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Mixed rare earth oxide, mixed rare earth fluoride, cerium-based abrasive using the materials and production processes thereof

A technology of mixing rare earths and oxides, which is applied in the field of abrasive materials and cerium-based abrasives, can solve the problems of reduced polishing rate, high combustion efficiency, and low combustion degree, and achieve small surface roughness, simple solid-state reaction, high Effect of Polishing Rate

Inactive Publication Date: 2007-08-01
SHOWA DENKO KK
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] However, when conventional cerium-based abrasives are used under conventional polishing conditions, the processing rate is low, but there are problems in that: the polishing rate drops sharply due to the clogging of the polishing pad; the dressing of the polishing pad or the exchange of the polishing slurry must be frequently performed ; and productivity has seriously deteriorated
However, in processes using this raw material, carbonic acid is lost as a gas during final combustion in the process of producing cerium-based abrasives
Therefore, this method cannot ensure low material cost and high combustion efficiency
In addition, if the degree of combustion of the framework rare earth oxide is low, the finally obtained cerium-based abrasive grains become uneven in hardness, which causes problems such as scratches on polished glass surfaces or very short polishing rates. decrease in time
In particular, in the case of hard glass surfaces, a sharp decrease in polishing rate is fatal

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0084] Preparation of mixed rare earth carbonates in which the content of all rare earth elements is 49% by mass based on oxides and the content of cerium is 60% by mass based on oxides and the content of lanthanum is The content of praseodymium is 7 mass % based on oxide, the content of neodymium is 1.5 mass % based on oxide, and the content of impurities other than rare earth elements is 1.0 mass % or less. Subsequently, 2 kg of this mixed rare earth carbonate was burned in an electric furnace at a temperature of 850° C. for 2 hours to obtain a mixed rare earth oxide.

[0085] Then, the mixed rare earth oxide was dried at a temperature of 120° C. for 2 hours, and charged into a ceramic crucible set to a constant mass. Then, by heating at a temperature of 1000° C. for 1 hour, ignition loss was measured and found to be 0.38% by mass. In addition, the crystallite diameter was calculated using X-ray diffraction detection, and as a result, the crystallite diameter was 218 Ȧ. X-...

Embodiment 2

[0101] The mixed rare earth oxide was obtained in the same manner as in Example 1, except that the combustion temperature of the mixed rare earth carbonate was changed to 1000°C. The ignition loss of the obtained mixed rare earth oxide was 0.12% by mass, and the crystallite diameter was 348 Ȧ. Using the mixed rare earth oxide, a cerium-based abrasive was obtained in the same manner as in Example 1.

[0102] Polishing was performed using the obtained cerium-based abrasive in the same manner as in Example 1, and the state of polishing was evaluated. The production conditions and results are listed in Table 1 and Table 2, respectively.

Embodiment 3

[0104] The mixed rare earth fluoride was obtained in the same manner as in Example 1, except that the heat treatment temperature of the mixed rare earth fluoride was changed to 400°C. The maximum particle diameter of the obtained mixed rare earth fluoride was 96 micrometers, and the ignition loss was 3.45% by mass. Using the mixed rare earth fluoride, a cerium-based abrasive was obtained in the same manner as in Example 1.

[0105] Polishing was performed using the obtained cerium-based abrasive in the same manner as in Example 1, and the state of polishing was evaluated. The production conditions and results are listed in Table 1 and Table 2, respectively.

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Abstract

The present invention provides a mixed rare earth oxide for the production of a cerium-based abrasive, in which the ignition loss after heating at a temperature of 1,000 DEG C for 1 hour is 0.5 mass% or less on the dry mass basis and the crystallite diameter is from 200 to 400 A; a mixed rare earth fluoride for the production of a cerium-based abrasive, in which the ignition loss is from 3 to 15% on the dry mass basis; a process for producing a cerium-based abrasive from these mixed rare earth oxide or mixed rare earth fluoride; and a cerium-based abrasive produced by using these mixed rare earth oxide or mixed rare earth fluoride.

Description

[0001] Cross References to Related Applications [0002] This application is an application filed pursuant to 35 U.S.C. 111 §(a), pursuant to 35 U.S.C. 119 §(e) requiring provisional application 60 / 608,877 filed September 13, 2004 under 35 U.S.C. 111 §(b) Benefits on filing date. field of invention [0003] The present invention relates to a cerium-based abrasive for polishing transparent substrates, such as glass substrates for optical lenses, liquid crystal panels, hard disks, specific frequency wavelength filters, etc.; raw materials for abrasives; and methods of making them. In particular, the present invention relates to cerium-based abrasives for final polishing of high-precision glass substrates (such as hard disk substrates) and glass substrates for liquid crystal panels; raw materials for said abrasives; and methods for their preparation . Background technique [0004] More recently, glass materials have been used extensively, and in some of these applications su...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/14C01F17/00B24B37/00C01F17/206
CPCC03C19/00C01P2006/82C01F17/0043C01P2002/60C09K3/1409C01P2004/61C09K3/1436C01F17/206
Inventor 平岩正增田知之别所直纪
Owner SHOWA DENKO KK
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