Solvent-tolerant acrylate composition and applications thereof
A technology of acrylate and composition, applied to acrylate composition and its application field, can solve the problems such as the inability to completely solve the solvent resistance performance, the intrusion of the solvent in the adhesive tape bonding interface, etc., and is suitable for large-scale production and popularization and application. , Excellent anti-aging performance, good adhesion effect
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Embodiment 1
[0026] The acrylate polymer is prepared by the following steps: put 50g of ethyl acetate into the reaction kettle, raise the temperature to 60°C, pass nitrogen gas for 10 minutes, and drop the mixed monomer solution. The mixed monomer solution is: soft monomer butyl acrylate 50g, Soft monomer isooctyl acrylate 26.5g, hard monomer methyl methacrylate 15g, hard monomer acrylonitrile 5g, glycidyl methacrylate 3.5g, benzoyl peroxide (BPO) 0.4g, 4-6 After the hourly addition was completed, 50 g of ethyl acetate was added, and the reaction was continued for 4-5 hours before finishing, and diluted with 50 g of ethyl acetate to obtain an acrylate polymer with a solid content of 40%.
[0027] Preparation of solvent-resistant acrylate composition solution: take 25 g of the above acrylate polymer, add 0.25 g of phosphoric acid, mix evenly, and obtain through cross-linking reaction. The solution of the solvent-resistant acrylate composition is coated on a PET substrate and dried at 110° C...
Embodiment 2
[0029] The acrylate polymer is prepared by the following steps: put 50g of toluene / ethyl ester mixture (1:1 mass ratio) into the reaction kettle, raise the temperature to 70°C, blow nitrogen for 10 minutes, add the mixed monomer solution dropwise, mix the monomer solution For: 58.5g of isooctyl acrylate, 20g of methyl acrylate, 5g of methyl methacrylate, 9g of styrene, 1.5g of glycidyl methacrylate, 6g of acrylonitrile and 0.4g of azobisisobutyronitrile (AIBN), After 4-6 hours, add 50g of toluene / ethyl ester mixture (1:1 mass ratio), continue the reaction for 4-5 hours, and dilute with 50g of ethyl acetate to obtain acrylate pressure-sensitive adhesive with a solid content of 40%. glue.
[0030] Take 25g of the above pressure-sensitive adhesive, add 0.1g of phosphoric acid and mix well. Coating on a PET substrate and drying at 110°C for 3 minutes to obtain a chemically resistant pressure-sensitive adhesive tape.
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