Graphene natural rubber mountaineering shoe sole composite foaming material and preparation method thereof

A technology of natural rubber and composite foaming, which is used in shoe soles, footwear, clothing, etc., and can solve the problems of poor wear resistance, poor mechanical properties, and low foaming degree.

Inactive Publication Date: 2021-09-14
FUJIAN WUCHIHENG TECH DEV CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] 1. The wear resistance is poor. When used as a climbing shoe sole material, it is easy to wear and tear, resulting in damage and poor durability;
[0008] 2. After foaming, the tensile strength is greatly reduced, the mechanical properties are poor, and the comprehensive performance is poor; or the degree of foaming is low, and it does not have good portability;
[0009] 3. Poor anti-slip effect

Method used

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  • Graphene natural rubber mountaineering shoe sole composite foaming material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] A kind of graphene natural rubber mountaineering sole composite foaming material, comprises the raw material of following weight part:

[0046]60-70 parts of natural rubber, 12-18 parts of butadiene rubber, 13-17 parts of EPDM rubber, 4-6 parts of white carbon black, 1.6-2.0 parts of graphene, 1.4-1.7 parts of zinc oxide, heat stabilizer 3-4 parts, 1.8-2.2 parts of cross-linking agent, 3.5-5 parts of flow aid, 2-2.6 parts of foaming agent.

[0047] In the present embodiment, described graphene natural rubber mountaineering shoe sole composite foaming material comprises the raw material of following weight portion:

[0048] 65 parts of natural rubber, 15 parts of butadiene rubber, 16 parts of EPDM rubber, 5 parts of white carbon black, 1.8 parts of graphene, 1.55 parts of zinc oxide, 3.5 parts of heat stabilizer, 2 parts of crosslinking agent, flow aid 4.3 parts, foaming agent 2.3 parts.

[0049] In the present embodiment, described graphene natural rubber mountaineeri...

Embodiment 2

[0065] A kind of graphene natural rubber mountaineering sole composite foaming material, comprises the raw material of following weight part:

[0066] 60 parts of natural rubber, 12 parts of butadiene rubber, 13 parts of EPDM rubber, 4 parts of white carbon black, 1.6 parts of graphene, 1.4 parts of zinc oxide, 3 parts of heat stabilizer, 1.8 parts of crosslinking agent, flow aid 3.5 parts, foaming agent 2 parts.

[0067] In the present embodiment, described graphene natural rubber mountaineering shoe sole composite foaming material also includes the raw material of following weight portion:

[0068] 6 parts of phenylene ether silicone rubber.

[0069] In this embodiment, the flow aid is a mixture of polyethylene oxide and ethylene bisstearamide.

[0070] In this embodiment, the mass ratio of oxidized polyethylene to ethylene bis-stearamide in the mixture of oxidized polyethylene and ethylene bis-stearamide is 1:0.25.

[0071] In this embodiment, the crosslinking agent is a...

Embodiment 3

[0083] A kind of graphene natural rubber mountaineering sole composite foaming material, comprises the raw material of following weight part:

[0084] 70 parts of natural rubber, 18 parts of butadiene rubber, 17 parts of EPDM rubber, 6 parts of white carbon black, 2.0 parts of graphene, 1.7 parts of zinc oxide, 4 parts of heat stabilizer, 2.2 parts of crosslinking agent, flow aid 5 parts, foaming agent 2.6 parts.

[0085] In the present embodiment, described graphene natural rubber mountaineering shoe sole composite foaming material also includes the raw material of following weight portion:

[0086] 8 parts of phenylene ether silicone rubber.

[0087] In this embodiment, the flow aid is a mixture of polyethylene oxide and ethylene bisstearamide.

[0088] In this embodiment, the mass ratio of oxidized polyethylene to ethylene bis-stearamide in the mixture of oxidized polyethylene and ethylene bis-stearamide is 1:0.32.

[0089] In this embodiment, the crosslinking agent is a...

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Abstract

The invention discloses a graphene natural rubber mountaineering shoe sole composite foaming material and a preparation method thereof. The graphene natural rubber mountaineering shoe sole composite foaming material comprises the following raw materials in parts by weight: 60 to 70 parts of natural rubber, 12 to 18 parts of butadiene rubber, 13 to 17 parts of ethylene propylene diene monomer, 4 to 6 parts of white carbon black, 1.6 to 2.0 parts of graphene, 1.4 to 1.7 parts of zinc oxide, 3 to 4 parts of a heat stabilizer, 1.8 to 2.2 parts of a cross-linking agent, 3.5 to 5 parts of a flow promoter and 2 to 2.6 parts of a foaming agent. The graphene natural rubber mountaineering shoe sole composite foaming material is low in density and ultralight; the wear-resisting property is excellent, the tensile strength is high, the mechanical property is good, and the durability is good; and in addition, the non-slip coefficient (dry type non-slip and wet type non-slip) is high, and the non-slip effect is good.

Description

[0001] The present invention is a divisional application of an invention patent application with the application number 202010039700.7, the application date is January 15, 2020, and the title is "Graphene Natural Rubber Polymer Mountaineering Shoe Sole Composite Foaming Material and Its Preparation Method". technical field [0002] The invention relates to the technical field of polymer composite foaming materials, in particular to a graphene natural rubber mountaineering shoe sole composite foaming material and a preparation method thereof. Background technique [0003] Present various soles are mostly made of EVA or rubber material, and the cost is relatively controllable, and properties such as elasticity and hardness can be adjusted as required, which has basically met people's requirements. [0004] Natural rubber is the variety with the best coordination of physical and mechanical properties and process performance among rubber materials. It has been widely used in dail...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08L9/00C08L23/16C08L23/30C08L83/06C08K13/04C08K7/26C08K3/22C08K5/20C08K3/06C08K5/098C08K3/04C08J9/10A43B13/04A43B13/18A43B5/00A43B13/22
CPCC08J9/103C08J9/0061C08J9/0066C08J9/0028C08J9/0095A43B13/04A43B13/187A43B5/002A43B13/22C08J2307/00C08J2409/00C08J2423/16C08J2423/30C08J2483/06C08J2203/04
Inventor 丁天宁丁德材丁幼丝
Owner FUJIAN WUCHIHENG TECH DEV CO LTD
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