Inorganic coating composition regulated by pH value and its preparation method and use
An adjustment method and technology of inorganic coatings, applied in the direction of coatings, etc., can solve the problems of reduced hardness, weather resistance and heat resistance, shortening the effective use time of coatings, and short effective use time.
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Embodiment 1
[0027] Assuming the use of H with a pKa value of around 6.1 2 CO 3 (carbonic acid) to prepare a buffer solution with a pH value=6.8, then carbonic acid is based on pKa value=6.1 with H 2 CO 3 and HCO 3 - Two forms exist, here H 2 CO 3 is the conjugate acid, HCO 3 - is the conjugate base.
[0028]
[0029] Acids with the above relationship are called conjugate acids, and acid radicals are called conjugate bases. When mixing the same amount of conjugate acid (a chemical species (ion or neutral molecule) that can donate a proton to an acid group) and conjugate base (a chemical species that can accept a proton (neutral molecule or ion)), the buffer solution The pH value is the same as the pKa value. That is, H 2 CO 3 and HCO 3 - When the amount of the same, the pH value becomes 6.1 which is the same as the pKa value, and in order to prepare a buffer solution with a pH value of 6.8, there are more conjugate bases than conjugate acids. How much more can be calc...
Embodiment 2
[0035] Organic acid + alkaline metal or alkaline earth metal can be used as another buffer solution. Assuming that acetic acid and its salts are used to prepare a buffer solution with a pH value of 6.8, after preparing 100ml of acetic acid solution with a conjugate acid of 0.1M and 100ml of its salt with 0.1M sodium acetate solution, slowly set any solution as a reference solution. Pour into the remaining solution and adjust the pH to 6.8.
[0036] A solution containing both substances neutralizes the acid or acid radicals of the pigment or filler that are slowly expelled from the paint.
[0037]
[0038] If acid is added to the paint with buffer solution added, due to the added H + with CH 3 COO - react to form CH 3 COOH, so the pH of the solution remains almost constant.
[0039] CH 3 COO - +H + →CH 3 COOH
[0040] If acid radicals are added to the buffer solution, the added OH - with H 3 o + A neutralization reaction occurs to make H 3 o + decrease, so...
Embodiment 3
[0050] Put colloidal silica, colloidal alumina and organic acid into alkoxysilane, then hydrolyze, then add half of all alcohol (methanol, isopropanol, ethanol), and put fillers (inorganic antibacterial materials, Inorganic corrosion inhibitors, other fillers) and pigments are then stirred with a ball mill, sand mill, etc. to make the average particle size less than 10 μm, and then cleaned with the remaining 1 / 2 alcohol, poured into the buffer solution and stirred thoroughly so as not to produce sediment. If the average particle size is 10 μm or more, the decoration and stain resistance will be lowered, so stirring is performed when the composition is applied so as not to generate deposits.
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