Water quality fluoride detection method based on digital image colorimetric analysis

A technology of colorimetric analysis and digital image, which is applied in the direction of analyzing materials, analyzing materials through optical means, and analyzing materials through chemical reactions. On-line detection of fluoride, susceptibility to the influence of water sample pH and impurities, etc., to reduce low image brightness, improve image clarity, and low cost

CN113945556APending Publication Date: 2022-01-18ZHEJIANG UNIV OF TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2022-01-18

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Abstract

The invention discloses a water quality fluoride detection method based on digital image colorimetric analysis. The xylenol orange zirconium system is used for replacing a fluorine reagent in a national standard method, and the method has the advantages of being few in used reagent, low in cost, rapid in color development, high in sensitivity, good in stability and the like; according to the invention, MSRCR image enhancement is carried out on a digital image acquired based on a CCD industrial camera, so that the influence of low image brightness can be effectively reduced; according to the method, multi-dimensional color feature extraction is utilized, the Lab color first moment is utilized, color space distribution and pixels can be considered, image information can be better reflected, and the robustness of the established multiple linear regression quantitative analysis model is higher. The method has the advantages of wide detection range, convenience in operation, higher accuracy and precision, simple image acquisition equipment, easiness in carrying and convenience in field measurement.
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Description

technical field

[0001] The invention relates to the technical field of fluoride detection in water quality, in particular to a water quality fluoride detection method based on digital image colorimetric analysis. Background technique

[0002] Fluorine is a non-metallic chemical element ubiquitous in the environment, widely present in soil, rocks and water in nature. As one of the 14 kinds of trace elements necessary for the human body, it is an indispensable and important part of bones and teeth. In daily life, people obtain fluorine through drinking water and food, and 65% of the fluorine contained in the human body is obtained through drinking water. Insufficient absorption of fluoride by the human body is one of the factors leading to dental caries, but excessive absorption, fluorosis, will cause great harm to the human body. Typical symptoms are dental fluorosis and bone fluorosis. Therefore, the detection of fluoride in natural water has important practical significan...

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Embodiment Construction

[0055] In order to make the public have a thorough understanding of the present invention, the present invention will be described in detail below in conjunction with the drawings and specific embodiments, but it should not be construed as a limitation of the present invention. The present invention covers any alternatives, modifications, equivalent methods and schemes made on the spirit and scope of the present invention, and those skilled in the art can fully understand the present invention without description of these details. The reagents and materials used in the following examples can all be obtained from commercial sources.

[0056] Image acquisition devices based on CCD industrial cameras such as figure 1 As shown, the device includes a cover plate 1 and a box body 2 that are 3D printed using black PLA material to form a closed sampling space that is not affected by external light sources. The inside of the box body 2 is provided with a cuvette holder 3, a Stabilized...