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Method for preparing glyphosate potassium salt granules

A technology of glyphosate potassium salt and potassium salt granules, applied in botany equipment and methods, herbicides, algicides, biocides, etc., can solve the problem of long cooling and crystallization time, difficult drying of wet products, and redundant steps Complexity and other issues, to achieve the effect of reducing production energy consumption, overcoming production difficulties, and simple process

Active Publication Date: 2012-10-03
SICHUAN LESHAN FUHUA TONGDA AGRO-CHEM TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the special alkali metal properties of potassium, the solubility of glyphosate potassium salt in water is very large, and the reaction between alkali containing potassium ions and glyphosate acid will generate water at the same time, so it is difficult to control the amount of water added in the reaction. After the reaction, The wet product is not easy to dry, and it takes a long time to cool and crystallize after the reaction
In addition, in the early stage of the reaction, it needs to consume a lot of energy to dry glyphosate acid, and the steps of adding solvent and post-treatment of solvent are redundant and complicated, and the reaction heat and water generated during the process will cause production difficulties

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A preparation method of glyphosate potassium salt granules, characterized in that: the preparation method specifically comprises the following steps:

[0017] A, mixing: by mixing glyphosate acid wet powder and potassium hydroxide in the stirring and grinding equipment provided with the circulating air flow channel, the circulating air will take away the heat of reaction and remove the moisture in the air flow through condensation. The stirring and grinding equipment is Stirring ball mill or high-speed kneader; the ratio of glyphosate acid to potassium hydroxide is 1 mole of glyphosate acid: 1 mole of potassium hydroxide, glyphosate acid reacts with potassium hydroxide to generate glyphosate potassium salt; cycle The function of the air flow is to take away the heat of reaction to reduce the fluidity of the system and condense to remove part of the water to control the water content of the material, to avoid the material from becoming semi-fluid due to the reaction of wa...

Embodiment 2

[0024] A preparation method of glyphosate potassium salt granules, characterized in that: the preparation method specifically comprises the following steps:

[0025] A, mixing: by mixing glyphosate acid wet powder alkaline potassium salt in the agitating and grinding equipment provided with the circulating air flow channel, the circulating air is condensed to take away the heat of reaction and remove the moisture content in the air flow. The agitating and grinding equipment is Stirring ball mill or high-speed kneader; glyphosate acid and potassium ion ratio is 1 mole of glyphosate acid: 1.1 mole of potassium cation, glyphosate acid reacts with alkaline potassium salt to form glyphosate potassium salt; circulating air flow The function is to take away the heat of reaction to reduce the fluidity of the system and condense to remove part of the water to control the moisture of the material, to avoid the material from becoming semi-fluid due to the reaction of water, so that the re...

Embodiment 3

[0032] A preparation method of glyphosate potassium salt granules, specifically comprising the steps of:

[0033] A, mixing: by mixing glyphosate acid wet powder and potassium hydroxide in the stirring and grinding equipment provided with the circulating air flow channel, the circulating air will take away the heat of reaction and remove the moisture in the air flow through condensation. The stirring and grinding equipment is Stirring ball mill or high-speed kneader; glyphosate acid and potassium ion ratio is 1 mole of glyphosate acid: 1 mole of potassium cation, glyphosate acid reacts with potassium hydroxide to generate glyphosate potassium salt; The function is to take away the heat of reaction to reduce the fluidity of the system and condense to remove part of the water to control the moisture of the material, to avoid the material from becoming semi-fluid due to the reaction of water, so that the reaction can be completed smoothly to directly produce a powder with a certai...

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PUM

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Abstract

The invention relates to a preparation method for producing glyphosate potassium salt granules by using glyphosate wet powder, which belongs to the field of chemical industry. The preparation method comprises four steps of mixing, charging, granulating and drying to obtain a finished product. The soluble glyphosate potassium salt granules can be obtained through the reaction of the glyphosate wet powder and alkali containing potassium cations or alkali potassium salt, and the glyphosate wet powder is directly adopted for the reaction. Compared with the prior art, the glyphosate wet powder is directly adopted for the reaction so as to save the energy consumption for drying glyphosate acid; steps of adding a solvent, post-treating the solvent and the like are saved; the reaction heat and the difficult production caused by the generated water are overcome by condensing, cooling and dewatering; the process is simple, and can reduce the production energy consumption and improve the production efficiency; and meanwhile, the integral process is simple, can reduce the production energy consumption and improve the production efficiency, and is suitable for popularization and application.

Description

technical field [0001] The invention relates to a preparation method for producing glyphosate potassium salt solid granules from glyphosate wet powder, which belongs to the field of chemical industry. Background technique [0002] Glyphosate is an excellent herbicide that kills herbicides. It has been rapidly promoted in the market since it was first developed by Monsanto in 1971. It is mainly used for field weeding of glyphosate-resistant transgenic crops, weeding of non-cultivated land, and planting of no-tillage crops. At present, the global pesticide market sales are as high as 30 billion U.S. dollars, of which herbicides are about 15 billion U.S. dollars, accounting for 50% of the entire pesticide market, and my country's herbicides account for about 30% of the entire pesticide market. There are about 600 varieties of herbicides in the world, of which glyphosate accounts for up to 30% of the total global herbicides. In recent years, glyphosate has been occupying the f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A01N25/14A01N57/20A01P13/00
Inventor 陈茜姜永红
Owner SICHUAN LESHAN FUHUA TONGDA AGRO-CHEM TECH CO LTD
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