Indolyl styrene salt compound, high density recording medium including said compound and its preparing method
A technology of indole styrene and recording media, applied in the field of high-density recording media, can solve the problems of short storage life of products, difficult to manufacture, and inability to share dyes.
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Embodiment 1
[0057] Take starting material (I) (R 1 =CH2-Ph-CO2-1-Naph) 3 grams of solids and 2.8 grams of sodium hexafluoroantimonate (NaSbF6) were heated to reflux in 45 milliliters of methanol, and after reacting for 48 hours, added After 1.06 grams, it was heated to reflux for 18 hours. Afterwards, the above-mentioned reaction product was filtered and dried to obtain 1.7 grams of blue-purple solid compound (3) (Y - for SbF 6 - ), after physical property analysis, it is measured that the absorption wavelength of compound (3) is 568nm (UV max =568nm), absorption coefficient (ε)=1.12×10 5 . Its UV analysis chart is shown in figure 1 .
Embodiment 2
[0059] Take starting material (I) (R 1 = ) of solid 1.3 g with 0.46 g was heated under reflux in 30 ml of ethanol for 16 hours, and then drained to obtain 2.3 g of green solid (II), and the green solid and sodium hexafluoroantimonate (NaSbF 6 ) 1.08 grams in 30 milliliters of ethanol, heated to reflux for 18 hours, filtered and dried to obtain 1.36 grams of blue-green solid compound (5) (Y - for SbF 6 - ), after physical property analysis, it is measured that the absorption wavelength of compound (5) is 567nm (UV max =567nm), absorption coefficient (ε)=1.11×10 5 . Its UV analysis chart is shown in figure 2 .
Embodiment 3
[0061] Take starting material (I) (R 1 = 4-fluorbenzyl) solid 10 g with 4.88 grams were heated under reflux in 100 milliliters of ethanol for 16 hours, after that, filtered to obtain 9.2 grams of green solid (2), and then 3.0 grams of this green solid (2) was mixed with sodium hexafluoroantimonate (NaSbF 6 ) 1.82 g in 50 ml of ethanol, heated to reflux for 18 hours, filtered and dried to obtain 3.45 g of blue solid compound (12) (Y - for SbF 6 - ), after physical property analysis, it was measured that the absorption wavelength of compound (12) was 564.5nm (UV max =564.5nm), absorption coefficient (ε)=1.18×10 5 , see its UV analysis diagram image 3 .
[0062] The indole styrene salt compound shown in Table 1 comprises an indole styrene cation and an anion (SbF 6 - or I - ), and the indole styrene salt compound can also be added to other ionic compounds in the presence of an organic solvent and heated to reflux to further replace its anion part with other anions (suc...
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