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Method for preparing emulsified fuel oil

A technology of fuel oil and oleic acid, which is applied in the field of gasoline microemulsion or kerosene microemulsion to prepare diesel microemulsion, which can solve the problems of complex production process, affecting product quality, and difficulty in controlling the emulsification process, so as to ensure the use performance And safe use, high transparency and stability, conducive to energy saving and environmental protection

Inactive Publication Date: 2010-04-28
陈映波
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The diesel emulsifiers in the United States, Japan, Germany and other countries have already been sold as commodities, and the third or fourth generation products have been developed; my country has also made great progress in emulsifiers in recent years, but most of them are more or less There are some problems that affect the promotion and application of emulsified diesel oil, emulsified gasoline, and emulsified kerosene
[0004] For example, the cost of emulsifiers is high. If ethanolamine or cyclohexylamine is used for the alkali phase, the material price is 15,000-25,000 yuan / ton. Although the transparency of the emulsion is relatively high, the cost is comparable to the price of petrochemical refined oil, which has no practical significance; The production process is difficult to control. For example, although some alkaline phases also use ammonia water, which reduces the cost of emulsifiers, the emulsification process is difficult to control due to the strong alkalinity of ammonia water, which affects product quality and causes poor stability, and oil-water separation is prone to occur; production process Complexity and large investment in equipment. If some special production equipment such as light, magnetism or ultrasonic is required to achieve product transparency, it also increases production costs and investment risks; petrochemical refined oil has complex components, large component changes and polarity Strong, there is a certain difficulty in solving the miscibility between the emulsion and it; etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] ①Add 200g of oleic acid to a 500ml beaker, then add 100g of methanol, and stir until completely dissolved to form 300g of acid phase. ②Add 50g of ammonia water to a 200ml beaker with a cover, then add 30g of ethanol, shake until completely dissolved and become 80g of alkali phase. ③Slowly add 80g of the base phase into 300g of the stirring acid phase to prepare 380g of emulsifier. ④Add 300g of diesel oil to a 1000ml beaker, then add 30g of water, adjust the speed of the mixer to 600-800 rpm, first stir the oil and water until milky white, then slowly add 25g of the above emulsifier, stir until the liquid is transparent and clear, Filter after placing to make 355g of diesel microemulsion.

Embodiment 2

[0031] ①Add 200g of oleic acid to a 500ml beaker, then add 200g of methanol, and stir until completely dissolved to form 400g of acid phase. ②Add 50g of ammonia water to a 200ml beaker with a cover, then add 50g of ethanol, and shake until completely dissolved to form 100g of alkali phase. ③Slowly add 100g of the base phase into 400g of the stirring acid phase to prepare 500g of emulsifier. ④Add 300g of diesel oil to a 1000ml beaker, then add 100g of clear water, adjust the speed of the mixer to 600-800 rpm, first stir the oil and water until milky white, then slowly add 120g of the above emulsifier, stir until the liquid is transparent and clear, After placing and filtering, 520 g of diesel oil microemulsion was prepared. ⑤Under stirring, add 50g of kerosene, 0.2g of ferrocene, 1.1g of isooctyl nitrate, 0.1g of metal corrosion inhibitor, and 0.1g of rubber anti-swelling agent, and mix completely to obtain 571.5g of emulsified diesel oil.

Embodiment 3

[0033] ①Add 200g of oleic acid to a 500ml beaker, then add 100g of methanol, and stir until completely dissolved to form 300g of acid phase. ②Add 30g of ammonia water to a 200ml beaker with a cover, then add 20g of methanol, shake until completely dissolved and become 50g of alkali phase. ③Slowly add 50g of the base phase into 300g of the stirring acid phase to prepare 350g of emulsifier. ④Add 400g of gasoline to a 1000ml beaker, then add 50g of water, adjust the speed of the mixer to 600-800 rpm, first stir the oil and water until milky white, then slowly add 70g of the above emulsifier, stir until the liquid is transparent and clear, Filter after placing and promptly make gasoline microemulsion 520g. ⑤Under stirring, add 30g of light naphtha, 0.2g of ferrocene, 5g of methyl tert-butyl ether, 0.1g of metal corrosion inhibitor, and 0.1g of rubber anti-swelling agent, and mix completely to obtain the product emulsified gasoline 555.4g.

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PUM

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Abstract

The invention relates to a method for preparing emulsified fuel oil, which comprises the following steps: 1) adding methanol or ethanol into oleic acid or fatty acid, and stirring for forming an acid phase; 2) adding the methanol or the ethanol into ammonia, and stirring for forming a base phase; 3) adding the base phase into the acid phase while stirring for preparing an emulsifier; and 4) adding clean water into petrochemical finished oil, firstly stirring till milk white, then adding the emulsifier, stirring till that liquid is transparent and clear, standing and then filtering, thereby preparing the emulsified fuel oil. The method can also add a diluent, a modifier, a protective agent and the like according to needs. The emulsified fuel oil has the advantages of simple production technology, extensive resources of raw materials, cheap price, high product stability and good intersolubility with the petrochemical finished oil.

Description

technical field [0001] The invention relates to a water-in-oil type (W / O type) emulsified fuel oil, in particular to a method for preparing diesel oil microemulsion, gasoline microemulsion or kerosene microemulsion by using diesel oil, gasoline or kerosene. Background technique [0002] With the rapid development of industrial and agricultural production and the automobile and transportation industries, people's demand for refined oil is increasing day by day. However, petrochemical refined oil is a non-renewable energy source, and its incomplete combustion causes environmental pollution. Therefore, fuel-saving and anti-pollution technologies such as emulsified diesel oil, emulsified gasoline, emulsified kerosene and their additives have emerged as the times require. [0003] The diesel emulsifiers in the United States, Japan, Germany and other countries have already been sold as commodities, and the third or fourth generation products have been developed; my country has als...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G31/08
Inventor 陈映波
Owner 陈映波
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