The invention relates to the field of
steelmaking and particularly provides
molten steel of an
atmosphere-
corrosion-resistant structural steel. The total weight of the
molten steel serves as the datum, and the
molten steel comprises 0.01%-0.09% of C, 0.15%-0.35% of Si, 0.30%-0.60% of Mn, 0.30%-0.40% of Cu, 0.20%-0.30% of Ni, 2.0%-3.5% of Cr, 0.13%-0.15% of V, 0.005%-0.030% of Ti, 0.01%-0.015% of Nb, 0.015%-0.020% of N, not greater than 0.030% of P and not greater than 0.020% of S. The invention provides the
atmosphere-
corrosion-resistant structural steel and a production method thereof. By means of
continuous casting of the molten steel, center quality of a
casting blank can be improved, center cracks and center shrinkage cavities are avoided, therefore quality of the
casting blank of the structural steel high in strength and
atmosphere-
corrosion resistance can be improved, and the qualification rate of the
casting blank can be remarkably increased; and in addition, the atmosphere-corrosion-resistant structural steel which is finally obtained is good in atmosphere-corrosion resistance and higher in strength performance.