Porous aluminum body and manufacturing method therefor

a technology of porous aluminum and manufacturing methods, which is applied in the direction of cell components, electrochemical generators, transportation and packaging, etc., can solve the problems of difficult to obtain a porous body with high porosity and difficult to perform continuous and highly efficient manufacturing as a whol

Inactive Publication Date: 2017-11-16
MITSUBISHI MATERIALS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This method enables the production of porous aluminum bodies with porosity of 70% or more in a continuous and cost-effective manner, improving performance in applications such as electrode collectors and heat exchangers.

Problems solved by technology

However, there has been a problem that when a porous body is formed of these aluminum foil and aluminum powder, it is difficult to obtain a porous body having high porosity.
However, in the above method for manufacturing an aluminum porous body, there has been a problem that since a predetermined holding time is required particularly in the step of foaming a viscous composition, it is necessary to employ a so-called batch treatment, and it is difficult to perform continuous and highly efficient manufacturing as a whole.

Method used

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  • Porous aluminum body and manufacturing method therefor
  • Porous aluminum body and manufacturing method therefor
  • Porous aluminum body and manufacturing method therefor

Examples

Experimental program
Comparison scheme
Effect test

first embodiment

[0027]FIG. 1 to FIG. 4 illustrate a first embodiment of the porous aluminum body of the present invention.

[0028]A plurality of aluminum fibers 1 are mutually connected and integrated and formed into a plate shape, thus obtaining the porous aluminum body. Here, the aluminum fibers 1 each have an average wire diameter of 40 to 300 μm (preferably 50 to 100 μm) and a length of 0.2 to 20 mm (preferably 1 to 10 mm).

[0029]Here, the aluminum fibers 1 each have, on an outer peripheral surface thereof, a plurality of columnar protrusions 2 protruding outward from the outer peripheral surface. These columnar protrusions 2 are formed at intervals in 5 to 100 places per 100 μm in length of the aluminum fibers. Further, the columnar protrusions 2 each have a smaller diameter than the aluminum fibers 1 and a length protruding outward from the outer peripheral surface of 1 to 500 μm.

[0030]Further, at least the tip part of each columnar protrusion 2 is formed of a compound including titanium and alu...

second embodiment

[0046]FIG. 5A to FIG. 5C illustrate a second embodiment of the porous aluminum body according to the present invention.

[0047]This porous aluminum body is different from that shown in the first embodiment in that, although a plurality of aluminum fibers 1 are mutually connected and integrated in the same manner as shown in the first embodiment, the porous aluminum body is formed into a bulk shape such as a columnar shape, a cylindrical shape, and a rectangular plate shape.

[0048]Here, a method for manufacturing the above porous aluminum body will be described. Also in this manufacturing method, titanium powder, titanium hydride powder, or a mixed powder thereof each having an average particle size of 1 to 50 μm (preferably 5 to 30 μm) (hereinafter generically referred to as titanium powder 3) is added to a large number of aluminum fibers 1 having an average wire diameter of 40 to 300 μm (preferably 50 to 200 μm) and a length of 0.2 to 20 mm (preferably 1 to 10 mm) followed by mixing t...

examples

[0051]A porous aluminum body was manufactured by the method for manufacturing a porous aluminum body shown in the first embodiment.

[0052]First, 5% by weight of titanium hydride (TiH2) having an average particle size of 10 μm was added to aluminum fibers having an average wire diameter of 50 μm to prepare premixed fibers, and then the premixed fibers are wet-blended with a cellulose binder followed by drying to obtain a product, which was used as premixed fibers.

[0053]Then, the premixed fibers were uniformly spread on a carbon sole plate to obtain a filled layer having a thickness of about 1 mm in the state of bulk-filling. Next, the premixed fibers on the carbon sole plate were sintered at 658° C. for 10 minutes in an argon gas atmosphere at a dew point of −65° C. or less to prepare a porous aluminum body.

[0054]FIG. 6 to FIG. 9 are each a microscope photograph of a porous aluminum body manufactured in this way.

[0055]These photographs reveal that the resulting porous aluminum body co...

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Abstract

A porous aluminum body having high porosity and a manufacturing method therefor are provided, wherein the porous aluminum body can be manufactured by continuous manufacturing steps. In the present invention, this porous aluminum body includes a plurality of aluminum fibers connected to each other. The aluminum fibers each have a plurality of columnar protrusions formed at intervals on an outer peripheral surface of the aluminum fibers, the columnar protrusions protruding outward from the outer peripheral surface. Adjacent aluminum fibers are integrated with the aluminum fibers and the columnar protrusions.

Description

TECHNICAL FIELD[0001]The present invention relates to a porous aluminum body including a large number of aluminum fibers and a manufacturing method therefor.BACKGROUND ART[0002]For example, many porous bodies made of aluminum are proposed as an electrode collector of an electric double-layer capacitor or a lithium ion battery, a filter for recovering hydrogen in a fuel cell, a refrigerant passage of a heat pipe for heat exchange, or a regenerator of a Stirling engine mechanism.[0003]Conventionally, as such a porous aluminum body, a porous body obtained by forming an aluminum foil and a porous body having a skeleton obtained by sintering aluminum powder as observed in the following Patent Literature 1 are known.[0004]However, there has been a problem that when a porous body is formed of these aluminum foil and aluminum powder, it is difficult to obtain a porous body having high porosity. On the other hand, the improvement in a porous body has been demanded because, in the above capac...

Claims

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Application Information

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Patent Type & AuthorityApplications(United States)
IPC IPC(8): B22F3/11B22F3/00H01M4/66H01G11/68H01M10/0525B22F1/00H01G11/86B22F1/05B22F1/052B22F1/062
CPCB22F3/11B22F1/0011B22F1/004B22F3/002H01M4/661H01M10/0525H01G11/68H01G11/86B22F2201/11B22F2301/052B22F2301/205B22F2304/10C22C1/08C22C21/00C22C47/14C22C49/14C22C1/0416H01M4/806H01G9/045H01G11/70Y10T428/12424Y02E60/10B22F1/052B22F1/062B22F1/05B22F3/1103Y02E60/13
InventorYANG, JI-BINHOSHINO, KOJISAIWAI, TOSHIHIKO
OwnerMITSUBISHI MATERIALS CORP