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A kind of anti-ablation coating material for resin-based composite material and preparation method thereof

A composite material and coating material technology, applied in coatings, fire-resistant coatings, etc., can solve the problems of interlayer stress mismatch, shedding, low thermal conductivity, etc. The effect of time boundaries

Active Publication Date: 2021-06-01
AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Thermal barrier coatings have low thermal conductivity and appropriate expansion coefficient, and have good thermal insulation properties. They are relatively mature in thermal protection applications on metal-based surfaces, but their bonding strength with resin-based composite materials is low, and there are interlayers. The problem of stress mismatch, it is easy to fall off during use and lose the heat insulation effect

Method used

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  • A kind of anti-ablation coating material for resin-based composite material and preparation method thereof

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Effect test

Embodiment 1

[0019] An anti-ablation coating material for resin-based composite materials is provided, and the anti-ablation coating material is yttria-stabilized zirconia, resin, Cu and SiO 2 A homogeneous mixture that is a spherical particle or spherical aggregate material.

[0020] Further, wherein, yttria stabilized zirconia, resin, Cu, SiO 2 The mass ratio between them is: 72:3:8:17.

[0021] Further, wherein, the resin includes phenolic resin, modified silicone resin and polyester; the mass ratio between the phenolic resin, modified silicone resin and polyester is: 1:2:1.

[0022] Provided is a method for preparing an anti-ablation coating material for resin-based composite materials. Yttria-stabilized zirconia (YSZ) powder with a particle size of 10-20 nm, resin powder with a particle size of 1-2 μm, and Yttria-stabilized zirconia (YSZ) powder with a particle size of 3-5 μm are provided. Cu powder and SiO with a particle size of 3-5 μm 2 The powder is uniformly mixed to form a mi...

Embodiment 2

[0027] On the basis of the foregoing embodiments, the steps of this embodiment are:

[0028] An anti-ablation coating material for resin-based composite materials is provided, and the anti-ablation coating material is yttria-stabilized zirconia, resin, Cu and SiO 2 A homogeneous mixture that is a spherical particle or spherical aggregate material.

[0029] Further, wherein, yttria stabilized zirconia, resin, Cu, SiO 2The mass ratio between them is: 72:4:8:16.

[0030] Further, wherein, the resin includes phenolic resin, modified silicone resin and polyester; the mass ratio between the phenolic resin, modified silicone resin and polyester is 2:2:1.

[0031] Provide a method for preparing an anti-ablation coating material for resin-based composite materials. Yttria-stabilized zirconia (YSZ) powder with a particle size of 15 nm, resin powder with a particle size of 1 μm, Cu powder with a particle size of 3 μm and Cu powder with a particle size of 3 μm are provided. SiO 2 The ...

Embodiment 3

[0036] On the basis of the foregoing embodiments, the steps of this embodiment are:

[0037] An anti-ablation coating material for resin-based composite materials is provided, and the anti-ablation coating material is yttria-stabilized zirconia, resin, Cu and SiO 2 A homogeneous mixture that is a spherical particle or spherical aggregate material.

[0038] Further, wherein, yttria stabilized zirconia, resin, Cu, SiO 2 The mass ratio between them is: 74:8:8:10.

[0039] Further, wherein, the resin includes phenolic resin, modified silicone resin and polyester; the mass ratio between the phenolic resin, modified silicone resin and polyester is 2:2:2.

[0040] Provide a method for preparing an anti-ablation coating material for resin-based composite materials. Yttria-stabilized zirconia (YSZ) powder with a particle size of 15nm, resin powder with a particle size of 2μm, Cu powder with a particle size of 2μm and Cu powder with a particle size of 4μm SiO 2 The powder is uniform...

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Abstract

The invention relates to an anti-ablation coating material for resin-based composite materials and a preparation method thereof. The anti-ablation coating material is yttria-stabilized zirconia, resin, Cu and SiO 2 A homogeneous mixture that is a spherical particle or spherical aggregate material. The preparation method includes powder mixing, ball milling and spray granulation. The advantage of the present invention is that the composite YSZ ceramic surface layer with exothermic specific components is used. On the one hand, the ceramic layer plays a good role in heat insulation and anti-ablation; Further improve the anti-ablation and heat insulation properties of the composite material.

Description

technical field [0001] The invention belongs to the field of thermal protective coating materials for resin-based composite materials, in particular to an anti-ablation coating material for resin-based composite materials and a preparation method thereof, especially for anti-ablation coating materials for polyimide resin-based composite materials. Ablation and thermal protection. Background technique [0002] Polyimide resin-based composite materials have a series of advantages such as high specific strength, strong designability, and good fatigue fracture resistance. , The thrust reverser device has been widely used, and the weight reduction effect is obvious. [0003] The service environment of advanced aero-engines is at a higher temperature, which puts forward higher thermal protection requirements for the service performance of engine components of polyimide resin-based composite materials. performance stability. At present, the polyimide resin-based composite materi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D1/00C09D7/65C09D5/18C09D7/61C08J7/04C08J7/05C08L101/00
CPCC09D1/00C09D7/65C09D5/18C09D7/61C08J7/04C08J2300/00B29B9/10B29B2009/125B29B9/12B29B7/90B29B7/103C08K3/36C08K2003/085C08K2003/2244C08K2201/011C08K9/02B29B9/08B29K2029/04B29K2283/00C08K7/18C08K2003/2248C08L29/04C08L83/04
Inventor 田浩亮庞洁王长亮郭孟秋汤智慧于洋高俊国崔永静张欢欢
Owner AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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