using a resin composition having a composition described in Table 1, a first protective layer (thickness: 3 μm) was formed on the pattern layer by gravure printing. Next, using the resin composition having the composition shown in Table 1, on the first protective layer, the position of the duct part corresponding to the wood grain pattern of the pattern layer is a non-formed part, and the second pipe part matching the wood grain pattern is placed on the first protective layer. A protective layer (thickness: 3 μm) was formed in a pattern. Next, electron beams were irradiated from the second protective layer side (acceleration voltage 165kV, irradiation dose 50kGy (5Mra...
Embodiment 7~12
[0163] (production of decorative sheets)
[0164] On an ABS resin film (thickness 400 μm) as a base layer, a pattern layer (thickness 5 μm) was formed by gravure printing using an ink containing vinyl chloride-vinyl acetate-acrylic copolymer resin. The pattern of the pattern layer is a wood grain pattern. Next, using a resin composition having a composition described in Table 2, a third protective layer (thickness: 3 μm) was formed on the pattern layer by gravure printing. Next, using a resin composition having a composition described in Table 2, a first protective layer (thickness: 3 μm) was formed on the third protective layer by gravure printing. Next, on the first protective layer, using a resin composition having the composition shown in Table 2, the position of the duct part corresponding to the wood grain pattern of the pattern layer is a non-formed part, and the second layer matching the wood grain pattern is placed on the first protective layer. A protective layer (...
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Abstract
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