Mixed rare earth oxide, mixed rare earth fluoride, cerium-based abrasive using the materials and production processes thereof
A technology of mixing rare earths and oxides, which is applied in the field of abrasive materials and cerium-based abrasives, can solve the problems of reduced polishing rate, high combustion efficiency, and low combustion degree, and achieve small surface roughness, simple solid-state reaction, high Effect of Polishing Rate
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Embodiment 1
[0084] Preparation of mixed rare earth carbonates in which the content of all rare earth elements is 49% by mass based on oxides and the content of cerium is 60% by mass based on oxides and the content of lanthanum is The content of praseodymium is 7 mass % based on oxide, the content of neodymium is 1.5 mass % based on oxide, and the content of impurities other than rare earth elements is 1.0 mass % or less. Subsequently, 2 kg of this mixed rare earth carbonate was burned in an electric furnace at a temperature of 850° C. for 2 hours to obtain a mixed rare earth oxide.
[0085] Then, the mixed rare earth oxide was dried at a temperature of 120° C. for 2 hours, and charged into a ceramic crucible set to a constant mass. Then, by heating at a temperature of 1000° C. for 1 hour, ignition loss was measured and found to be 0.38% by mass. In addition, the crystallite diameter was calculated using X-ray diffraction detection, and as a result, the crystallite diameter was 218 Ȧ. X-...
Embodiment 2
[0101] The mixed rare earth oxide was obtained in the same manner as in Example 1, except that the combustion temperature of the mixed rare earth carbonate was changed to 1000°C. The ignition loss of the obtained mixed rare earth oxide was 0.12% by mass, and the crystallite diameter was 348 Ȧ. Using the mixed rare earth oxide, a cerium-based abrasive was obtained in the same manner as in Example 1.
[0102] Polishing was performed using the obtained cerium-based abrasive in the same manner as in Example 1, and the state of polishing was evaluated. The production conditions and results are listed in Table 1 and Table 2, respectively.
Embodiment 3
[0104] The mixed rare earth fluoride was obtained in the same manner as in Example 1, except that the heat treatment temperature of the mixed rare earth fluoride was changed to 400°C. The maximum particle diameter of the obtained mixed rare earth fluoride was 96 micrometers, and the ignition loss was 3.45% by mass. Using the mixed rare earth fluoride, a cerium-based abrasive was obtained in the same manner as in Example 1.
[0105] Polishing was performed using the obtained cerium-based abrasive in the same manner as in Example 1, and the state of polishing was evaluated. The production conditions and results are listed in Table 1 and Table 2, respectively.
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