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Quantum dot ink based on ink-jet printing

An inkjet printing and quantum dot technology, applied in inks, household appliances, applications, etc., can solve problems such as affecting QLED charge transfer, demanding quantum dot inks, damaging quantum dots, etc. The effect of simplifying the solvent system

Inactive Publication Date: 2019-02-12
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, inkjet printing has strict requirements on quantum dot inks. In order to achieve jetting stability, the commonly used quantum inks add ink stabilizers, surface tension agents, viscosity modifiers, etc., although the jetting stability and film formation of ink droplets are improved. properties, but the additives will affect the charge transport in QLEDs, and some additives will even damage the quantum dots themselves

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A quantum dot ink based on inkjet printing, the specific steps are:

[0022] Decane (boiling point 174°C) is purified by water removal and used as an organic solvent.

[0023] Add red rod-shaped ZnSe / ZnS core-shell quantum dots with oleylamine oleic acid ligands to the organic solvent, control the mass fraction of the core-shell quantum dots to 2wt%, 5 nm in diameter, and 8 nm in length, and shake to Disperse evenly and filter for later use.

Embodiment 2

[0025] Cyclodecane (boiling point 201°C) and toluene (boiling point 110°C) were mixed in a 5ml reagent bottle at a volume ratio of 1:1 and stirred evenly as an organic solvent for use.

[0026] Add red rod-shaped ZnSe / ZnS core-shell quantum dots with oleylamine oleic acid ligands to the organic solvent, with a diameter of 5 nm and a length of 8 nm, control the mass fraction of the core-shell quantum dots to 2wt%, and shake to Disperse evenly and filter for later use.

Embodiment 3

[0028] Decane (boiling point 174°C) is purified by water removal and used as an organic solvent.

[0029] Incorporation of green inorganic perovskite CsPbBr with oleylamine ligands into organic solvents 3 The nanodisc has a thickness of 3nm and a diameter of 30nm. The mass fraction of the inorganic perovskite quantum dots is controlled to be 2wt%, oscillated until uniformly dispersed, and filtered for use.

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Abstract

The invention belongs to the technical field of photoelectric display device materials and specifically relates to quantum dot ink based on ink-jet printing. The quantum dot ink is prepared from a quantum dot and an organic solvent, wherein the quantum dot material is prepared from a core-shell quantum dot system of CdS and the like or an inorganic perovskite quantum dot; the organic solvent is asingle solvent or a mixed solvent, and the single solvent or the mixed solvent is a low-polarity or non-polar solvent. According to the prepared ink disclosed by the invention, a complex ink additivefor regulating an ink film forming coffee ring is effectively avoided, and interaction force of movement of non-symmetrical quantum dots in ink is utilized to simply and effectively realize even filmformation of the quantum dots; thus, a quantum dot ink solvent system is greatly simplified; meanwhile, a selection space of a hole transport layer is widened; the quantum dot ink has the advantages of better dispersion, stability, appropriate boiling point, surface tension and viscosity, ability in meeting a requirement of quantum dot ink-jet printing and favorability for industrialization of quantum dot pixelate display.

Description

technical field [0001] The invention belongs to the technical field of photoelectric display device materials, and in particular relates to a quantum dot ink based on inkjet printing. Background technique [0002] In addition to the advantages of OLED all-solid-state, low energy consumption, ultra-thin, no viewing angle limitation, high color gamut, excellent shock resistance, and easy realization of flexible display, QLED also shows good stability and is suitable for solution method preparation. Features, with potential low manufacturing costs and other advantages. These advantages make quantum dot printing display technology considered to be the fastest growing new flat panel display technology in the future. The quantum dots in the luminescent layer are nanocrystals with quantum confinement effects and separate energy band structures. It can emit fluorescence with tunable wavelength under the conditions of light injection and current injection. The principle of quantum...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/38
CPCC09D11/38
Inventor 李福山刘洋胡海龙徐中炜马福民郭太良
Owner FUZHOU UNIV
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