The application provides a BiOI with
iodine defects 1‑x Rod-like material, preparation method and application thereof.
Bismuth nitrate pentahydrate and 1,3,5-
benzene tricarboxylic acid are added into
methanol in proportion, and a
metal organic framework [Bi9(C9H3O6)·9(H2O)9] is synthesized by heating at 100-140 DEG C for 20-24 h; the
metal organic framework is mixed with
ammonium iodide in proportion, and then is subjected to water bath at 60-100 DEG C for 0.5-1.5 h to derive rod-like BiOI; the obtained BiOI is calcined in a
muffle furnace at 350-450 DEG C to obtain the rod-like BiOI material with
iodine defects, which is represented as BiOI 1‑x . The material has the rod-like
microstructure of the precursor [Bi9(C9H3O6)·9(H2O)9], the axial size is slightly reduced, the
diameter of the rod is about 1-2 microns, the length is about 3-8 microns, the surface is rough, and the material has a porous structure. The material can be used as a photocatalyst for degradation of
gaseous formaldehyde and liquid
tetracycline, and both have excellent degradation performance.