Preparation method of 3D printing material capable of spontaneously emitting red light
A 3D printing and red light technology, applied in the field of 3D printing materials, can solve the problems of high printing cost, affecting the marketization of 3D printing technology, and shortage of printing materials.
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Embodiment 1
[0024] (1) Preparation of light-converting agent / red-emitting fluorescent material composite: prepare titanate coupling agent, absolute ethanol, light-converting agent with xanthracene structure and red-emitting fluorescent material (SrAl 2 o 4 :Eu 2+ , Dy 3+ ) mixture, heated to 70°C in a closed and high-speed dispersion state, reacted for 40 minutes, filtered after the reaction, and fully washed with absolute ethanol, dried, and pulverized to obtain a light conversion agent / red fluorescent material composite; The preparation of the light conversion agent / red-emitting fluorescent material compound is an existing technology, and the existing ratio and operating parameters can be used. For example, the light conversion agent / red-emitting fluorescent material is prepared by using the data disclosed in the patent CN201610134614.8 Complex;
[0025] (2) Grinding and screening of the light conversion agent / red-emitting fluorescent material compound: the prepared light-converting ...
Embodiment 2
[0030] (1) Preparation of photoconverter / red-emitting fluorescent material composite: titanate coupling agent, absolute ethanol, light-converting agent with anthracene structure and red-emitting fluorescent material (SrAl 2 o 4 :Eu 2+ , Dy 3+ ) mixture, heated to 80°C in a closed and high-speed dispersion state, reacted for 50 minutes, filtered after the reaction, and fully washed with absolute ethanol, dried, and pulverized to obtain a light conversion agent / red fluorescent material composite;
[0031] (2) Grinding and screening of the light conversion agent / red-emitting fluorescent material compound: the prepared light-converting agent / red-emitting fluorescent material compound was pulverized by mechanical grinding and jet milling to prepare a particle size of 10um left and right powder;
[0032](3) Preparation of self-emitting red 3D printing material masterbatch: TPE (thermoplastic elastomer) powder must be dried in a vacuum oven at 100°C for 3 hours before use. After d...
Embodiment 3
[0036] (1) Preparation of photoconverter / red-emitting fluorescent material composite: titanate coupling agent, absolute ethanol, light-converting agent with anthracene structure and red-emitting fluorescent material (SrAl 2 o 4 :Eu 2+ , Dy 3+ ) mixture, heated to 80°C in a closed and high-speed dispersion state, reacted for 55 minutes, filtered after the reaction, and fully washed with absolute ethanol, dried, and pulverized to obtain a light conversion agent / red fluorescent material composite;
[0037] (2) Grinding and screening of the light conversion agent / red-emitting fluorescent material compound: the prepared light-converting agent / red-emitting fluorescent material compound was pulverized by mechanical grinding and jet milling to prepare a particle size of 10um left and right powder;
[0038] (3) Preparation of 3D printing material masterbatch that emits red light: TPE (thermoplastic elastomer) powder must be dried in a vacuum oven at 100°C for 2.5 hours before use. ...
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