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Flame-retardant plastic alloy capable of self-extinguishing from fire and capable of conducting heat and electricity, and preparation method thereof

A technology of electrical and thermal conductivity and flame retardant plastics, applied in the field of high molecular polymers and their preparation, can solve the problem of not being able to have electrical conductivity, thermal conductivity and self-extinguishing flame retardant properties at the same time, and achieve easy molding, excellent electrical conductivity, flowability, etc. good effect

Active Publication Date: 2020-11-27
RES INST OF ZHEJIANG UNIV TAIZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The purpose of the present invention is to solve the technical problem that the same polymer material cannot have the characteristics of electric conduction, heat conduction and self-extinguishing flame retardant at the same time

Method used

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  • Flame-retardant plastic alloy capable of self-extinguishing from fire and capable of conducting heat and electricity, and preparation method thereof
  • Flame-retardant plastic alloy capable of self-extinguishing from fire and capable of conducting heat and electricity, and preparation method thereof
  • Flame-retardant plastic alloy capable of self-extinguishing from fire and capable of conducting heat and electricity, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A flame-retardant plastic alloy that is self-extinguishing from fire and capable of conducting heat and electricity, comprising the following components:

[0030] component name Mass percentage (%) Acrylonitrile-Butadiene-Styrene Terpolymer 20 SG-8 type polyvinyl chloride 45 Phosphor flake graphite 20 Hexagonal Aluminum Nitride 7 Organotin Mercaptide 3 Aluminum oxide 5

[0031] Add SG-8 type polyvinyl chloride, mercaptan organotin, graphite flake, hexagonal aluminum nitride, aluminum oxide and acrylonitrile-butadiene-styrene terpolymer into the mixer in turn, keeping the speed of 200rpm, Mix for 10 minutes to obtain a homogeneous mixture;

[0032] The above mixture is extruded and granulated through a co-rotating parallel twin-screw extruder. The processing temperature is 130-180°C.

[0033] The above-mentioned materials have been tested to have a volume resistance of 3056Ωm and a thermal conductivity of 4.3W / mk. At t...

Embodiment 2

[0035] A flame-retardant plastic alloy that is self-extinguishing from fire and capable of conducting heat and electricity, comprising the following components:

[0036]

[0037]

[0038] Add SG-8 type polyvinyl chloride, mercaptan organotin, graphite flake, hexagonal aluminum nitride, aluminum oxide, acrylonitrile-styrene copolymer and butene rubber into the mixer in turn, keep the speed of 180rpm, and mix for 15min , to obtain a homogeneous mixture;

[0039] The above mixture is extruded and granulated through a co-rotating parallel twin-screw extruder. The processing temperature is 130-180°C.

[0040] The above-mentioned materials have been tested, and the volume resistance is 8187Ωm, the thermal conductivity is 2.9W / mk, and it has reached the self-extinguishing flame retardant level defined by the UL-94 test standard.

Embodiment 3

[0042] A flame-retardant plastic alloy that is self-extinguishing from fire and capable of conducting heat and electricity, comprising the following components:

[0043] component name Mass percentage (%) Acrylonitrile-Butadiene-Styrene Terpolymer 19 SG-8 type polyvinyl chloride 44 Phosphor flake graphite 22 Hexagonal Aluminum Nitride 7 Organotin Mercaptide 3 Aluminum oxide 5

[0044] Add SG-8 type polyvinyl chloride, mercaptan organotin, graphite flake, hexagonal aluminum nitride, aluminum oxide and acrylonitrile-butadiene-styrene terpolymer into the mixer in turn, keeping the speed of 200rpm, Mix for 10 minutes to obtain a homogeneous mixture;

[0045] The above mixture is extruded and granulated through a co-rotating parallel twin-screw extruder. The processing temperature is 130-180°C.

[0046] The above-mentioned materials have been tested, and the volume resistance is 1056Ωm, the thermal conductivity is 3.7W / mk, and th...

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Abstract

The invention discloses a flame-retardant plastic alloy capable of self-extinguishing away from fire and capable of conducting heat and electricity, and a preparation method thereof, wherein the flame-retardant plastic alloy capable of self-extinguishing away from fire and capable of conducting electricity and heat includes acrylonitrile-butadiene-styrene copolymer, polyvinyl chloride, graphite, aluminum nitride, organic tin mercaptide and metal oxide, and the flame-retardant plastic alloy adopts a co-rotating parallel twin-screw extruder for blending and extrusion processing. The flame-retardant plastic alloy of the present invention has excellent electrical conductivity, thermal conductivity and flame retardancy; it has good fluidity, is easy to shape, is suitable for injection molding, extrusion and other processes, is environmentally friendly, and can be widely used in various scenarios.

Description

technical field [0001] The invention relates to a high molecular polymer and a preparation method thereof, in particular to a flame-retardant plastic alloy capable of self-extinguishing when away from fire and capable of conducting heat and electricity, and a preparation method thereof. Background technique [0002] A variety of flame-retardant plastic alloy materials have been used in all aspects of life, including interior decoration of transportation vehicles, shielding materials and packaging bags of various electrical appliances, etc. [0003] Such plastic alloy materials, in addition to having appropriate electrical properties, must also substantially retain their original properties in order to have effective performance over many years of use and meet strict national safety standards. [0004] Flame retardants are chemicals used in polymers to inhibit or resist the spread of fire. Some compounds containing halogen elements were first found to improve the flame retar...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L55/02C08K3/04C08K3/28C08K5/58C08K3/22
CPCC08K2003/2227C08K2003/282C08L27/06C08L2201/02C08L55/02C08K3/04C08K3/28C08K5/58C08K3/22C08K3/2279
Inventor 周伯昕聂祝平丁伟伟黄然
Owner RES INST OF ZHEJIANG UNIV TAIZHOU