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Metal cup-cylinder composite nano structure array and preparation method thereof

A technology of composite nanostructure and metal nanostructure, which is applied in the direction of nanostructure manufacturing, nanotechnology, nanotechnology, etc., can solve the problems of low efficiency and high cost, and achieve the effect of good repeatability and large hot spot area

Active Publication Date: 2015-01-07
NAT UNIV OF DEFENSE TECH
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

[0003] At present, most of the "top-down" or "bottom-up" processes for preparing nanostructure arrays have high cost and low efficiency, and are mostly limited by factors such as lithography resolution and nanosphere size, making it difficult to Achieving controllable preparation of nanostructures with smaller nanoscale gaps

Method used

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  • Metal cup-cylinder composite nano structure array and preparation method thereof
  • Metal cup-cylinder composite nano structure array and preparation method thereof
  • Metal cup-cylinder composite nano structure array and preparation method thereof

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Embodiment Construction

[0049] The present invention will be further described below in conjunction with specific embodiments and the description of the drawings.

[0050] Kind of like Figure 14 The gold cup-pillar composite nanostructure array of the present invention shown includes a two-dimensional periodically arranged hexagonal array structure formed by gold nanostructure array units in an orderly manner. The gold nanostructure array unit is a gold cup-pillar composite nanostructure, The gold cup-pillar composite nano structure includes a cup-shaped gold nano outer wall 1, and the center of the cup groove surrounded by the gold nano outer wall is a cylindrical gold nano particle 2. In this embodiment, the distance d between the central cylindrical gold nano particles 2 of adjacent array units is 300 nm, the average thickness t and the average height a of the cup-shaped gold nano outer wall are 50 nm and 60 nm, respectively, and the cylindrical gold nano particles The average height h and the aver...

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Abstract

The invention discloses a novel metal cup-cylinder composite nano structure array which is formed by sequential arrangement of metal nano structure array units. The metal nano structure array units are of a metal cup-cylinder composite nano structure which comprises a cup-shaped metal nano outer wall, and the center of a cup groove formed by the metal nano outer wall is a cylindrical metal nano particle. The invention also discloses a preparation method of the metal nano structure array, and the preparation method comprises the processing steps of preparing a single-layer orderly polrvinyl benzene nano ball compact arrangement, preparing a single-layer orderly polrvinyl benzene nano ball non-compact arrangement, preparing a nano annular-structure array mask made of composite materials, preparing a silicon-nano-structure array template, preparing the metal cup-cylinder composite nano-structure array, and the like. The metal nano array structure provided by the invention has gaps with smaller nano sizes and can be used for realizing the Roman detection of a single biomolecule; and according to the preparation method, the compatibility is good, the efficiency is high and the cost is low.

Description

technical field [0001] The invention relates to the field of metal nanostructures, in particular to a composite nanostructure array and a preparation method thereof. Background technique [0002] In recent years, metal nanostructure arrays with nanoscale gaps have excellent optical properties due to the plasmon resonance generated by the collective excitation of free electrons on the surface, so they are used in optical filters, plasmonic optical waveguides, biological / chemical Sensors, substrate materials for surface-enhanced spectroscopy and other fields have a very wide range of application values. Among them, the size of the nanoscale gap directly affects the sensitivity and other properties of the nanosensor. The establishment of a controllable nanogap structure and corresponding characterization technology has become one of the key foundations for the development of ultra-high-sensitivity nanosensors and molecular devices. [0003] At present, most of the "top-down" o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B81C1/00B82B1/00
Inventor 董培涛吴学忠邸荻王朝光王浩旭陈剑吕宇王俊峰
Owner NAT UNIV OF DEFENSE TECH
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