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Antibacterial and low-toxin modified corn starch powdery adhesive

A technology of corn starch and adhesives, applied in the direction of starch adhesives, adhesive additives, adhesive types, etc., can solve the problems of easy gelation, poor fluidity, high viscosity, etc., and achieve the effect of long storage period

Inactive Publication Date: 2018-03-20
李琛璞
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Starch is a polysaccharide polymer formed by the interconnection of many glucose sacking units. It is usually granular and insoluble in water. It can swell or swell in cold water, and then shrink into granular shape after drying. After adding water and heating and gelatinizing starch, although it has Adhesive, but even if the concentration or solid content is very low, its viscosity will be very high, resulting in poor fluidity, easy gelation, and difficult sizing, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] An antibacterial and low-toxic modified cornstarch powdery adhesive, comprising the following components in parts by weight: 120 parts of cornstarch, 6 parts of montmorillonite, 20 parts of casein, 22 parts of sodium acetate, 3 parts of hydrochloric acid, 7 parts of zinc oxide, 1 part of silane coupling agent, 7 parts of tributyl phosphate, 25 parts of composite preservative, 13 parts of nano-silver oxide, 18 parts of urea, and 17 parts of cetyltrimethylammonium bromide.

[0028] In the present invention, the composite anticorrosion agent is ammonia-soluble alkylamine copper and naphthenate copper, and its mass percentage is 3:1.

[0029] A preparation method of an antibacterial and low-toxic modified corn starch powdery adhesive, the specific steps are as follows:

[0030] Step 1. Add montmorillonite to deionized water and stir at high speed until the suspension is formed. When the temperature rises to 70°C, slowly add hexadecyltrimethylammonium bromide while stirring,...

Embodiment 2

[0036] An antibacterial and low-toxic modified cornstarch powdery adhesive, comprising the following components in parts by weight: 130 parts of cornstarch, 8 parts of montmorillonite, 25 parts of casein, 23 parts of sodium acetate, 4 parts of hydrochloric acid, 8 parts of zinc oxide, 2 parts of aluminate coupling agent, 8 parts of tributyl phosphate, 30 parts of composite preservative, 15 parts of nano-silver oxide, 20 parts of urea, and 21 parts of cetyltrimethylammonium bromide.

[0037] In the present invention, the composite preservative is ammonia-soluble alkylamine copper and naphthenate copper, and its mass percentage is 4:1.

[0038] A preparation method of an antibacterial and low-toxic modified corn starch powdery adhesive, the specific steps are as follows:

[0039] Step 1. Add montmorillonite to deionized water and stir at a high speed to a suspension. When the temperature rises to 75°C, slowly add hexadecyltrimethylammonium bromide while stirring, and continue to...

Embodiment 3

[0045] An antibacterial and low-toxic modified cornstarch powdery adhesive, comprising the following components in parts by weight: 140 parts of cornstarch, 10 parts of montmorillonite, 30 parts of casein, 24 parts of sodium acetate, 5 parts of hydrochloric acid, 9 parts of zinc oxide, 3 parts of complex coupling agent, 9 parts of tributyl phosphate, 35 parts of composite preservative, 17 parts of nano-silver oxide, 22 parts of urea, and 25 parts of cetyltrimethylammonium bromide.

[0046] In the present invention, the composite preservative is ammonia-soluble alkylamine copper and naphthenate copper, and its mass percentage is 5:1.

[0047] A preparation method of an antibacterial and low-toxic modified corn starch powdery adhesive, the specific steps are as follows:

[0048] Step 1. Add montmorillonite to deionized water and stir at high speed until the suspension is formed. When the temperature rises to 80°C, slowly add hexadecyltrimethylammonium bromide while stirring, and...

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PUM

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Abstract

An antibacterial and low-toxic modified corn starch powdery adhesive, comprising the following components in parts by weight: 120-140 parts of corn starch, 6-10 parts of montmorillonite, 20-30 parts of casein, 22 parts of sodium acetate ‑24 parts, 3‑5 parts of hydrochloric acid, 7‑9 parts of crosslinking agent, 1‑3 parts of coupling agent, 7‑9 parts of defoaming agent, 25‑35 parts of composite preservative, 13‑17 parts of antibacterial agent, urea 18-22 parts, 17-25 parts of cetyltrimethylammonium bromide; the present invention also discloses a preparation method of an antibacterial and low-toxic modified corn starch powdery adhesive: first corn starch, compound Preservatives and organically modified montmorillonite are mixed evenly, then urea and casein are added for heating reaction to obtain mixture B, then dispersant, coupling agent and defoamer are added to obtain jelly C, and finally spray drying and centrifugation are carried out. Obtain powdery kudzu root starch adhesive. The invention has the characteristics of high bonding strength, water resistance, antibacterial, long environmental protection storage period, etc., effectively reduces the harm to the environment, reduces the production cost, and improves the production benefit of the enterprise.

Description

technical field [0001] The invention belongs to the technical field of adhesives, and in particular relates to an antibacterial and low-toxic modified corn starch powder adhesive. Background technique [0002] Adhesives are the blood of my country's wood-based panel industry. As the largest country in the world's wood-based panel production, consumption, and import and export trade, China uses more than 6.5 million tons of adhesives for wood-based panel production in terms of solid content. Traditional glue The three main types are urea-formaldehyde resin adhesives, melamine-modified urea-formaldehyde resins and phenolic resins, which are three "aldehyde-based" synthetic resin adhesives. These adhesives generally have a certain amount of apron release, which endangers the health of consumers. . In order to reduce the defects of formaldehyde release from the above-mentioned adhesives, starch was used as the main raw material to prepare adhesives. Starch is a polysaccharide po...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J103/02C09J11/08C09J11/04C09J11/06
CPCC09J103/02C08K2003/2286C08K2003/2296C08K2201/011C08K2201/018C08L2201/06C08L2201/08C09J11/04C09J11/06C09J11/08C08L89/00C08K13/02C08K3/346C08K5/098C08K3/22C08K5/521
Inventor 李琛璞
Owner 李琛璞
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