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A kind of black carbon aerosol generator

An aerosol generator and generator technology, applied in aerosol preparation, colloid chemistry, colloid chemistry and other directions, can solve the problems of affecting secondary organic aerosols, inability to meet, flame instability, etc., and achieve concentration and particle size distribution. The effect of maintaining stability, preventing unstable airflow supply, and preventing flow fluctuations

Active Publication Date: 2021-11-12
BEIHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The flame produced by the premix burner is unstable, resulting in an unstable black carbon aerosol
The flame produced by the inverted burner is relatively stable, but in the case of poor flow control or unreasonable structural design, the flame is also unstable
[0004] Because the gas burner produces black carbon aerosol, it will also produce a large amount of organic aerosol attached to the surface of black carbon aerosol, which will seriously affect the measurement of black carbon aerosol particle size, optical properties, etc., and will also produce carbon monoxide, nitrogen, etc. Oxides, volatile organic compounds, etc., affect the generation of secondary organic aerosols
Although the black carbon aerosol produced by the gas burner can remove the organic matter attached to its surface after passing through the heat diffuser, it cannot be completely removed, even at a higher temperature, and the temperature is too high will cause carbonization and black carbon gas Sol oxidation
In addition, heat diffusers are generally used to process aerosol samples with small gas flow rates (generally less than 1L min-1), which cannot meet the requirements of subsequent simultaneous measurement of larger gas flow rates by multiple instruments

Method used

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  • A kind of black carbon aerosol generator
  • A kind of black carbon aerosol generator
  • A kind of black carbon aerosol generator

Examples

Experimental program
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Effect test

Embodiment 1

[0039] Such as figure 1 As shown, the black carbon aerosol generator of this embodiment includes a gas supply system, a combustion system, a dilution system, a catalytic oxidation device and a fixing frame.

[0040]The gas supply system includes a first gas supply pipe 1-1 for supplying fuel gas and a second gas supply pipe 1-2 for supplying combustion-supporting gas. The first gas supply pipe 1-1 is provided with a mass flow controller 1-3, and the second gas supply pipe 1-2 is provided with a mass flow controller 1-4. In particular, a flashback arrestor 1-5 is provided on the first air supply pipe 1-1. When the gas pressure in the gas supply pipe decreases, the fire in the combustion head will spread to the direction of the gas source through the pipe, which is called backfire. The backfire arrestor 1-5 can prevent and block the backfire to avoid accidents.

[0041] The combustion system includes a boss structure 2-1, an annular distribution orifice plate 2-2, a quartz tu...

Embodiment 2

[0050] In this embodiment, the stability of the black carbon aerosol particle size distribution spectrum produced in Example 1 is continuously monitored. Burning Equivalent Ratio As an example, the results of 10 consecutive scans (about 60 min) of the black carbon aerosol processed by the catalytic oxidizer 5-1 are as follows: figure 2 As shown, the concentration deviation of the total number of particulate matter produced by combustion is 2.78%, and the concentration deviation of the peak particle size is less than 10%, indicating that the generated black carbon aerosol has good stability and can be used as a stable source of black carbon aerosol for follow-up research.

Embodiment 3

[0052] This embodiment measures the content of organic matter in the black carbon aerosol generated in Example 1. In this embodiment, the black carbon aerosol produced by the black carbon generator is treated by catalytic oxidation generator 5-1 at 280°C, and compared with the black carbon aerosol collected without treatment, the test results are as follows image 3 As shown, the total carbon (Total Carbon) in the figure is the sum of OC (organic substance) and EC (elemental carbon). From image 3 can be found when In the range of 0.8 to 1.3, the black carbon aerosol without catalytic oxidation generator 5-1 still contains a relatively large proportion of organic matter, and the proportion of organic carbon to the total carbon is in the range of 17% to 25%; The organic carbon in the black carbon aerosol treated by device 5-1 is greatly reduced, and the proportion of organic carbon to the total carbon is about 3%, that is, the proportion of elemental carbon is as high as 97%...

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Abstract

The invention belongs to the field of environmental monitoring, in particular to a black carbon aerosol generator, comprising a gas supply system, a combustion system, a dilution system, a catalytic oxidation device and a fixing frame; the gas supply system includes a first Air supply pipe and a second air supply pipe for supplying combustion-supporting gas; the combustion system includes an air intake device, a combustion chamber, a combustion head and an ignition hole; the dilution system includes a third air supply pipe for supplying dilution gas, a dilution chamber , a sampling port and a heat preservation device; the catalytic oxidation device includes a catalytic oxidizer and a heating device, the sampling port is connected to the inlet end of the catalytic oxidizer through a pipeline, and an exhaust port is arranged on the pipeline; a gas supply system, a combustion system and a dilution system It is fixedly installed on the fixed frame, so that the generator is in a vertical and stable state. The generator can produce stable and pure black carbon aerosols with different particle sizes and concentration ranges, and can generate a large flow rate to meet the subsequent simultaneous measurement of multiple instruments.

Description

technical field [0001] The invention belongs to the field of environmental monitoring, in particular to a black carbon aerosol generator, in particular to a black carbon aerosol generator based on an inverted co-flow diffusion flame combustion, which has the function of generating black carbon aerosols of different sizes and concentrations . Background technique [0002] Black carbon is an important component of atmospheric aerosols, which has an important impact on human health, local visibility reduction, regional haze and global climate change. Among them, the climate effect of black carbon aerosols has received special attention internationally in recent years. Make it one of the global research hotspots. [0003] Gas burners are often used to generate black carbon aerosols for aerosol research for different purposes, such as black carbon aerosol morphology research, aerosol optical performance research, instrument calibration, etc. At present, gas burners can be divid...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J13/00
CPCB01J13/0095
Inventor 李兴华郭太伦肖茂栋阮兵
Owner BEIHANG UNIV
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