A photocatalytic apatite encapsulation technology special anti-virus spray
A technology for catalyzing apatite and catalysts, which is applied in the direction of catalyst activation/preparation, physical/chemical process catalysts, biocides, etc., which can solve the problems of restricting the disinfection efficiency of killing viruses and low quantum utilization rate, and achieve high-efficiency antibacterial effect, Good heat resistance and good antibacterial effect
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Embodiment 1
[0031] A photocatalytic apatite encapsulation technology special virus-killing spray, including virus-killing active ingredients and a solvent, the virus-killing active ingredients being apatite-nano-titanium dioxide composite photocatalyst, the apatite-nano-titanium dioxide The composite photocatalyst has a two-layer coating structure: the core core of the innermost layer is a nano-titanium dioxide core ball, and the nano-titanium dioxide core ball is coated with a hydroxyapatite shell layer.
[0032] The nano titanium dioxide core ball is a MOFs-nano titanium dioxide composite core ball. MOFs (metal organic framework compounds, English name Metal organic Frameworks) are new porous nanostructures connected by organic ligands and metal cations or clusters, with high specific surface area, high porosity and well-dispersed active centers.
[0033]The MOFs are platinum-silver bimetallic organic framework compounds, combined with the synergistic catalytic effect of platinum-silver...
Embodiment 2
[0039] A photocatalytic apatite encapsulation technology special virus-killing spray, including virus-killing active ingredients and a solvent, the virus-killing active ingredients being apatite-nano-titanium dioxide composite photocatalyst, the apatite-nano-titanium dioxide The composite photocatalyst has a two-layer coating structure: the core core of the innermost layer is a nano-titanium dioxide core ball, and the nano-titanium dioxide core ball is coated with a hydroxyapatite shell layer.
[0040] The nano titanium dioxide core ball is a MOFs-nano titanium dioxide composite core ball. MOFs (metal organic framework compounds, English name Metal organic Frameworks) are new porous nanostructures connected by organic ligands and metal cations or clusters, with high specific surface area, high porosity and well-dispersed active centers.
[0041] The MOFs are platinum-silver bimetallic organic framework compounds, combined with the synergistic catalytic effect of platinum-silve...
Embodiment 3
[0050] The preparation method of the apatite-nano titanium dioxide composite photocatalyst described in embodiment 2 may further comprise the steps:
[0051] (1) Preparation of platinum-silver bimetallic organic framework compound: react platinum nitrate, silver nitrate and pyromellitic acid at room temperature, centrifuge, wash, dry and calcinate to obtain the platinum-silver bimetallic organic framework compound ;
[0052] (2) Preparation of MOFs-nano-titanium dioxide composite core ball: the platinum-silver bimetallic organic framework compound is made into a solution, and then nano-titanium dioxide is added to the solution, dispersed by microwave, centrifuged, washed, dried, and calcined to obtain the MOFs- Nano titanium dioxide composite core ball;
[0053] (3) The synthesized MOFs-nano-titanium dioxide composite core ball is first coated with Ca(OH)2 to obtain an intermediate product, and then the intermediate product is directly phosphated to convert the Ca(OH)2 shell ...
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