Self-assembly method of precious metal quantum dot/one-dimensional titanate nanoribbon heterojunction material
A technology of noble metals and quantum dots, applied in nanomaterials and nanometer fields, can solve problems such as lack of technical means, and achieve the effect of simple process, high degree of controllability, and low equipment requirements
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Embodiment 1
[0028] The self-assembly method of the photocatalyst material of the precious metal quantum dot / one-dimensional titanate nanobelt heterojunction includes the following steps:
[0029] (1) Take sulfhydryl acetic acid and ethanol, dissolve sulfhydryl acetic acid in ethanol, and prepare a sulfhydryl acetic acid solution with a concentration of 10 mg / mL;
[0030] (2) Add 0.4g one-dimensional titanic acid (H 2 Ti 5 O 11 ·3H 2 O) The nanometer tape is immersed in the above 0.8g sulfhydryl acetic acid solution and vacuumed (the vacuum degree is 10 -1 ~10 -5 ), soak overnight in the state of ventilating Ar gas, then heat treatment at 100°C for 2 hours, and wash with acetone to obtain one-dimensional titanate nanobelts treated with phosphonic acid surfactants;
[0031] (3) The preparation of Pt precious metal quantum dots is as follows: Weigh 0.1g polyvinylpyrrolidone (PVP), 10mL chloroplatinic acid (6mmol / L), dissolve in 5mL deionized water and 40mL ethanol, stir until the mixture is uniform;...
Embodiment 2
[0041] The self-assembly method of the photocatalyst material of the precious metal quantum dot / one-dimensional titanate nanobelt heterojunction includes the following steps:
[0042] (1) Take 3-mercaptopropionic acid and methanol, and dissolve 3-mercaptopropionic acid in methanol to prepare a 3-mercaptopropionic acid solution with a concentration of 30mg / mL;
[0043] (2) The 0.4g prepared one-dimensional titanic acid (H 2 Ti 5 O 11 ·3H 2 O) Soak the nanometer strips in the above 1.0g 3-mercaptopropionic acid solution and apply a vacuum (the vacuum degree is 10 -1 ~10 -5 ), soak overnight in the state of ventilating Ar gas, then heat treatment at 100°C for 2 hours, and wash with acetone to obtain one-dimensional titanate nanobelts treated with phosphonic acid surfactants;
[0044] (3) The preparation of Au precious metal quantum dots is: Weigh 0.1g HAuCl 4 Dissolve in 30mL deionized water to obtain HAuCl 4 Aqueous solution; Weigh 2.187g of tetraoctyl ammonium bromide (TOAB) and dissol...
Embodiment 3
[0050] The self-assembly method of the photocatalyst material of the precious metal quantum dot / one-dimensional titanate nanobelt heterojunction includes the following steps:
[0051] 1) Take a phosphonic acid surfactant and a solvent, and dissolve the phosphonic acid surfactant in the solvent to form a phosphonic acid surfactant solution with a concentration of 10 mg / mL; the phosphonic acid surfactant is 3-mercaptopropionic acid; the solvent is ethanol;
[0052] 2) According to the mass ratio of the one-dimensional titanic acid nanobelt to the phosphonic acid surfactant solution of 1:3, select the phosphonic acid surfactant solution and combine the one-dimensional titanic acid (H 2 Ti 5 O 11 ·3H 2 O) The nanometer strip is immersed in the above phosphonic acid surfactant solution and vacuumed (the vacuum degree is 10 -1 ~10 -5 ), soaked overnight in the state of ventilating Ar, then heat-treated at 100°C for 3 hours, and washed with acetone to obtain one-dimensional titanate nanobe...
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