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A kind of composite surfactant containing quaternary ammonium salt and application thereof

A surfactant and quaternary ammonium salt technology, applied in the field of surfactant preparation, can solve the problems of harsh conditions, flocculation and stratification, and easy precipitation, so as to simplify the production process and improve production efficiency

Active Publication Date: 2021-06-15
邱越
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But due to lack of preparation Carnauba Wax Lotion special surfactants, resulting in Carnauba Wax Lotion In the preparation process, it is often necessary to add a series of additives such as various surfactants, emulsifiers, dispersants, defoamers, and anti-settling agents, and the emulsification process is complicated and the conditions are harsh; and the conventional method prepared Carnauba Wax Lotion Long-term storage is unstable, prone to precipitation and flocculation stratification

Method used

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  • A kind of composite surfactant containing quaternary ammonium salt and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The preparation of embodiment 1 composite surfactant containing quaternary ammonium salt

[0025] The weight ratio of quaternary ammonium salt surfactant and oleaginous resin oil surfactant is 1:1 mixes and promptly obtains described composite surfactant containing quaternary ammonium salt; Described quaternary ammonium salt surfactant is Cetyltrimethylammonium chloride;

[0026] Described oleaginous resin oil surfactant is prepared by following method:

[0027] (1) Mix oleoresin oil and fumaric acid in a reaction kettle at a weight ratio of 1:0.3, and then adjust the temperature to 200°C for 4 hours to obtain fumaric acid modified oleoresin oil.

[0028] (2) Mix fumaric acid modified oleoresin oil, deionized water and xylitol in a weight ratio of 1:1.5:0.5 in the reaction kettle, and the added weight is 3% of the weight of fumaric acid modified oleoresin oil Zinc sulfate catalyst, and then adjust the temperature to 240 ° C for 4 hours, after cooling, the oleaginous r...

Embodiment 2

[0029] The preparation of embodiment 2 composite surfactant containing quaternary ammonium salt

[0030] The weight ratio of quaternary ammonium salt surfactant and oleaginous resin oil surfactant is 2:1 and mixes and obtains described composite surfactant containing quaternary ammonium salt; Described quaternary ammonium salt surfactant is Cetyltrimethylammonium chloride;

[0031] Described oleaginous resin oil surfactant is prepared by following method:

[0032] (1) Mix olean resin oil and fumaric acid in a reaction kettle at a weight ratio of 1:0.5, and then adjust the temperature to 180°C for 5 hours to obtain fumaric acid modified oleoresin oil.

[0033] (2) In the reactor, mix fumaric acid modified oleoresin oil, deionized water and xylitol in a weight ratio of 1:1:0.6, and the added weight is 5% of the weight of fumaric acid modified oleoresin oil The catalyst zinc sulfate, and then adjust the temperature to 220 ° C for 3 hours, after cooling, the oleaginous resin oil...

Embodiment 3

[0034] The preparation of embodiment 3 composite surfactant containing quaternary ammonium salt

[0035] The weight ratio of quaternary ammonium salt surfactant and oleaginous resin oil surfactant is 1:2 mixes to obtain described composite surfactant containing quaternary ammonium salt; Described quaternary ammonium salt surfactant is Cetyltrimethylammonium chloride;

[0036] Described oleaginous resin oil surfactant is prepared by following method:

[0037] (1) Mix oleoresin oil and fumaric acid in a reaction kettle at a weight ratio of 1:0.2, and then adjust the temperature to 220°C for 3 hours to obtain fumaric acid modified oleoresin oil.

[0038] (2) In the reactor, mix fumaric acid modified oleoresin oil, deionized water and xylitol in a weight ratio of 1:1:0.3, and the added weight is 2% of the weight of fumaric acid modified oleoresin oil The catalyst zinc sulfate, and then adjust the temperature to 250 ° C for 5 hours, after cooling, the oleaginous resin oil surfact...

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Abstract

The invention discloses a compound surfactant containing quaternary ammonium salt and application thereof. The complex surfactant containing quaternary ammonium salt includes quaternary ammonium salt surfactant and oleoresin oil surfactant. The oleifera resin oil surfactant is prepared by the following method: (1) Mix the oleoresin oil and fumaric acid in a reaction kettle at a weight ratio of 1:0.2-0.5, and then adjust the temperature to 180-220°C React for 2 to 5 hours to obtain fumaric acid modified oleoresin oil; (2) Fumaric acid modified oleoresin oil, deionized water and xylitol in a weight ratio of 1:1 to 1.5 in the reaction kettle: Mix 0.3-0.6, add a catalyst whose weight is 2%-5% of the fumaric acid modified oleoresin oil, then adjust the temperature to 220-250°C for 3-5 hours, and get the oleoresin oil surfactant after cooling . The composite surfactant containing quaternary ammonium salt has very good dispersing and emulsifying ability for carnauba wax, and can easily disperse carnauba wax in water to form a stable carnauba wax emulsion.

Description

technical field [0001] The invention relates to the technical field of surfactant preparation, in particular to a composite surfactant containing a quaternary ammonium salt and an application thereof. Background technique [0002] Surfactant refers to a substance that can significantly change the interface state of its solution system when added in a small amount; A series of physical and chemical effects such as antistatic and antistatic are a kind of fine chemical products that are flexible and versatile. [0003] carnauba wax lotion It is a product prepared by emulsification technology based on carnauba wax as the main raw material; it is widely used in the manufacture of leather finishing agents, water-based inks, water-based paints, water-based paints, glazing agents, fruit preservation, and plastic and rubber lubricants, etc. . But due to lack of preparation carnauba wax lotion special surfactants, resulting in carnauba wax lotion In the preparation process, it is...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01F17/18B01F17/56C07H1/00C07H13/06C09K3/00C09K23/18C09K23/56
CPCC07H1/00C07H13/06C09K3/00C09K23/018
Inventor 邱越
Owner 邱越
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