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Self-assembly method of precious metal quantum dot/one-dimensional titanate nanoribbon heterojunction material

A technology of noble metals and quantum dots, applied in nanomaterials and nanometer fields, can solve problems such as lack of technical means, and achieve the effect of simple process, high degree of controllability, and low equipment requirements

Active Publication Date: 2013-02-06
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the degree of dispersion of noble metals on the surface of photocatalyst materials, particle size and interface binding have a significant impact on the enhancement of photocatalytic effect, and there is still a lack of effective technical means.

Method used

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  • Self-assembly method of precious metal quantum dot/one-dimensional titanate nanoribbon heterojunction material
  • Self-assembly method of precious metal quantum dot/one-dimensional titanate nanoribbon heterojunction material
  • Self-assembly method of precious metal quantum dot/one-dimensional titanate nanoribbon heterojunction material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The self-assembly method of the photocatalyst material of the precious metal quantum dot / one-dimensional titanate nanobelt heterojunction includes the following steps:

[0029] (1) Take sulfhydryl acetic acid and ethanol, dissolve sulfhydryl acetic acid in ethanol, and prepare a sulfhydryl acetic acid solution with a concentration of 10 mg / mL;

[0030] (2) Add 0.4g one-dimensional titanic acid (H 2 Ti 5 O 11 ·3H 2 O) The nanometer tape is immersed in the above 0.8g sulfhydryl acetic acid solution and vacuumed (the vacuum degree is 10 -1 ~10 -5 ), soak overnight in the state of ventilating Ar gas, then heat treatment at 100°C for 2 hours, and wash with acetone to obtain one-dimensional titanate nanobelts treated with phosphonic acid surfactants;

[0031] (3) The preparation of Pt precious metal quantum dots is as follows: Weigh 0.1g polyvinylpyrrolidone (PVP), 10mL chloroplatinic acid (6mmol / L), dissolve in 5mL deionized water and 40mL ethanol, stir until the mixture is uniform;...

Embodiment 2

[0041] The self-assembly method of the photocatalyst material of the precious metal quantum dot / one-dimensional titanate nanobelt heterojunction includes the following steps:

[0042] (1) Take 3-mercaptopropionic acid and methanol, and dissolve 3-mercaptopropionic acid in methanol to prepare a 3-mercaptopropionic acid solution with a concentration of 30mg / mL;

[0043] (2) The 0.4g prepared one-dimensional titanic acid (H 2 Ti 5 O 11 ·3H 2 O) Soak the nanometer strips in the above 1.0g 3-mercaptopropionic acid solution and apply a vacuum (the vacuum degree is 10 -1 ~10 -5 ), soak overnight in the state of ventilating Ar gas, then heat treatment at 100°C for 2 hours, and wash with acetone to obtain one-dimensional titanate nanobelts treated with phosphonic acid surfactants;

[0044] (3) The preparation of Au precious metal quantum dots is: Weigh 0.1g HAuCl 4 Dissolve in 30mL deionized water to obtain HAuCl 4 Aqueous solution; Weigh 2.187g of tetraoctyl ammonium bromide (TOAB) and dissol...

Embodiment 3

[0050] The self-assembly method of the photocatalyst material of the precious metal quantum dot / one-dimensional titanate nanobelt heterojunction includes the following steps:

[0051] 1) Take a phosphonic acid surfactant and a solvent, and dissolve the phosphonic acid surfactant in the solvent to form a phosphonic acid surfactant solution with a concentration of 10 mg / mL; the phosphonic acid surfactant is 3-mercaptopropionic acid; the solvent is ethanol;

[0052] 2) According to the mass ratio of the one-dimensional titanic acid nanobelt to the phosphonic acid surfactant solution of 1:3, select the phosphonic acid surfactant solution and combine the one-dimensional titanic acid (H 2 Ti 5 O 11 ·3H 2 O) The nanometer strip is immersed in the above phosphonic acid surfactant solution and vacuumed (the vacuum degree is 10 -1 ~10 -5 ), soaked overnight in the state of ventilating Ar, then heat-treated at 100°C for 3 hours, and washed with acetone to obtain one-dimensional titanate nanobe...

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Abstract

The invention relates to a self-assembly method of a photocatalyst material, and relates to a self-assembly method of a precious metal quantum dot / one-dimensional titanate nanoribbon heterojunction material, which is characterized by comprising the following steps of: (1) preparing a phosphonic acid surfactant solution with the concentration of not less than 10mg / mL; (2) obtaining the one-dimensional titanate nanoribbon processed with a phosphonic acid surfactant according to the mass ratio of the one-dimensional titanate nanoribbon to the phosphonic acid surfactant solution being 1:1-1:10; (3) preparing a precious metal quantum dot solution with the concentration of not less than 10mg / mL according to the mass ratio of the precious metal quantum dot to the one-dimensional titanate nanoribbon being 0.1-12 percent; (4) immersing the one-dimensional titanate nanoribbon processed with the phosphonic acid surfactant in the precious metal quantum dot solution to obtain the precious metal quantum dot / one-dimensional titanate nanoribbon heterojunction material with different precious metal contents in a self-assembly mode. The method has simple process and low cost. Moreover, the obtained photocatalyst material has prominent photocatalytic enhancement effect.

Description

Technical field [0001] The invention relates to a self-assembly method of photocatalyst materials and belongs to the field of nano materials and nano technology. Background technique [0002] One-dimensional nanomaterials exhibit superior mechanical, optical, electrical, magnetic and other physical properties due to their special nano-sized morphology and structure, which has increasingly become a research focus. TiO 2 Semiconductor-based nanomaterials have great advantages as photocatalysts and have good application prospects in environmental protection, clean energy, and green building materials. Studies have shown that under ultraviolet light conditions, TiO 2 The material can be used as a photocatalyst to effectively decolor and mineralize macromolecular organic matter, and decompose into small inorganic molecules such as water and carbon dioxide. But TiO 2 The material has a wide band gap (3.2eV), and can only use ultraviolet light with a wavelength of less than 380nm. Und...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/20B01J23/652B01J23/68B01J37/00B01J35/02B82Y30/00B82Y40/00
Inventor 刘曰利陈文钟蕾舒威周静
Owner WUHAN UNIV OF TECH
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