Rapid processing method of isopropyl nitrate, and applications thereof
A technology of isopropyl nitrate and treatment method, which is applied in the field of safe treatment of nitrate ester energetic materials, can solve the problems of undisclosed safe treatment methods of isopropyl nitrate energetic materials, etc., and achieve increased reaction rate and removal rate , the effect of simple reaction conditions
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Embodiment 1-16
[0021] Prepare 150mL sodium sulfide solutions of different concentrations, add them to a constant temperature water bath, raise the temperature to the corresponding temperature, then adjust the pH value, add 5mL isopropyl nitrate, and start the reaction. Take 10 mL of the reaction product at 25 min, 50 min, 75 min, and 8 h of reaction, extract with 10 mL of diethyl ether, analyze the extraction phase by gas chromatography, and calculate the removal rate of isopropyl nitrate.
[0022] The concentration of sodium sulfide solution, reaction temperature, reaction pH value and removal rate of isopropyl nitrate in each embodiment are shown in Table 1 below.
[0023]
[0024] As can be seen from Table 1, the preferred reaction conditions of isopropyl nitrate and excessive sodium sulfide reaction are:
[0025] A sodium sulfide aqueous solution with a concentration of 0.1-0.2 mol / L is used, the pH of the reaction solution is controlled to be 6-14, and the temperature is 50-70°C. In...
Embodiment 17-20
[0029] Prepare 150mL of sodium sulfide solution with a concentration of 0.2mol / L, add it to the reaction kettle, raise the temperature to 70°C, adjust the pH value to 10, add 5mL of isopropyl nitrate to be decomposed, and add a corresponding amount of catalyst to start the reaction.
[0030] The amount that adds catalyst among the embodiment 17-20 is respectively 1%, 3%, 5%, 7% of isopropyl nitrate molar weight, does not add dodecyl pyridinium chloride in comparative example, considers the effect of catalyst with this Quantitative effect on the reaction. At 5min, 15min, 25min, 35min, and 4h of the reaction, 10mL of the reaction product was taken, extracted with 10mL of ether, and the extraction phase was analyzed by gas chromatography to determine the removal rate of isopropyl nitrate. By comparison, the influence of the catalyst on the reaction was determined. Table 2 is the test results. figure 1 A plot of the rate constants measured for different experimental reactions. ...
Embodiment 21-24
[0037] With reference to embodiment 17-20, in embodiment 21-24, control the reaction temperature of sodium sulfide aqueous solution and isopropyl nitrate to be 60 ℃, the amount of adding catalyst is 5% of isopropyl nitrate molar weight, all the other reaction control conditions and The removal rate of isopropyl nitrate measured in different time periods is shown in Table 3 below.
[0038]
[0039] From the comparison of the removal rate of isopropyl nitrate in Table 3 and Table 1, it can be seen that the catalyst dodecylpyridinium chloride catalyzes the reaction of sodium sulfide aqueous solution and isopropyl nitrate, which can significantly improve the reaction rate constant and obtain a large amount of nitrate in a relatively short period of time. High removal rate of isopropyl nitrate.
[0040] The invention also discloses the application of the above method, which is applied to the scrap treatment of weapons and ammunition containing isopropyl nitrate. For example, fo...
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