Molybdenum disulfide/polyferrocenyl Schiff base composite material and preparation method thereof

A technology of polyferrocenyl mat and polyferrocenyl, which is applied in the field of molybdenum disulfide/polyferrocenyl Schiff base composite material and its preparation, and can solve the problems of uneven dispersion and poor compatibility

Inactive Publication Date: 2020-01-07
HARBIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to solve the problem of compounding molybdenum disulfide and ferrocene-based polymers in order to synthesize a class of new functional composite materials with many excellent properties such as lubricity and electrical conductivity, as well as the combination of molybdenum disulfide and high molecular polymers. The problem of poor compatibility and uneven dispersion between them can fundamentally make up for the shortcomings of the traditional physical blending method, realize the transformation of the composite material from two phases to a single phase, and obtain many excellent properties such as electrical conductivity, and provide a two-phase Molybdenum sulfide / polyferrocenyl Schiff base composite material and preparation method thereof

Method used

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  • Molybdenum disulfide/polyferrocenyl Schiff base composite material and preparation method thereof

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specific Embodiment approach 1

[0012] Specific embodiment one: This embodiment is a kind of molybdenum disulfide / polyferrocenyl Schiff base composite material, which is prepared by inorganic solvent, organic solvent, lithium intercalation molybdenum disulfide, polyferrocenyl Schiff base Formed; The quality of described lithium intercalation molybdenum disulfide and the volume ratio of inorganic solvent are 1g:(100~300) mL; The quality of described lithium intercalation molybdenum disulfide and polyferrocenyl Schiff base The ratio is 1: (1~6);

[0013] The lithium intercalation molybdenum disulfide is prepared by mixing and stirring molybdenum disulfide, n-butyl lithium and n-hexane by n-butyllithium intercalation method; the polyferrocenyl Schiff base is prepared by It is made by polymerization of ferrocene formaldehyde, diamine compound, terephthaloyl chloride and organic solvent.

specific Embodiment approach 2

[0014] Embodiment 2: The difference between this embodiment and Embodiment 1 is: the inorganic solvent is water; the organic solvent is DMF.

[0015] Others are the same as the first embodiment.

specific Embodiment approach 3

[0016] Embodiment 3: The difference between this embodiment and Embodiment 1 or 2 is that the diamine compound is p-phenylenediamine, 1,6-hexanediamine, 1,4-cyclohexane diamine.

[0017] Others are the same as those in Embodiment 1 or 2.

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Abstract

The invention discloses a molybdenum disulfide/polyferrocenyl Schiff base composite material and a preparation method thereof, and relates to a composite functional material which is synthesized by compounding molybdenum disulfide and polyferrocenyl Schiff base and has multiple excellent properties such as lubricity and conductivity. The preparation method of the molybdenum disulfide/polyferrocenyl Schiff base composite material comprises the following steps: 1, preparing a lithium-intercalated molybdenum disulfide suspension; 2, preparing a polyferrocenyl Schiff base/DMF mixed solution; 3, dropwise adding the polyferrocenyl Schiff base/DMF mixed solution into the lithium-intercalated molybdenum disulfide to obtain a reaction product; and 4, carrying out separation treatment on the reaction product to obtain the molybdenum disulfide/polyferrocenyl Schiff base composite material. The preparation method has the advantages that the problems of poor compatibility and non-uniform dispersionof a traditional physical blending method are fundamentally solved, and various excellent properties such as lubricity and conductivity of the material are improved. The method is mainly used for preparing the molybdenum disulfide/polyferrocenyl Schiff base composite material.

Description

technical field [0001] The invention relates to a molybdenum disulfide / polyferrocenyl Schiff base composite material and a preparation method thereof. Background technique [0002] The two-dimensional layered transition metal chalcogenide (molybdenum disulfide) is a "sandwich" structure: two layers of sulfur atoms form a sandwich structure, a layer of molybdenum atoms is between the interlayers, and the layers are connected by van der Waals force. Based on the unique spatial structure and valence band structure of molybdenum disulfide, molybdenum disulfide nanomaterials have been widely used in many fields such as photovoltaic devices, lubricants, electrocatalysis, and hydrogen energy storage. Ferrocene has a sandwich structure and an aromatic highly electron-rich system with good thermal stability and good reactivity. This metal-organic compound is more popular among many metal-organic compounds due to its cheapness, low toxicity and easy substitution. Having attention. T...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/02C08K3/30
CPCC08K3/30C08K2003/3009C08L79/02
Inventor 尚岩沈沉
Owner HARBIN UNIV OF SCI & TECH
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