Slow release organic fertilizer for passivation repairing of heavy metal polluted soil and preparation and application thereof

A technology for organic fertilizers and polluted soils, applied in the preparation of organic fertilizers, organic fertilizers, inorganic fertilizers, etc., can solve the problems of improving and stabilizing adverse repair effects, reducing the effective concentration of pollutants, and reducing the bioavailability of heavy metals, etc. Achieve the effects of enhancing passivation stability, preventing the increase of effective heavy metal content, and reducing the accumulation of nitrite

Inactive Publication Date: 2019-03-19
SHENYANG INST OF APPL ECOLOGY CHINESE ACAD OF SCI
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  • Summary
  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Soil pollution remediation generally reduces the bioavailability of heavy metals through complexation, adsorption, precipitation, redox, etc. The remediation technologies for heavy metal-contaminated soil mainly include electrodynamic remediation technology, leaching method, phytoremediation, microbial remediation, and plant-microbial joint remediation. technology, etc., but these technologies have disadvantages of varying degrees, such as high cost, complex operation, low repair efficiency, poor long-term stability and single repair pollution
[0003] Passivating agent remediation is a method that can reduce the absorption of heavy metal ions by plants. It can be divided into inorganic and organic passivating agents. As an organic passivating agent, organic fertilizer has a passivating effect on heavy metals and is an effective method for repairing heavy metal-contaminated soil. Means, organic and inorganic passivators can reduce the effective concentration of pollutants in the soil through processes such as adsorption, co-precipitation, and complexation. Although these two types of passivators have the advantages of low cost, simple process, and reduced plant toxicity of heavy metals, etc. , but have the disadvantages of low repair efficiency, poor stability, and easy to produce secondary pollution [Reference 2: Mahar, A., Ping, W.A.N.G., Ronghua, L.I., & ZHANG, Z. (2015). Immobilization of lead and cadmium incontaminated soil using amendments: a review. Pedosphere, 25(4), 555-568.]
At the same time, if the soil is barren and under water stress conditions, coupled with the coexistence of various heavy metal pollution ions in the polluted soil, the soil environmental conditions will be worse, and the interaction between pollutants will also aggravate the toxicity, inhibit soil animals and The growth and reproduction of microorganisms, as well as the growth of plants, is not conducive to the improvement and stability of the restoration effect

Method used

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  • Slow release organic fertilizer for passivation repairing of heavy metal polluted soil and preparation and application thereof
  • Slow release organic fertilizer for passivation repairing of heavy metal polluted soil and preparation and application thereof
  • Slow release organic fertilizer for passivation repairing of heavy metal polluted soil and preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A multifunctional slow-release organic fertilizer for passivation repairing heavy metal-contaminated soil and a preparation method thereof, comprising the following steps:

[0040] (1) Preparation of decomposed compost: Dry or sun-dry the corn stalks so that the weight moisture content is 10%, crush the corn stalks into 2-5cm pieces; fully mix the fresh pig manure and corn stalks, and adjust the initial raw materials for composting The carbon-to-nitrogen ratio is 30, and the weight moisture content is controlled at 60% during the composting process. Ventilation and turning are carried out under natural conditions, and the pile is turned once every 4 days, and the pile is turned 9 times in total. 60%, when the temperature gradually decreases to 10°C slightly higher than the ambient temperature, the dung pile is compacted to form an anaerobic environment inside the dung pile, and the composting process is completed in 35 days. The decomposed compost is dried at 50°C for 3...

Embodiment 2

[0051] The multifunctional slow-release organic fertilizer of a kind of passivation repairing heavy metal polluted soil prepared by the embodiment of the present invention 1 is added in the heavy metal (taking cadmium as an example) polluted soil according to the 3% consumption of repairing soil dry weight, test soil property As shown in Table 1, plow in time.

[0052] Table 1: Properties of the tested soils

[0053]

[0054] According to the organic fertilizer of the present invention in the embodiment 2, heavy metal polluted soil is carried out remediation experiment, table 2 is organic fertilizer of the present invention and general heavy metal pollution remediation agent to the comparison table of extractable cadmium removal rate in polluted soil, general remediation agent comprises Commercially available common organic fertilizers, biochars, and mixed restoration agents of common organic fertilizers and biochars. In this comparative test, the common organic fertilizers...

Embodiment 3

[0061] (1) Preparation of decomposed compost: the same as in Example 1.

[0062] (2) Preparation of biochar: same as Example 1.

[0063] (3) Preparation of modified biochar: same as in Example 1.

[0064] (4) Preparation of organic fertilizer granules with water retention performance: same as in Example 1.

[0065] (5) Preparation of coating solution: the same as in Example 1.

[0066] (6) Preparation of granular fertilizer: same as in Example 1.

[0067] (7) Fertilizer granule coating: the same as in Example 1.

[0068] The organic fertilizer prepared by the present invention is added to the heavy metal polluted soil according to the amount of 1% of the dry weight of the soil, and the properties of the soil are shown in Table 1 in Example 2. Timely plowing, one month sampling analysis of heavy metal cadmium content.

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Abstract

The invention primarily relates to a multifunctional slow release organic fertilizer containing a heavy metal passivator and a preparation method. The fertilizer comprises the main components: thoroughly decomposed compost, a chemical nitrogen fertilizer, a biochemical inhibitor, a soil heavy metal passivating material, plant growth beneficial elements, a water retaining material and a coating liquid for coating the periphery of the organic particles. The proportion of the thoroughly decomposed compost, the chemical nitrogen fertilizer, the biochemical inhibitor, the soil heavy metal passivating material, the plant growth beneficial elements, the water retaining material and the coating liquid is 1: (0.1-0.3):(0.05-0.1):(0.01-0.2):(0.001-0.02):(0.04-0.08):(0.05-0.1). The fertilizer can reduce bio-availability of heavy metals in the heavy metal polluted soil and reduce adsorption of the heavy metals by crops and increase the content of organic matters in soil and improve the soil fertility, can promote crop growth and enhance water and fertilizer-retaining abilities of the soil, and enhance various functions of crops, for example, disease resistance, drought resistance and the like.

Description

technical field [0001] The invention belongs to the field of remediation of soil heavy metal pollution by organic passivators, and relates to a method for realizing remediation of soil heavy metal pollution by utilizing organic fertilizers. Specifically, it is a slow-release organic fertilizer that can not only reduce the bioavailability of heavy metals in the soil, but also promote crop growth and enhance soil water and fertilizer retention capacity, so as to realize resource recycling. Background technique [0002] With the rapid development of industrialization and urbanization, soil heavy metal pollution is becoming more and more serious. The 2014 my country Soil Pollution Survey Bulletin shows [Reference 1: National Soil Pollution Survey Bulletin [EB / OL].2014-04-17], my country 19.4% of farmland soil pollution points exceeded the standard, especially heavy metal polluted soil, and the excessive use of chemical fertilizers aggravated the pollution of heavy metals to the s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00C05G3/04C05G3/08A01C21/00C05G3/80C05G3/90
CPCA01C21/00C05C9/00C05G3/00C05G3/80C05G3/90C05G5/30C05G5/36C05D1/00C05D9/00C05D9/02C05F3/00C05F11/00C05F17/00Y02P60/21Y02A40/22
Inventor 周长瑞宇万太马强宁川川袁海燕夏竹青
Owner SHENYANG INST OF APPL ECOLOGY CHINESE ACAD OF SCI
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