Environment-friendly compounded denitrification agent and denitrification method

An environment-friendly, denitrifying agent technology, applied in chemical instruments and methods, degassed water/sewage treatment, neutralized water/sewage treatment, etc. Ammonia nitrogen treatment effect is poor and other problems, to achieve the effect of overcoming adverse effects, less impact, and low cost of use

Inactive Publication Date: 2016-06-15
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Aiming at the problems of poor ammonia nitrogen treatment effect, low treatment efficiency, non-green and environmentally friendly denitrification agent, large amount of denitrification agent, and poor treatment effect on organic nitrogen in the existing high-concentration ammonia nitrogen wastewater treatment process, the present invention provides an environmental Friendly compound denitrification agent and denitrification method, the new denitrification agent can effectively reduce the ammonia nitrogen in high-concentration ammonia nitrogen wastewater to below 0.3mg / L, and at the same time can recover high-purity ammonia nitrogen non-products, thus achieving environmental benefits Unity with social benefits

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] The environment-friendly compound denitrification agent and denitrification method of this embodiment are especially suitable for the treatment of high-concentration ammonia nitrogen wastewater. 20g of sodium carboxymethylcellulose, 10g of biosurfactant phosphatidylacetamide, 10g of ethylene glycol deaminase, 5g of sodium ferrate, 30g of oxalic acid, and 25g of hydrogen peroxide are fully mixed to prepare 100g of compound denitrification The denitrification agent is used to treat wastewater with an ammonia nitrogen concentration of 10,000 mg / L and a Kjeldahl nitrogen concentration of 13,000 mg / L. The dosage of the compound denitrification agent is 4 mg / L, and the pH of the wastewater is adjusted to 9.5. Blast aeration is adopted, the initial air-water ratio is 50:1, and aeration is for 20 minutes; after the ammonia nitrogen concentration is reduced to 5000mg / L, adjust the air-water ratio to 200:1, and aeration is for 30 minutes; when the ammonia nitrogen concentration is...

Embodiment 2

[0035]An environment-friendly compound denitrification agent and denitrification method in this embodiment are basically the same as in Example 1, except that the ratio of each component of the denitrification agent is different. 40 g of sodium carboxymethyl cellulose, 8 g of biosurfactant phosphatidylacetamide, 10 g of ethylene glycol deaminase, 10 g of potassium ferrate, 10 g of acetic acid, and 22 g of hydrogen peroxide are prepared into 100 g of compound denitrification agents. 30000mg / L, Kjeldahl nitrogen concentration of 35000mg / L wastewater treatment, the dosage of compound denitrification agent is 8mg / L, and the pH of wastewater is adjusted to 10.5. Blast aeration is adopted, the initial air-water ratio is 20:1, and aeration is for 20 minutes; when the ammonia nitrogen concentration is reduced to 5000mg / L, adjust the air-water ratio to 50:1, and aeration is for 30 minutes; when the ammonia nitrogen concentration is reduced to 100mg / L , adjust the air-water ratio to 100...

Embodiment 3

[0037] An environment-friendly compound denitrification agent and denitrification method in this embodiment are basically the same as in Example 1, except that the ratio of each component of the denitrification agent is different. Carboxymethylcellulose sodium 50g, biosurfactant phosphatidylacetamide 20g, ethylene glycol deaminase 10g, sodium ferrate 5g, oxalic acid 10g, and hydrogen peroxide 5g are formulated into 100g of compound denitrification agent. The wastewater with ammonia nitrogen concentration of 5000mg / L and Kjeldahl nitrogen concentration of 5200mg / L is treated, the dosage of compound denitrification agent is 2mg / L, and the pH of wastewater is adjusted to 7.0. Blast aeration is adopted, the initial air-water ratio is 50:1, and the aeration is 20 minutes; after the ammonia nitrogen concentration is reduced to 5000mg / L, the air-water ratio is adjusted to 100:1, and the aeration is 30 minutes; the ammonia nitrogen concentration is reduced to 100mg / L, adjust The air-w...

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Abstract

The invention discloses an environment-friendly compound denitrification agent and a denitrification method, belonging to the technical field of wastewater denitrification. The present invention adopts green surfactant, ethylene glycol deaminase, ferrate and organic carboxylic acids compounded according to a certain proportion, wherein surfactant accounts for 30-70%, and ethylene glycol deaminase accounts for 10- 20%, ferrate 5-10%, organic carboxylic acids 5-30%, hydrogen peroxide 5-30%. Add the compound denitrification agent in the above ratio to the ammonia nitrogen wastewater, the amount added is 2-8mg / L, and adjust the pH of the wastewater to 7.0-10.5 at the same time, according to the residual ammonia nitrogen concentration in the wastewater, adopt the stage aeration method. Aeration blow off. The invention is suitable for the treatment of high-concentration ammonia nitrogen and organic nitrogen wastewater, can reduce the concentration of ammonia nitrogen in the wastewater to below 0.3mg / L, has the advantages of a compound denitrification agent that is environmentally friendly, uses less denitrification agent, and has high denitrification efficiency.

Description

technical field [0001] The invention belongs to the technical field of denitrification of wastewater, and more specifically relates to an environment-friendly compound denitrification agent and a denitrification method. Background technique [0002] With the continuous development of industrial and agricultural production, water pollution (mainly water eutrophication) produced by nitrogen is becoming more and more serious. For this reason, countries have higher and higher requirements for the discharge of wastewater treatment effluent. In addition to strict requirements for organic matter (carbon) and suspended solids, there are also requirements for nitrogen in the treated effluent. Nitrogen exists in several forms: organic nitrogen, ammonia nitrogen, nitrate nitrogen, nitrite nitrogen, and nitrogen gas. [0003] At present, in industrial wastewater, high-concentration ammonia-nitrogen wastewater is mainly the main pollution source of total nitrogen exceeding the standard....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F3/34C02F9/14C02F101/16C02F101/38
CPCC02F3/342C02F1/20C02F1/66C02F1/72C02F1/722C02F9/00C02F2101/16C02F2101/38C02F2305/023C02F2305/026C02F2305/04
Inventor 张炜铭吕路陈良潘丙才
Owner NANJING UNIV
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