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Ceramic catalyst

A ceramic catalyst and catalyst technology, applied in the direction of catalyst carrier, catalyst activation/preparation, physical/chemical process catalyst, etc., can solve the problems of pressure loss increase, performance degradation, distance increase, etc., to achieve pressure loss reduction, prevent increase, Effect of preventing pressure loss

Inactive Publication Date: 2004-03-10
DENSO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the amount of co-catalyst components increases, the distance between these components and the noble metal catalyst on the support surface increases, thereby causing a problem of performance degradation
In addition, as a result of the increasing thickness of the promoter layer formed on the cell wall surface, the pressure loss increases

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] Ceramic bodies were prepared in the following manner to demonstrate the effects of the present invention. First, talc, kaolin, alumina, and aluminum hydroxide were used as raw materials for cordierite, and the raw materials were formulated to approach the theoretical composition of cordierite by substituting W for 5% of the Si source and Co for 5% of the Si source. Then binders, lubricants, humectants and moisture are added to the raw material in an appropriate amount, and then kneaded to form a cell wall thickness of 100 μm, a cell density of 400 cpsi (number of cells per square inch), and a diameter of 50 mm. Honeycomb shape. The formed dense honeycomb body was calcined at 1260° C. in air to obtain a direct-loaded ceramic carrier composed of a cordierite honeycomb structure.

[0053] In order to load the main catalyst component of the precious metal catalyst form on the direct loading type ceramic carrier obtained in the above-mentioned manner, the ceramic carrier is...

Embodiment 2-9

[0064] Ceramic catalyst bodies were prepared in the same manner as in Example 1, except that the types of oxygen storage components used as co-catalyst components were changed, as shown in Table 1, and slurries in which particles of these co-catalyst components were dispersed were used. The thickness of the co-catalyst layer, the amount of the co-catalyst component on the inner surface of the pores, the pressure loss and the purification performance were measured in the same manner as in Example 1. These results are also shown in Table 1.

Embodiment 10

[0066] A ceramic catalyst body was prepared in the same manner as in Example 1, except that for the cocatalyst component ceria / zirconia solid solution particles containing solid-solubilized W therein, a particle containing W's slurry of ceria / zirconia solid solution particles, and make the loading amount 20g / L. The thickness of the co-catalyst layer, the amount of the co-catalyst component on the inner surface of the pores, the pressure loss and the purification performance were measured in the same manner as in Example 1. These results are also shown in Table 1.

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Abstract

An automotive catalytic converter has a primary catalytic component, and a co-catalytic component which facilitates the application of the primary component to a ceramic substrate. The substrate surface structure has a large number of open pores into which the catalytic components are placed. 50% or more, e.g. 70% or more, of the co-catalytic component is applied to the inner surfaces of the open pores. The primary catalytic component is a catalytic noble metal. The co-catalytic component is a compound incorporating oxygen. the ceramic substrate is a honeycomb ceramic material.

Description

technical field [0001] The present invention relates to a ceramic catalyst body preferably used, for example, as a catalyst for purifying exhaust gas of an automobile engine. Background technique [0002] A typical three-way catalyst used as a catalyst for purifying exhaust gas generally has a structure in which a coating of γ-alumina, etc. is formed on the surface of a ceramic carrier composed of a cordierite honeycomb structure with high thermal shock resistance, and then a noble metal catalyst is supported . However, problems such as increased heat capacity and increased pressure loss occurred due to the formation of the coating, so studies were conducted on the catalyst support without the formation of the coating. Although Japanese Examined Patent Publication No. 5-50338 describes a method of increasing the specific surface area of ​​cordierite itself by heat treatment after acid treatment, the destruction of the crystal lattice of cordierite by a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F01N3/10B01D53/86B01D53/94B01J23/63B01J32/00B01J35/04B01J35/10B01J37/02C04B41/85F01N3/28
CPCB01J35/04B01J23/63B01J37/0203B01J37/0211Y10S502/524B01J37/0217B01D53/945Y10S502/525Y02T10/22Y02T10/12
Inventor 长谷智实中西友彦植野秀章新吉隆利
Owner DENSO CORP