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Multilayer tube internal layer polymer composite material for automobile fuel pipes, and preparation method thereof

A composite material and multi-layer tube technology, applied in the field of automotive materials, can solve the problems of not being able to burn like gasoline, affecting the performance and life of the engine, and avoiding the formation and accumulation of carbon deposits and the formation of carbon deposits in the combustion chamber of the engine. , the effect of good low temperature performance and high temperature performance

Inactive Publication Date: 2018-04-20
东莞科姆新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the continuous improvement of our income and living standards, cars have entered the homes of ordinary people and have become an indispensable means of transportation for our daily life. However, environmental problems have become a major problem for us. Gradually entered a part of the national automobile emission standards, the multi-layer compounding of automobile fuel multi-layer pipes has solved this problem very well, but at present, the inner layer of multi-layer fuel pipes is mostly toughened PA6, and PA6 is toughened to the current use The effect needs to add a considerable proportion of tougheners and plasticizers. Most of the additives are small molecular compounds, which will slowly dissolve when soaked in gasoline, and enter the combustion chamber of the engine with the fuel. These small molecules cannot burn like gasoline, but After carbonization, hard-to-remove carbon deposits are formed in the engine combustion chamber, which affects the performance and life of the engine

Method used

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  • Multilayer tube internal layer polymer composite material for automobile fuel pipes, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Example 1: The present invention relates to a polymer composite material for the inner layer of a multilayer tube for automobile fuel pipes. The inner layer material includes the following components in parts by weight: 50 parts of nylon resin, 10 parts of PE, 5 parts of EVM, corresponding 10 parts of solvent, 1 part of additives; the nylon resin is PA510 (relative viscosity 4.4~4.8), PE is linear low density polyethylene, and the EVM is ethylene vinyl acetate copolymer, wherein the content of vinyl acetate is not Less than 40%; the adjuvant is selected from a mixture of antioxidants, chain extenders and end-capping agents in any ratio; the phase solvent is PE-g-MAH or POE-g-GMA.

[0013] The method for preparing the polymer composite material of the inner layer of the multilayer tube for automobile fuel pipe includes the following steps:

[0014] (1) Weigh each component according to the ratio;

[0015] (2) Add nylon resin, PE, EVM, phase solvent and auxiliary agent to the m...

Embodiment 2

[0017] Example 2: The difference from Example 1 is that the nylon resin is 60 parts, PE 15 parts, EVM 8 parts, phase solvent 15 parts, and auxiliary agent 2 parts. The phase solvents are SEBS-g-MAH and SEBS-g-GMA, and the preparation method of the polymer composite material for the inner layer of the multilayer tube for automobile fuel pipe includes the following steps: (1) Weigh each component according to the proportion; 2) Sequentially add nylon resin, PE, EVM, phase solvent and additives to the mixer, mix evenly and then extrude and granulate through a twin-screw extruder. In the step (2), the stirring temperature is room temperature, the stirring speed is 400 rpm, and the stirring time is 10 minutes; the screw speed of the twin-screw extruder is 300 rpm, and the mixture formed by each component is stirred After homogenization, it passes through nine zones of the twin-screw extruder and then extrudes. The temperature of each zone is 200℃ in one zone, 210℃ in two zone, 220℃ ...

Embodiment 3

[0018] Example 3: The difference from Example 1 is that the inner polymer composite material includes the following parts by weight: 70 parts of nylon resin, 30 parts of PE, 10 parts of EVM, 30 parts of phase solvent, additives 5 parts; the phase solvent is selected from one of PE-g-MAH, POE-g-GMA, SEBS-g-MAH, SEBS-g-GMA. The preparation method of the polymer composite material for the inner layer of the multilayer pipe for automobile fuel pipe includes the following steps: (1) Weigh each component according to the proportion; (2) sequentially add nylon resin, PE, EVM, phase solvent and additives to the mixer , After mixing evenly, it is extruded and granulated through a twin-screw extruder. In the step (2), the stirring temperature is room temperature, the stirring speed is 400 rpm, and the stirring time is 10 minutes; the screw speed of the twin-screw extruder is 320 rpm, and the mixture formed by each component is stirred After homogenization, it passes through nine zones o...

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PUM

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Abstract

The invention relates to a multilayer tube internal layer polymer composite material for automobile fuel pipes, and a preparation method thereof. The internal layer material comprises, by weight, 50-70 parts of nylon resin, 10-30 parts of PE, 5-10 parts of EVM, 10-30 parts of a compatilizer and 1-5 parts of an assistant. Compared with existing materials, the material in the invention has the advantages of few micro-molecular compounds, less precipitation in use, and effectiveness in reduction or avoiding of formation and accumulation of carbon in engine combustion chambers. The composite material has the advantages of effectiveness in avoiding of the use of a plasticizer and a flexibilizer, remarkable reduction of the fuel leaching rate, reduction or avoiding of the formation of carbon inthe engine combustion chambers, and keeping of good low-temperature performances and high-temperature performances.

Description

Technical field [0001] The invention relates to a polymer composite material with a multilayer tube inner layer for automobile fuel pipes and a preparation method thereof, and belongs to the field of automobile materials. Background technique [0002] With the continuous improvement of our income and living standards, automobiles have entered the homes of ordinary people. They have become an indispensable transportation tool for our daily life. However, environmental issues have become a major problem that plagues us, and the self-emissions of automobile fuel pipes are also Gradually entering part of the national automobile emission standards, the multi-layer composite of automobile fuel multi-layer pipes solves this problem very well, but the inner layer of the multi-layer fuel pipe is mostly toughened PA6, which is toughened to the current use. The effect requires the addition of a considerable proportion of tougheners and plasticizers. Most of these additives are small molecul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08L23/08C08L51/06C08L51/00B29B9/06B29C47/92B29C48/92
Inventor 田钟涛陈平旭
Owner 东莞科姆新材料有限公司
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