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A kind of aluminum alloy profile quenching additive and quenching process

A technology of aluminum alloy profiles and additives, applied in the field of quenching fluid, can solve the problems of high toxicity of diisobutyl ketone, blackening of quenching agent, strong irritation, etc., to ensure quality consistency, reduce maintenance times, and excellent flame retardant performance. Effect

Active Publication Date: 2022-07-29
ANHUI LANT ALUMINUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PAG is not a perfect quenching agent. After all, the quenching of the workpiece is an ultra-high temperature process. Although the PAG polymer itself is relatively stable, it will hardly be oxidized and decomposed under normal conditions, and will not react with acid-base substances. It is neutral itself, but during use, due to the adhesion of PAG on the surface of the workpiece, it will be taken out. On the other hand, there are PAG, air and ultra-high temperature workpieces at the interface of the workpiece contacting the quenching agent. These three Under these conditions, complex reactions will occur on the surface, and PAG will be oxidized and decomposed, especially when the workpiece is large, the loss of PAG will be more, and the oxidized PAG will cause the quenching agent to turn black, and it will become a foul smell after a long time
[0006] The prior art has improved PAG. For example, 201110334830.4 discloses the addition of stabilizers containing polysiloxane solution, diisobutyl ketone, alkenyl succinic acid-zinc naphthenate, barium sulfonate, polyethylene glycol, etc., mainly It involves the performance of the workpiece, but the patent does not involve the state of PAG itself, and the diisobutyl ketone used is highly toxic, volatile, and strongly irritating to the eyes and nose. Repeated contact will cause nausea, dizziness, and liver and kidney damage. damage
Dalian Sairui Metal Products has published a series of patent applications, adding various components to the quenching liquid, such as preservatives, defoamers, fungicides, rust inhibitors, etc., but did not pay attention to the service life of the quenching liquid
In addition, CN105132642 also discloses a function recovery agent for quenching liquid, which uses triethanolamine, monoethanolamine, N, N'-methylenedimorpholine, triazine, boric acid and other substances. On the one hand, the composition of the recovery agent is complex and large It is an organic small molecular compound. On the other hand, the patent does not test whether the quenching agent can maintain the original performance after the recovery agent is used.

Method used

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  • A kind of aluminum alloy profile quenching additive and quenching process
  • A kind of aluminum alloy profile quenching additive and quenching process
  • A kind of aluminum alloy profile quenching additive and quenching process

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1D

[0022] Example 1 Synthesis of DOPO Derivatives

[0023]

[0024] Add 0.12mol DOPO, 0.1mol N,N,N-trimethyl-p-vinylbenzylammonium chloride (structure above), 1L dichloromethane to the reaction kettle, stir and reflux for 2h, after the reaction is completed, concentrate the reaction liquid, 650 ml of dichloromethane were evaporated, crystallized by cooling, filtered, and dried in vacuo to obtain a white solid with a yield of 98% and a HPLC purity of 99.2%. 1 H-NMR (D-CCl 3 , ppm): 7.42(m, 1H), 7.2~7.3(m, 4H), 7.11(s, 1H), 7.06(m, 2H), 6.98(m, 2H), 6.8~6.9(m, 2H), 5.2 (m, 2H), 3.13 (m, 9H), 2.9 (m, 2H), 1.6 (m, 2H).

Embodiment 2

[0026] Based on 100 parts by weight of the whole quenching agent, 15 parts by weight of PAG stock solution and 85 parts by weight of deionized water were prepared. The use of the quenching liquid in the company's production line: the outlet temperature of the profile is controlled at 550 ℃, and 2 tons of aluminum alloy profiles are processed continuously. The surface of the profile begins to show changes such as bending and streaks, and the quenching liquid turns black and has peculiar smell. Flavor is produced.

Embodiment 3

[0028] Based on 100 parts by weight of the quenching agent as a whole, configure 15 parts by weight of PAG stock solution, 8 parts by weight of quenching additives, and 77 parts by weight of deionized water;

[0029] Wherein, based on 100 parts by weight of the quenching additive, 40 parts by weight of polydimethylsiloxane, 30 parts by weight of benzalkonium chloride, and 30 parts by weight of DOPO derivatives shown in the examples;

[0030] The use of the quenching liquid in the company's production line: the outlet temperature of the profile is controlled at 550 ℃, and 9 tons of aluminum alloy profiles are processed continuously. Slightly dark, no peculiar smell, and no peculiar smell after 2 weeks; PAG, water and additives are supplemented to the initial value, and the profile can be discharged stably.

[0031] Example 3

[0032] Based on 100 parts by weight of the quenching agent as a whole, configure 20 parts by weight of PAG stock solution, 8 parts by weight of quenchin...

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PUM

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Abstract

In order to solve the problems existing in the prior art, the present invention proposes a quenching process for aluminum alloy profiles, mainly by using a specific quenching agent additive to at least make the quenching agent not easy to turn black and smelly, the service cycle is long, the maintenance times are reduced, and the Product quality consistency.

Description

technical field [0001] The invention belongs to the technical field of quenching liquid, and in particular relates to a related quenching process using a quenching agent additive. Background technique [0002] Quenching agent is a cooling medium used in the quenching stage of metal materials or alloys, especially aluminum alloy materials in the production process; commonly used quenching media include water, oil, molten salts, air, etc. The scope of application of oil quenching agents is relatively special. For aluminum alloys, when dealing with large workpieces, thick smoke billows during quenching, accompanied by violent combustion, resulting in numerous fires every year, huge losses, and a pungent odor, causing Serious environmental pollution; for aluminum alloys, the surface is not easy to clean and easily polluted, which affects the aesthetics of the finished product and requires additional cleaning steps. The corresponding water-based quenching agent is the most widel...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07F9/6574C21D1/60
CPCC21D1/60
Inventor 雷忠平熊茂清张雄孙建
Owner ANHUI LANT ALUMINUM
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