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A kind of low viscosity liquid detergent composition with yield stress and preparation method thereof

A liquid detergent, yield stress technology, applied in detergent compositions, soap detergent compositions, surface active detergent compositions, etc., can solve the problem of poor product pourability and water solubility, high cost, and suspension aids. The problem of high price, to achieve the effect of excellent suspension stability, excellent storage stability, and excellent washing performance

Active Publication Date: 2020-03-24
GUANGZHOU LIBY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because there is a certain density difference between softener, microcapsule essence, microcapsule antibacterial and acaricide and the matrix of detergent, there will often be problems of stratification, sedimentation or floating in the system
Therefore, in order to solve the problem of delamination, sedimentation or floating of the above-mentioned functional substances in liquid detergents, the patent CN103361197A that can be used for reference proposes a laundry liquid that uses gel to stably disperse microcapsule essence and its preparation process. The microcapsule essence is suspended by natural polymer gel suspending agents such as xanthan gum, gellan gum or hydroxymethyl cellulose CMC. Due to the effect of polymer gel, on the one hand, the amount of suspending agent in the system is relatively large. On the other hand, the viscosity of the washing system formed is also very high, resulting in higher product cost, and the product has poor pourability and water solubility, which cannot be generally accepted by consumers.
Patent WO 2008 / 076693A2 takes suspension stabilizers as the starting point, and proposes different suspending agents Carbopol series to have suspension stability for system suspensions, such as Carbopol Aqua SF-1, Carbopol EZ-4 and Ultrez 10, etc. Experiments have proved that some Carbopol systems are in It has a certain suspension stability at room temperature, but the suspension of the system disappears at high temperatures, and for high molecular polymers with excellent suspension effects, the cost of the polymer used is relatively high, which can almost reach the cost of the total surfactant in the system , the viscosity of the system will also increase sharply
[0004] At present, in the daily chemical industry, the cost of liquid detergents with suspending effects remains high and the technical problems of mainly relying on the addition of suspending aids and the formation of a certain yield stress under high viscosity. On the one hand, the price of suspending aids is generally high. Large consumption leads to expensive system; on the other hand, the addition of suspending aids will lead to changes in the viscosity and stability of the system, causing incompatibility of the system

Method used

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  • A kind of low viscosity liquid detergent composition with yield stress and preparation method thereof
  • A kind of low viscosity liquid detergent composition with yield stress and preparation method thereof
  • A kind of low viscosity liquid detergent composition with yield stress and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~3 and comparative example 1

[0172] Compositions A to D of Examples 1 to 3 and Comparative Example 1 were prepared according to Table 1. The rheological yield stress and viscosity of each system were tested, and the results are shown in Table 1.

[0173] Table 1 has yield stress low viscosity liquid detergent composition

[0174]

[0175] In Examples 1 to 3 and Comparative Example 1, the types and contents of surfactants in each system are the same, and the difference between the systems lies in the electrolyte content, resulting in a large difference in the rheological yield stress of each system. Due to the presence of sodium chloride and sodium citrate in 1 to 3, the system has a certain yield stress uniformly, while the comparative example has no yield stress; at the same time, the systems of Examples 1 to 3 have a certain yield stress in 20s -1 At a certain shear rate, each system maintains a viscosity lower than 1000mpa·s. Maintaining relatively high yield stress at relatively low viscosity, th...

Embodiment 4~7 and comparative example 2~5

[0177] According to Table 2, the compositions E-L of Examples 4-7 and Comparative Examples 2-5 were prepared. The rheological yield stress and viscosity of each system were tested, and the results are shown in Table 2.

[0178] Table 2 has yield stress low viscosity liquid detergent composition

[0179]

[0180]

[0181] Example 4 composition E and comparative example 2 composition F, embodiment 5 composition G and comparative example 3 composition H, embodiment 6 composition I and comparative example 4 composition J and embodiment 7 compositions in table 2 The difference between the four groups of K and the composition L of Comparative Example 5 lies in the difference in the electrolyte content between the Examples and the Comparative Examples.

[0182] figure 2 , image 3 with Figure 4 Schematic diagrams showing the rheological curves, microstructures under a polarizing microscope, and the suspension stabilization effect on colored decorative balls at 45° C. of t...

Embodiment 8~10 and comparative example 6

[0188] According to Table 3, the compositions M-P of Examples 8-10 and Comparative Example 6 were prepared. The rheological yield stress and viscosity of each system were tested. In addition, a decontamination test was also carried out on a low-viscosity liquid detergent composition with a certain yield stress. The results are shown in Table 3.

[0189] Table 3 has yield stress low viscosity liquid detergent composition

[0190]

[0191]

[0192] The difference between Examples 8-10 and Comparative Example 6 is that the compositions M, N and O of Examples contain a certain amount of electrolytes, while the composition P of Comparative Example 6 does not contain electrolytes. As can be seen from the results in Table 3, the cleaning performance of compositions M, N and O containing a certain amount of electrolyte (including carbon black stained cloth, protein stained cloth and sebum stained cloth) is better than composition P. In the compositions M, N and O, as the electr...

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Abstract

The invention discloses a low-viscosity liquid detergent composition with yield stress and a preparation method of the low-viscosity liquid detergent composition. The composition comprises 3.0-40.0% of surfactant by weight percentage and comprises the following ingredients: (1) 3.0-15.0% of electrolyte, (2) 1.0-35.0% of anionic surfactant: 1.0-20.0% of aromatic anionic surfactant and 0.1-10.0% offatty acid salt, (3) 1.0-30.0% of first non-ionic surfactant with a critical arrangement parameter P of 0.5 to 1.0 and in an A-B structure, (4) 1.0-20.0% of second non-ionic surfactant in a straight chain structure, and (5) 0.1-30.0% of assistant, wherein a critical packing parameter P of the first non-ionic surfactant is 0.5-1.0; and an HLB (hydrophile-lipophile balance) of the second non-ionic surfactant is 8-14. The composition has relatively low viscosity; the viscosity is less than 1000mpa*s at a shearing rate of 20s<-1>; the composition has the yield stress of 0.05-2.0Pa in a temperature range of 25-45 DEG C; and the composition can exert an excellent suspension effect on microcapsule particles, oil microemulsion and micro particle size solid suspended substances and keeps an excellent washing and stain removal effect at the same time.

Description

technical field [0001] The invention relates to a liquid detergent composition and a preparation method thereof, belonging to the technical field of daily chemical washing products, in particular to a low-viscosity liquid detergent composition with yield stress and a preparation method thereof. Background technique [0002] With the progress of the times and the improvement of living standards, daily-use chemicals have become an indispensable part of consumers' lives. Consumers' increasing demand for daily chemical products has led to the rapid development of today's daily chemical industry. Liquid detergent is a type of detergent that has developed rapidly in the fabric care market at home and abroad in recent years. In order to meet the diverse needs of the market, liquid detergent is no longer only satisfied with the basic decontamination effect, but also requires it to be soft and durable. Functional effects such as fragrance retention, antibacterial and mite removal. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C11D1/83C11D3/04C11D3/10C11D3/12C11D3/20C11D3/60C11D10/04
CPCC11D1/008C11D1/04C11D1/14C11D1/22C11D1/29C11D1/722C11D1/83C11D3/0015C11D3/046C11D3/10C11D3/1246C11D3/2079C11D3/2086C11D10/04
Inventor 高南李东华马玉杰邱振明王松营
Owner GUANGZHOU LIBY