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Carbon nano-tube combination electrode material, its production method and electrode

A carbon nanotube composite, electrode material technology, applied in electrode manufacturing, nanotechnology, nanotechnology and other directions, can solve the problem that graphite cannot meet the demand, and it is difficult to exert the large specific surface area of ​​carbon nanotubes.

Active Publication Date: 2008-09-24
TSINGHUA UNIV +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Lithium-ion secondary batteries and lithium-ion polymer secondary batteries are the most representative secondary batteries, and their negative electrodes are usually made of carbon materials such as graphite, but graphite can no longer meet the demand. Carbon nanotubes have a large Specific surface area, so it is used to replace graphite in the negative electrode of lithium-ion batteries
However, since the diameter of pure carbon nanotubes is on the molecular scale, the pores between carbon nanotubes are also small, so it is difficult for electrolyte or reactants to enter the pores and fully contact with the surface of carbon nanotubes, and it is difficult to play a role. Characteristics of large specific surface area of ​​carbon nanotubes

Method used

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  • Carbon nano-tube combination electrode material, its production method and electrode
  • Carbon nano-tube combination electrode material, its production method and electrode
  • Carbon nano-tube combination electrode material, its production method and electrode

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Embodiment Construction

[0012] refer to figure 1 , The technical solution provides a carbon nanotube composite electrode material 10, which includes a large number of carbon fibers 12 and carbon nanotubes 14, the carbon fibers 12 overlap to form a network structure, and the carbon nanotubes 14 are wound or attached to the carbon fibers 12.

[0013] The carbon nanotube composite electrode material 10 can be a thin film with a thickness between 0.1 mm and 10 mm. The diameter of the carbon fiber 12 may be 2 microns to 50 microns, and the length of the carbon fiber 12 may be 0.5 to 5 mm. The carbon nanotubes 14 can be single-walled carbon nanotubes or multi-walled carbon nanotubes with a diameter of 20 nm to 100 nm and a length of more than 10 microns.

[0014] Since the diameter of the carbon fiber 12 is about 100 times the diameter of the carbon nanotube 14, the pores between the carbon fibers 12 are also much larger than the pores between the carbon nanotubes in the electrode material formed solely b...

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Abstract

The invention relates to a combined electrode material of a carbon nanotube, a preparation method of the combined electrode material of the carbon nanotube and an electrode comprising the combined electrode material of the carbon nanotube. The combined electrode material of the carbon nanotube comprises large quantity of carbon fiber and a carbon nanotube, wherein, the large quantity of carbon fiber is lapped to form a network-like structure; the carbon nanotube intertwines or adheres to the carbon fiber. As the diameter of the carbon fiber is much larger than the diameter of the carbon nanotube, the holes in the combined electrode material of the carbon nanotube is larger than the holes of the electrode material purely formed by the carbon nanotube, so that an electrolyte or a reagent is easy to enter the holes of the combined electrode material of the carbon nanotube and fully contacts with the surface of the carbon nanotube, thus improving the capacity of a battery.

Description

technical field [0001] The invention relates to a carbon nanotube composite electrode material, a preparation method of the carbon nanotube composite electrode material and an electrode comprising the carbon nanotube composite electrode material. Background technique [0002] In recent years, portable electronic products such as notebook computers, mobile phones, and personal digital assistants have developed rapidly. higher and higher, thus placing higher demands on the secondary batteries that power them. [0003] Lithium-ion secondary batteries and lithium-ion polymer secondary batteries are the most representative secondary batteries, and their negative electrodes are usually made of carbon materials such as graphite, but graphite can no longer meet the demand. Carbon nanotubes have a large The specific surface area is therefore used to replace graphite in the negative electrode of lithium-ion batteries. However, since the diameter of pure carbon nanotubes is on the mo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/02H01M4/04H01M4/1393H01M4/58H01M4/587H01M10/052H01M10/36
CPCH01M10/052B82Y30/00C04B35/83C04B2235/526C04B2235/5264C04B2235/5288H01M4/04H01M4/0419H01M4/1393H01M4/587H01M4/661H01M4/663Y02E60/122Y02E60/10
Inventor 宋鹏程王鼎刘长洪范守善
Owner TSINGHUA UNIV