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Alumina-based hydraulic binder systems

A binder and hydraulic technology, which is applied in the field of producing the hydraulic binder system, can solve the problems of volume shrinkage, accelerated solidification, low permeability, etc., and achieve good drying behavior, good corrosion resistance and resistance Permeability, low shrinkage effect

Inactive Publication Date: 2018-11-09
NABALTEC AG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The combination of rho-alumina with magnesia improves the strength increase, accelerated setting acceleration, and increased water demand compared to concrete with pure rho-alumina bond, but there are still disadvantages due to the use of rho-alumina, such as volume shrinkage and prone to rupture due to low permeability

Method used

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  • Alumina-based hydraulic binder systems
  • Alumina-based hydraulic binder systems
  • Alumina-based hydraulic binder systems

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0137] Example 1: Curing behavior of fine-grained compositions consisting of calcined alumina

[0138] Table 1: Composition of Fine Particle Compositions

[0139] Composition of composition [wt%]

components

84.30

Binder system according to table 2

15.70

add water

[0140] Table 2: Composition of hydraulic binder systems

[0141]

[0142] 1 Lightly burnt, Nedmag from the Netherlands

[0143] 2 Plasticizer system (citric acid 72%, acetic acid 28%; both reagent grades from Merck)

[0144] experiment procedure

[0145] The calcined alumina was converted into a slurry by adding magnesia, plasticizer system and water with thorough mixing. The final mixture was poured into plastic molds and stored in an airtight container at room temperature for 27 hours. The curing time of the mixture was determined by the Vicat apparatus test. The apparent density (measured from the weight and volume of the specimen) and the cold compressive stre...

Embodiment 2

[0151] Example 2: Effect of the amount of magnesium oxide on the curing of alpha alumina concrete

[0152] Table 5: Composition of self-flowing α-alumina concrete

[0153] Composition of concrete [wt%]

components

Particle size D 50

39.0

Calcined α-alumina T60 1

1-3mm

7.8

Calcined α-alumina T60 1

0.5-1mm

15.0

Calcined α-alumina T60 1

<0.5

8.86

Calcined α-alumina T60 1

<45μm

23.45

Binder system according to table 6

5.63-5.65

add water

[0154] 1 Almatis GmbH from Germany

[0155] Table 6: Composition of hydraulic binder systems

[0156]

[0157] 2 Lightly burnt, Nedmag from the Netherlands

[0158] 3 Trisodium citrate, reagent grade

[0159] experiment procedure

[0160] A homogeneous slurry is first produced by adding the plasticizer system to the calcined alumina and adding water with thorough mixing. The slurry is then mixed with calcined alpha a...

Embodiment 3

[0164] Example 3: Effect of the BET specific surface area of ​​magnesium oxide on the curing of α-alumina concrete

[0165] Table 8: Composition of self-flowing α-alumina concrete

[0166] Composition of concrete [wt%]

components

Particle size D 50

38.9

Calcined α-alumina T60 1

1.0-3.0mm

7.9

Calcined α-alumina T60 1

0.5-1.0mm

14.9

Calcined α-alumina T60 1

<0.5mm

8.9

Calcined α-alumina T60 1

<45μm

23.8

Binder system according to table 9

5.6

add water

[0167] 1 Almatis GmbH from Germany

[0168] Table 9: Composition of hydraulic binder systems

[0169]

[0170] 2 Lightly burnt, Nedmag from the Netherlands

[0171] 3 65-87.5wt% polycarboxylate ether (PCE), 12-32.5wt% citric acid, 0.1-1.4wt% sulfamic acid, 0.1-1.4wt% silicon dioxide (such as 66.7wt% CASTAMENT FS 20 and 33.3 wt% CastamentFS 10, both available from BASF SE).

[0172] The tests were perfo...

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Abstract

The present invention relates to hydraulic binder systems based on calcined alumina for use in refractory materials. The invention also relates to a method for producing said hydraulic binder system and to its use.

Description

technical field [0001] The present invention relates to hydraulic binder systems based on calcined alumina for use in refractory materials. The invention also relates to a method for producing said hydraulic binder system and also to its use. Background technique [0002] Refractory products are used in all industrial sectors where processes need to be carried out at high temperatures. For example, in the sectors of metal mining and processing and in the cement, lime, gypsum, glass and ceramic industries. [0003] The most important refractory products are shaped dense products (bricks, components), shaped insulating products (light refractory bricks), unshaped refractory products (refractory concrete, stamping components, spray components, tamping components) or finished products Parts (molded articles, bulk materials). [0004] Currently, approximately 41.5 million metric tons of refractory products are produced worldwide annually (Ted Dickson, TAK Industrial Mineral Co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/06C04B14/30C04B111/28
CPCC04B14/303C04B2111/28C04B28/06C04B20/107C04B22/06C04B22/064C04B22/066C04B2103/34C04B24/06
Inventor 克里斯蒂安·东策恩塔德乌什·冯·里蒙·利平斯基
Owner NABALTEC AG