ClO2 bleaching method of bagasse pulp

A technology of chlorine dioxide and bagasse pulp, applied in the field of pulp bleaching, which can solve the problems of large environmental pollution and low yield of bleached pulp

Active Publication Date: 2009-09-30
GUANGXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, in southern my country, the rich bagasse resources are used to produce bleached pulp, mainly using chlorination-alkali treatment-??? hypochlorite (CEH) three-stage bleaching method, using (CEH) bleaching method, the yield of bleached pulp is low , generally 82 to 85%, and the bleaching wastewater contains a large amount of organic chloride, which greatly pollutes the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] 1000kg of bagasse primary color paste is cooked by traditional chemical method, then added with water to adjust the weight concentration of pulp to 10%, and then transported by a medium-concentration pump, so that the pulp passes through a chlorine dioxide mixer and mixed with chlorine dioxide containing 30kg of available chlorine. After the 1140kg aqueous solution is fully mixed, it enters the bottom of the up-flow bleaching tower for reaction, and the reaction temperature is maintained at 60°C. After the reaction time is 90min, it is diluted with 30,000kg of water and sent to the 1# vacuum washer for washing to obtain D of about 65% ISO. 0 section of bleached pulp. then D 0 The weight concentration of section bleached pulp is adjusted to 10%, then adding 20kg of NaOH and weight concentration is 25% H 2 o 2 Aqueous solution 16kg (ie H 2 o 2 The weight is 0.4% of the former color pulp weight), and is sent to the alkali treatment tower through the screw propeller for...

Embodiment 2

[0026] First, 1000kg of bagasse primary color paste is chemically cooked, then water is added to adjust the weight concentration to 10%, and then transported by a medium-concentration pump, so that the pulp passes through a chlorine dioxide mixer and is fully mixed with 950kg of chlorine dioxide aqueous solution containing 25kg of available chlorine. After mixing, enter the bottom of the up-flow bleaching tower for reaction, maintain the reaction temperature at 65°C, and after the reaction time of 80min, dilute with 40,000kg of water and transport it to the 1# vacuum washer for washing to obtain about 63% ISO D 0 section of bleached pulp. then D 0 The weight concentration of section bleached pulp is adjusted to 10%, then adding 15kg of NaOH and weight concentration is 25% H 2 o 2 12kg of aqueous solution (i.e. H 2 o 2 The weight is 0.3% of the former color paste weight), and is sent to the alkali treatment tower through the screw propeller for processing, maintains 65 ℃ of...

Embodiment 3

[0028] First, 1000kg of bagasse primary color paste is chemically cooked, then water is added to adjust the weight concentration to 10%, and then transported by a medium-concentration pump, so that the pulp passes through a chlorine dioxide mixer and is fully mixed with 1330kg of chlorine dioxide aqueous solution containing 35kg of available chlorine. After mixing, enter the bottom of the up-flow bleaching tower for reaction, maintain the reaction temperature at 55°C, and after the reaction time of 65min, dilute with 50,000kg of water and transport it to 1# vacuum washer for washing to obtain about 69% ISO D 0 section of bleached pulp. then D 0 The weight concentration of section bleached pulp is adjusted to 10%, then adding 25kg of NaOH and weight concentration is 25% H 2 o 2 20kg of aqueous solution (ie H 2 o 2 The weight is 0.5% of the original color paste weight), and is sent to the alkali treatment tower through the screw propeller for processing, maintains 70 ℃ of re...

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PUM

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Abstract

The invention relates to a clO2 bleaching method of bagasse pulp, which indicates 1) preparing the ponderance concentration of the bagasse fundamental colour pulp as 10%, and then getting d>=[0]albefaction pulp by mixing the aforementioned fundamental colour pulp with clo2 containing available chlorine of 2.5%-3.5% of the fundamental colour pulp by weight. 2) preparing the ponderance concentration of the aforementionedd>=[0]albefaction pulp as 10% after washing it, then gettinge>=[p]extraction pulp by addingh>=[2]o>=[2]which is 0.3%-0.5% of the fundamental colour pulp by weight and NaOH which is 1.5%-2.5% of the fundamental colour pulp by weight and carrying them into intensification alkalis reaction. 3) preparing the ponderance concentration of the aforementioned E>=[P]albefaction pulp as 10% after washing it, and then getting d>=[1]albefaction pulp by mixing the aforementioned fundamental colour pulp with clo2 containing available chlorine of 1.0%-1.5% of the fundamental colour pulp by weight. 4) In the end getting the high white content albefaction pulp with white content of 81%-87% ISO and yield rate of 90%-92% by diluting the aforementionedd>=[1]albefaction pulp and washing it.

Description

technical field [0001] The invention belongs to the technical field of pulp bleaching, in particular to a chlorine dioxide bleaching method for bagasse pulp. technical background [0002] Chlorine dioxide is a strong oxidizing agent. Stable chlorine dioxide has been considered by the World Health Organization as a fungicide with good effect and a bactericidal disinfectant with excellent performance, and it is also a good paper bleaching agent. The use of chlorine dioxide in pulp bleaching has the characteristics of high brightness, stable brightness, strength retention, low color drainage and low toxicity. Its unique advantages are unmatched by any other chemicals so far. In view of the superiority of chlorine dioxide bleaching and the high toxicity of chlorine bleaching, the National Development and Reform Commission has recommended chlorine dioxide as one of the chemicals for pulp bleaching, and phased out the chlorine bleaching process. [0003] At present, in southern m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21C9/16D21C9/14
Inventor 王双飞李许生农光再宋海农杨崎峰陈国宁卫威詹磊
Owner GUANGXI UNIV
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