Modified antioxidant for polypropylene phenol red, polypropylene composition and its preparation method and application
A technology of polypropylene composition and antioxidant, applied in the field of processing and forming of polypropylene film, to achieve the effects of improving migration resistance, increasing service life and improving compatibility
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Embodiment 1
[0038] Embodiment 1 provides a kind of modified antioxidant and preparation method thereof, comprising:
[0039] Prepare 92 g of toluene, 31.2 g of styrene, 3.5 g of hydroxyethyl acrylate, and 1.2 g of ammonium persulfate as an initiator, and react at a temperature of 80° C. for 6 hours to obtain a styrene-acrylate copolymer.
[0040] Add 16.1g of antioxidant (REVONOX 420) and 0.2g of sulfuric acid to the obtained styrene-acrylate copolymer, react at 60°C for 2 hours, pour into ethanol, precipitate and filter, and then dry to obtain the modified antioxidant Oxygen.
Embodiment 2
[0042] Embodiment 2 provides a kind of polypropylene composition, comprises:
[0043] Add modified antioxidant 1g in 1000g polypropylene resin, antioxidant 1010 2g, benzophenone light stabilizer 2g, wherein modified antioxidant is the modified antioxidant obtained in embodiment 1, mixes and passes The twin-screw extruder extruded and granulated, the temperature of the extruder was 180° C., and the screw speed was 200 rpm to obtain a polypropylene composition.
[0044] The prepared polypropylene composition is used to produce a casting film, and the film is accompanied by a slightly slight phenol red phenomenon after winding, which is acceptable in production and application.
Embodiment 3
[0046] Embodiment 3 provides a kind of polypropylene composition, comprises:
[0047] Add modified antioxidant 3g in 1000g polypropylene resin, antioxidant 168 1g, benzophenone light stabilizer 2g, wherein said modified antioxidant is the modified antioxidant obtained in embodiment 1, mix Extrude and granulate evenly through a twin-screw extruder, the temperature of the extruder is 210° C., and the screw speed is 300 rpm to obtain a polypropylene composition.
[0048] The prepared polypropylene composition is used to produce a casting film, and the phenomenon of phenol red does not occur after the film is rolled.
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Abstract
Description
Claims
Application Information
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