Method for removing chlorine included in hydrogen chloride gas

A technology of hydrogen chloride gas and hydrogen chloride, which is applied in the direction of chlorine/hydrogen chloride, chlorine/hydrogen chloride purification, etc., can solve the problems of complex purification system, expensive stannous chloride, and high cost of synthesizing hydrogen chloride, so as to broaden the scope of application, improve application value, The effect of low energy consumption and cost

Inactive Publication Date: 2013-01-02
HAOHUA HONGHE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology uses an iron salt solution that contains dissolved sodium or lithocholor acid to remove impurities from gases produced during chemical reactions like producing dichloromethane. By reacting this soluble material with certain substances found on it, these contaminants become more easily separated out when they form crystals due to their ability to absorb water vapor at different temperatures. These technical effectings include efficient cleanup of harmful compounds such as chlorinating agents while improving productivity and reducing costs associated therewith.

Problems solved by technology

Technological Problem addressed in this patents relates to improving the efficiency and effectiveness of separating harmful gases like chloroform or dichlorophyllum nitrodes during manufacturing processes that require highly purity materials. Current methods involve multiple steps involving different types of equipment which result in increased costs due to their complexity and energy usage.

Method used

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Embodiment 1

[0010] Step A. countercurrent reaction to remove chlorine: the purification solution containing saturated hydrogen chloride ferrous chloride concentration of 10wt% is sprayed into the packing layer from the top of the packing tower. The packing in this embodiment adopts Raschig ring packing, and the packing layer is axially thick 150cm Then the hydrogen chloride gas that adopts carbon tetrachloride and methane gas to produce tetrachlorethylene by-product is imported from the bottom of the packing tower; Chlorine 1.1% (v / v) is contained in the present embodiment hydrogen chloride gas, gas flow velocity 0.4m / s, the by-product hydrogen chloride gas is in full contact with the purification liquid in the packing layer from the bottom of the tower upwards, the ferrous chloride in the purification liquid undergoes redox reaction with chlorine gas, and the chlorine gas is reduced to chloride ions and enters the purification liquid and goes out of the tower with the purification liquid ...

Embodiment 2

[0014] Step A. Removal of chlorine by countercurrent reaction: the purification solution containing saturated hydrogen chloride with a ferrous chloride concentration of 0.8wt% is sprayed into the packing layer from the upper part of the packing tower. In this embodiment, the packing adopts silicon packing, and the packing layer has an axial thickness of 150 cm. Then the by-product hydrogen chloride gas produced by the methanol method to produce methyl chloride is imported from the bottom of the packed tower, containing 1.0% (v / v) of chlorine gas and gas flow velocity 0.6m / s in the hydrogen chloride gas produced by the present embodiment; by-product hydrogen chloride gas Fully contact with the purification liquid in the packing layer from the bottom of the tower, the ferrous chloride in the purification liquid undergoes oxidation-reduction reaction with chlorine gas, the chlorine gas is reduced to chloride ions and enters the purification liquid and is discharged from the bottom ...

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PUM

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Abstract

The invention, belonging to the field of chemical industry production, discloses a method for removing contained chlorine from a byproduct hydrogen chloride gas generated in the process of producing organic chlorides, comprising the following steps: carrying out reduction reaction upstream on a byproduct hydrogen chloride gas output by the process of producing organic chlorides and a purification solution in a packed tower to remove chlorine, and then conducting freeze drying to obtain a high-purity hydrogen chloride gas with the chlorine content of less than 1ppm. According to the invention, by using a ferrous chloride solution containing satuarated hydrogen chloride as the purification solution to remove chlorine from the hydrogen chloride gas with a chlorine content of less than 5%(v/v) to obtain chlorine, the advantages of simpleness, reliability, fast removing speed, and low energy consumption and cost of purification are achieved, and the method can effectively raise the application value of the byproduct hydrogen chloride gas, broaden the application range of the byproduct hydrogen chloride gas, and the like; and the method can be used for removing chlorine from a synthetic hydrogen chloride gas with a chlorine content of less than 5%(v/v and byproduct hydrogen chloride gases generated from other production processes.

Description

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Claims

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Application Information

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Owner HAOHUA HONGHE CHEM
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