Method for removing chlorine included in hydrogen chloride gas
A technology of hydrogen chloride gas and hydrogen chloride, which is applied in the direction of chlorine/hydrogen chloride, chlorine/hydrogen chloride purification, etc., can solve the problems of complex purification system, expensive stannous chloride, and high cost of synthesizing hydrogen chloride, so as to broaden the scope of application, improve application value, The effect of low energy consumption and cost
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Embodiment 1
[0010] Step A. countercurrent reaction to remove chlorine: the purification solution containing saturated hydrogen chloride ferrous chloride concentration of 10wt% is sprayed into the packing layer from the top of the packing tower. The packing in this embodiment adopts Raschig ring packing, and the packing layer is axially thick 150cm Then the hydrogen chloride gas that adopts carbon tetrachloride and methane gas to produce tetrachlorethylene by-product is imported from the bottom of the packing tower; Chlorine 1.1% (v / v) is contained in the present embodiment hydrogen chloride gas, gas flow velocity 0.4m / s, the by-product hydrogen chloride gas is in full contact with the purification liquid in the packing layer from the bottom of the tower upwards, the ferrous chloride in the purification liquid undergoes redox reaction with chlorine gas, and the chlorine gas is reduced to chloride ions and enters the purification liquid and goes out of the tower with the purification liquid ...
Embodiment 2
[0014] Step A. Removal of chlorine by countercurrent reaction: the purification solution containing saturated hydrogen chloride with a ferrous chloride concentration of 0.8wt% is sprayed into the packing layer from the upper part of the packing tower. In this embodiment, the packing adopts silicon packing, and the packing layer has an axial thickness of 150 cm. Then the by-product hydrogen chloride gas produced by the methanol method to produce methyl chloride is imported from the bottom of the packed tower, containing 1.0% (v / v) of chlorine gas and gas flow velocity 0.6m / s in the hydrogen chloride gas produced by the present embodiment; by-product hydrogen chloride gas Fully contact with the purification liquid in the packing layer from the bottom of the tower, the ferrous chloride in the purification liquid undergoes oxidation-reduction reaction with chlorine gas, the chlorine gas is reduced to chloride ions and enters the purification liquid and is discharged from the bottom ...
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