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Photocatalysis reactor for degrading dioxins in flue gas and method for activating photocatalyst

A technology of photocatalyst and activation method, applied in chemical instruments and methods, separation methods, dispersed particle separation, etc., can solve the problems of high operating costs, great environmental damage, inability to reduce the total amount of dioxins, etc., and achieve thorough treatment. Effect

Active Publication Date: 2012-03-14
ZHEJIANG UNIV
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Problems solved by technology

But there are two main defects in this method: the one, this method itself can not reduce the total amount of dioxin, only the dioxin in the gas phase is transferred to the solid phase by the adsorption of activated carbon and then collected, and the produced dioxin mixed with activated carbon Fly ash is enriched with high concentration of dioxins, which is very harmful to the environment. At present, there is no good way to dispose of fly ash from waste incineration. Domestically, landfill is mainly used to dispose of this kind of fly ash, which is harmful to the environment. The potential harm is very great; the second is that this method needs to consume a large amount of activated carbon, and the operating cost is relatively high

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  • Photocatalysis reactor for degrading dioxins in flue gas and method for activating photocatalyst
  • Photocatalysis reactor for degrading dioxins in flue gas and method for activating photocatalyst

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Embodiment Construction

[0027] A photocatalytic reactor is installed in the exhaust gas treatment of the incinerator. The photocatalyst in the photoreactor is loaded into a transparent container with a porous medium and irradiated with light. The photocatalyst can adsorb and degrade dioxins in the flue gas. When the photocatalyst is saturated, it is taken out, passes through the photocatalytic reduction reactor and the photocatalytic oxidation degradation reactor under light irradiation, and finally passes through the cleaning chamber, the photocatalyst can be restored to activity, and then added to the photocatalytic reactor for recycling.

[0028] The photocatalyst can be nano-TiO 2 , Nano-TiO modified by depositing precious metals 2 、Through nano-TiO composited with other semiconductor catalysts 2 Any of them, in this embodiment, nano-TiO 2 .

[0029] The porous medium loaded with the photocatalyst can be activated carbon, diatomaceous earth, or bentonite. In this embodiment, activated carbon is used. ...

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Abstract

The invention relates to a technique for controlling dioxin discharge in the process of processing solid wastes by a burning method, and aims to provide a photocatalytic reactor for degrading dioxin in flue gas and a photocatalyst activating method. The reactor is a light transparent container and the inside of the reactor is provided with a porous medium which is loaded with the photocatalyst. The method for activating the photocatalyst comprises the following steps: irradiating a deactivated photocatalyst by light in the presence of N2 gas; irradiating the photocatalyst by the light in the presence of O2; and washing the photocatalyst with clear water to recover the activity for standby. Compared with the prior process, the photocatalytic reactor and the photocatalyst activating method are more economical, and process the dioxide in the flue gas more thoroughly.

Description

Technical field [0001] The invention relates to a technology for controlling dioxin emission in the process of disposing of solid waste by incineration, in particular to a photocatalytic reactor and a photocatalyst activation method for degrading dioxin in flue gas. Background technique [0002] In the context of the rapid development of my country's national economy and the continuous improvement of people's material living standards, the amount of industrial waste and municipal solid waste is also rapidly increasing. Compared with other garbage disposal methods, the incineration method can better achieve the goal of "reduction, resource utilization and harmlessness", and it is widely used at home and abroad. Many cities in my country have also established large-scale waste incineration plants. Toxic substances are produced during the incineration process. Among them, dioxins are the most toxic. They are difficult to degrade after being discharged into the environment. They are...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/70
Inventor 陆胜勇严建华李晓东池涌王飞蒋旭光马增益金余其黄群星杨家林倪明江岑可法
Owner ZHEJIANG UNIV