High molecular europium ligand, its preparing process and use
A technology of europium complexes and polymers, which is applied in the field of polymer europium complexes, its preparation process and application, can solve the problems that europium complexes cannot be uniformly dispersed, and achieve the effect of improving photostability and high efficiency
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Embodiment 1
[0031] 1. Synthesis of polystyrene ligands containing 8-hydroxyquinoline at the end
[0032] Add the initiator, monomer (styrene), catalyst and solvent into the polymerization tube, and remove the oxygen in the system by continuous vacuuming and nitrogen filling, then put the polymerization tube into the oil bath and react at 90-130°C 3-10 hours. The resulting polymer was precipitated in methanol and washed with 1:1 hydrochloric acid to remove the catalyst. The polystyrene ligand containing 8-hydroxyquinoline in the terminal group can be obtained by suction filtration and vacuum drying, and its molecular weight can be adjusted by controlling the ratio of the monomer and the initiator.
[0033] The initiator used in this embodiment is 5-chloromethyl-8-hydroxyquinoline; the catalyst can be the complex of cuprous chloride and pentamethyldiethylenetriamine or 2,2'-bipyridine; the solvent is cyclic Hexanone, anisole, N, N-diformamide, etc.
[0034] 2. Synthesis of small molecule...
Embodiment 2
[0042] 1. Synthesis of polystyrene ligands containing 8-hydroxyquinoline at the end
[0043] Add the initiator, monomer (styrene), catalyst and solvent into the polymerization tube, and remove the oxygen in the system by continuous vacuuming and nitrogen filling, then put the polymerization tube into the oil bath and react at 90-130°C 3-10 hours. After reacting for a certain period of time, the obtained polymer was precipitated in methanol and washed with 1:1 hydrochloric acid to remove the catalyst. The polystyrene ligand containing 8-hydroxyquinoline in the terminal group can be obtained by suction filtration and vacuum drying, and its molecular weight can be adjusted by controlling the ratio of the monomer and the initiator.
[0044] The initiator used in this embodiment is 5-chloromethyl-8-hydroxyquinoline; the catalyst can be the complex of cuprous chloride and pentamethyldiethylenetriamine or 2,2'-bipyridine; the solvent is cyclic Hexanone, anisole, N, N-diformamide, e...
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