Transparent gas barrier laminated film, and electroluminescent light-emitting element, electroluminescent display device, and electrophoretic display panel using the same
A technology for electroluminescent elements and laminated films, which can be applied to electrical components, household components, electric solid-state devices, etc., and can solve the problems of unusable laminated films and opaque films.
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[0123] As a substrate, a 12 micron thick biaxially oriented PET film was prepared. This PET film was placed in an electron beam heating type vacuum deposition apparatus, metallic aluminum was evaporated, and oxygen gas was supplied to deposit a 15 nm thick aluminum oxide layer on one surface of the PET film.
[0124] The following coating agents were then prepared.
[0125] Preparation of coating agent
[0126] First, 89.6 g of hydrochloric acid (0.1 N) was added to 10.4 g of tetraethoxysilane, and the mixture was hydrolyzed for 30 minutes with stirring, thereby preparing a hydrolyzed solution having a solid content of 3% by weight in terms of silica, This solution was used as the first solution.
[0127] Then, as a second solution, a 97% by weight aqueous solution of isopropanol (wherein the weight ratio of water and isopropanol is 90:10) and 3% by weight of polyvinyl alcohol were mixed.
[0128] The first solution and the second solution were mixed at a weight mixing rati...
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