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Nitrogen-containing heterocyclic compound and application thereof

A compound and nitrogen heterocyclic technology, applied in the field of organic electroluminescence, can solve the problems of device performance and life expectancy, and achieve the effect of increasing the conjugated system, improving stability, and stabilizing the structure

Pending Publication Date: 2022-06-21
GUANGZHOU CHINARAY OPTOELECTRONICS MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented chemicals are useful for improving organic electroluminescent devices (OEL) by increasing their brightness or lifespan without losing effectiveness over longer periods due to decreased degradation caused by environmental factors such as oxygen exposure. These new materials have improved performance compared with existing ones while maintaining an attractive appearance on display screens like LCD displays.

Problems solved by technology

This patented technical problem addressed in this patents relates to finding better ways to use different types of molecules or substances that can enhance the emission process inside OLEDS while maintaining its superior quality and lifespan.

Method used

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  • Nitrogen-containing heterocyclic compound and application thereof
  • Nitrogen-containing heterocyclic compound and application thereof
  • Nitrogen-containing heterocyclic compound and application thereof

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specific embodiment

[0127] 1. Synthesis of compounds

[0128] Synthetic Example 1: Synthetic Organic Compound (1)

[0129]

[0130] Synthetic intermediate (1-a):

[0131] Put o-bromofluorobenzene (1.5eq), 1-fluorocarbazole (1eq), and potassium tert-butoxide (5eq) into a single-necked bottle, add 250mL of DMF, and react at 120°C for 8 hours. After the reaction solution was evaporated to dryness in vacuo, it was washed with dichloromethane, and the incompletely dissolved solid was filtered off. The filtrate was spin-dried and separated and purified by silica gel chromatography to obtain white solid intermediate (1-a) with a yield of 89%.

[0132] Synthetic intermediate (1-b):

[0133] Place diboronic acid pinacol ester (1.5eq), intermediate (1-a) (1eq), Pd(dppf) in a dry two-necked flask 2 Cl 2 (0.05eq), potassium acetate (4eq), and then add 250mL of a mixed solution of dioxane and water at a ratio of 3:1, stir and react at 90°C for 12 hours, cool to room temperature, ...

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Abstract

The invention discloses a nitrogen-containing heterocyclic ring compound and application thereof. The nitrogen-containing heterocyclic ring compound has a structure as shown in a general formula (1). When the material is used in an OLED, especially as a main body material of a light-emitting layer, the external quantum efficiency of a device can be improved, and the service life of the device can be prolonged. Meanwhile, the compound disclosed by the invention not only has a relatively stable eight-membered ring-containing structure, but also has a relatively large ring-shaped structure, so that a conjugated system can be increased, the structure is more stable, the stability of a device can be improved, and meanwhile, the starting voltage is reduced, so that the service life of the device is prolonged.

Description

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Claims

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Application Information

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Owner GUANGZHOU CHINARAY OPTOELECTRONICS MATERIALS
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