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Method for preparing alumina ceramic filter plate based on aluminum ash

An alumina ceramic and filter plate technology, which is applied in chemical instruments and methods, separation methods, filtration and separation, etc., can solve the problems of high resource consumption, high production cost, and difficulty in meeting demand for ceramic filter plates, and save natural resources. , The effect of less fuel consumption and lower production costs

Active Publication Date: 2022-07-01
ZHENGZHOU JINGWEI TECH & IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a method for preparing alumina ceramic filter plates based on aluminum ash, in order to solve the problems of resource consumption and production cost of ceramic filter plates in the prior art while realizing the harmless and resourceful utilization of aluminum ash. High cost and technical problems that the output is difficult to meet the demand

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Example 1: Method for preparing alumina ceramic filter plate based on aluminum ash

[0026] Take 40 parts of aluminum ash (containing Al 5%, AlN 8%, Al 2 O 3 82%, SiO 2 0.5%, MgO 0.5%, CaO 0.5%, Fe 2 O 3 0.3%, the rest are chlorine salt and fluoride salt impurities), 60 parts of alumina (purity 99%) are mixed evenly, plus 3 parts of aluminum hydroxide binder, 1 part of aluminum fluoride, the above powder and water according to 1: Mixed with a weight ratio of 1, wet-milled to 325 mesh in a ceramic ball mill to make a slurry.

[0027] Take a 30PPI polyurethane foam board and immerse it in the above slurry. After the slurry is evenly infiltrated, take out the polyurethane foam board and squeeze out the excess slurry; let the polyurethane foam board blank soaked in the slurry naturally dry for 24 hours, and then dry at 150 °C 12h.

[0028] Then sinter at 1450°C. The specific heating system is as follows: the heating rate is 30°C / h in the 0-300°C stage, 20°C / h in the...

Embodiment 2

[0030] Example 2: Method for preparing alumina ceramic filter plate based on aluminum ash

[0031] Take 90 parts of aluminum ash (containing Al 3%, AlN 5%, Al 2 O 3 85%, SiO 2 0.3%, MgO 0.5%, CaO 0.3%, Fe 2 O 3 0.3%, the rest are chlorine salt and fluoride salt impurities), 10 parts of alumina (alumina purity 99%) are mixed evenly, plus 3 parts of aluminum hydroxide binder, 3.5 parts of aluminum fluoride, the above powder and water according to Mixed in a ratio of 4:1, wet-milled to 325 mesh with a ceramic ball mill to make a slurry.

[0032] Take a 40PPI polyurethane foam board and immerse it in the above slurry; after the slurry is evenly saturated, take out the polyurethane foam board and squeeze out the excess slurry; air the polyurethane foam board blank with the slurry naturally for 24 hours, and then dry it at 150 ℃ for 12 hours .

[0033] Then sinter at 1550°C, the specific heating curve is: 0-300°C, 30°C / h, 300-550°C, 20°C / h, 550-1000°C, 5°C / h, oxygen content ...

Embodiment 3

[0035] Example 3: Method for preparing alumina ceramic filter plate based on aluminum ash

[0036] Take 50 parts of aluminum ash (including Al 4%, AlN 9%, Al 2 O 3 81%, SiO 2 0.3%, MgO 0.5%, CaO 0.3%, Fe 2 O 3 0.3%, the rest are chlorine salt and fluoride salt impurities), 50 parts of alumina (alumina purity ≥ 99%) are mixed evenly, plus 5 parts of aluminum hydroxide binder, 2.5 parts of aluminum fluoride, the above powder and water Mixed according to the ratio of 3:2, wet-milled to 325 mesh with a ceramic ball mill to make slurry;

[0037] Take a polyurethane foam board with a density of 60 PPI and immerse it in the above slurry; after the slurry is evenly infiltrated, take out the polyurethane foam board and squeeze out the excess slurry;

[0038] Dry the polyurethane foam board blank with the slurry naturally for 24 hours, and then dry it at 150°C for 12 hours;

[0039] Then sinter at 1650°C, the specific heating steps are: 0-300°C, 30°C / h, 300-550°C, 20°C / h, 550-1...

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Abstract

The invention relates to a method for preparing an alumina ceramic filter plate based on aluminum ash; the method mainly uses 40-90% of aluminum ash and 10-60% of alumina powder as main materials, and a binder (weight of the main material) 1-5%) and impurity remover (0.5-5% by weight of aluminum ash) as auxiliary materials, and wet grinding and pulping the powder and water according to the weight ratio of 1-5:1; The above slurry is made into blanks; after drying and drying, oxygen-rich sintering; the obtained alumina ceramic filter plate has a porosity of ≥85%, a content of α alumina phase ≥85%, and thermal shock resistance ≥5 times; the method of the present invention makes full use of The aluminum component in aluminum ash realizes the harmless and resource utilization of aluminum ash, saves natural resources and reduces production costs (metal aluminum burns, releases a lot of heat, and consumes less fuel during the preparation process; aluminum ash raw material prices much lower than the price of bauxite or alumina).

Description

technical field [0001] The invention relates to the technical field of filter material preparation, in particular to a method for preparing an alumina ceramic filter plate based on aluminum ash. Background technique [0002] Aluminum ash is a waste produced in the production process of the aluminum industry. The main components are elemental aluminum, aluminum compounds, silicon oxide, magnesium oxide, sodium salt, potassium salt, fluoride salt, titanium oxide, etc., which are toxic and flammable. The scum produced on the melt surface during the melt transfer, purification and impurity removal process of electrolytic aluminum process, the scum (salt slag and aluminum ash) produced on the melt surface during the melt transfer, purification and impurity removal process of waste aluminum smelting, molten salt method The salt slag and secondary aluminum ash produced in the process of recycling metal aluminum from aluminum ash and aluminum slag are listed in the 2019 edition of t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D39/20
CPCB01D39/2068B01D2239/10B01D2239/1208B01D2239/1291
Inventor 王玉于长军冯晓强牛文军乔继才
Owner ZHENGZHOU JINGWEI TECH & IND