Nitrogen-containing heterocyclic compound and application thereof
A compound and nitrogen heterocyclic technology, applied in the field of organic electroluminescence, can solve the problems of device performance and life expectancy, and achieve the effect of increasing the conjugated system, improving stability, and stabilizing the structure
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[0127] 1. Synthesis of compounds
[0128] Synthetic Example 1: Synthetic Organic Compound (1)
[0129]
[0130] Synthetic intermediate (1-a):
[0131] Put o-bromofluorobenzene (1.5eq), 1-fluorocarbazole (1eq), and potassium tert-butoxide (5eq) into a single-necked bottle, add 250mL of DMF, and react at 120°C for 8 hours. After the reaction solution was evaporated to dryness in vacuo, it was washed with dichloromethane, and the incompletely dissolved solid was filtered off. The filtrate was spin-dried and separated and purified by silica gel chromatography to obtain white solid intermediate (1-a) with a yield of 89%.
[0132] Synthetic intermediate (1-b):
[0133] Place diboronic acid pinacol ester (1.5eq), intermediate (1-a) (1eq), Pd(dppf) in a dry two-necked flask 2 Cl 2 (0.05eq), potassium acetate (4eq), and then add 250mL of a mixed solution of dioxane and water at a ratio of 3:1, stir and react at 90°C for 12 hours, cool to room temperature, ...
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