Nylon modified material and preparation method thereof

A modified material, nylon technology, applied in the field of nylon modified materials and its preparation, can solve the problems of polymer material performance enhancement, no significant enhancement of nylon material mechanical properties, and increased preparation process complexity, etc., to achieve enhanced toughness and resistance Impact resistance, prevention of crystal nucleation, and improvement of interface conditions

Active Publication Date: 2015-04-22
KINGFA SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The research on nano-hydroxyapatite whiskers began in the 1990s, and its chemical formula is Ca 10 (PO 4 ) 6 (OH) 2 (referred to as HA or HAP), widely used in the field of composite material reinforcement, such as the composite reinforcement of biomedical materials, but it has not been reported to apply it to the performance enhancement of polymer materials
[0007] CN101768355A discloses a method for preparing attapulgite / nylon 6 nanocomposites using anion ring-opening method, which is used to increase the heat resistance of nylon, but its preparation adopts in-situ polymerization and ultrasonic dispersion technology, which increases The complexity of the preparation process, on the other hand, cannot guarantee the uniformity of the distribution of nano-attapulgite
Similarly, CN101235198A discloses a method for preparing nylon 6 / attapulgite nanocomposites in situ by reactive extrusion, wherein the in-situ polymerization method in which nano attapulgite and polymer reaction raw materials are added simultaneously, and twin-screw extrusion The shearing effect of the extruder screw helps the dispersion of the nano-attapulgite material, but also cannot ensure the uniformity of the distribution of the nano-material, and does not significantly enhance the mechanical properties of the nylon material.

Method used

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  • Nylon modified material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 63 parts of nylon, 10 parts of nanomaterial dispersion modifier ethylene-propylene copolymer, 10 parts of styrene butyl acrylate binary graft modified ethylene-propylene rubber, 12 parts of nano attapulgite, and 5 parts of nano-apatite whiskers , 0.1 part of antioxidant BHT, and 5 parts of processing aid stearic acid, added to a high-speed mixing mixer, stirred and mixed until uniform; melted, kneaded, extruded, cooled, dried, cut through a twin-screw extruder grain.

Embodiment 2

[0030] Using the preparation process of Example 1, the parts by weight of each component are: 69 parts of nylon, 10 parts of nanomaterial dispersion modifier alpha olefin oligomer, 8 parts of styrene butyl acrylate binary graft-modified ethylene propylene rubber parts, 12 parts of nano-attapulgite, 4 parts of nano-apatite whiskers, 10,102 parts of antioxidant, and 0.1 part of processing aid white mineral oil.

Embodiment 3

[0032]Using the preparation process of Example 1, the parts by weight of each component are: 73 parts of nylon, 7 parts of nanomaterial dispersion modifier ethylene-propylene copolymer, 6 parts of styrene butyl acrylate binary graft modified ethylene-propylene rubber , 8 parts of nano-attapulgite, 2 parts of nano-apatite whiskers, 1680.1 parts of antioxidant, 5 parts of processing aid silicone oil.

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Abstract

The invention provides a nylon modified material product and a preparation method thereof. The nylon material comprises nylon, nano material disperse modifier, styrene / butyl acrylate binary grafting modified ethylene-propylene rubber, nano attapulgite, 2-5 parts of nano apatite whisker, 0.1-2 parts of antioxidant and 0.1-5 parts of processing assistant. The nylon modified material provided by the invention can prevent the aggregation of the nano material, and has favorable mechanical properties.

Description

technical field [0001] The invention relates to a nylon modified material, in particular to a nylon modified material with excellent mechanical properties and a preparation method thereof. Background technique [0002] Nylon is an engineering plastic with a long history and a wide range of uses. It has good physical and mechanical properties, including excellent mechanical properties, heat resistance, wear resistance, chemical resistance and self-lubrication, and it is easy to process. In the past ten years, the average annual growth rate of nylon resin for engineering plastics is about 8%, and it is widely used in automobile, electrical and electronic, packaging, machinery, construction and other industries, especially the Chinese market. Great room for development. [0003] In order to improve the material properties and overcome the shortcomings of nylon materials, glass fiber or other fillers are generally used in the industry to be filled and reinforced to improve its ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/02C08L77/06C08L51/06C08K13/04C08K7/08C08K3/32C08K3/34B29C47/92B29C48/92
CPCB29C47/0011B29C47/92B29C48/04
Inventor 王鹏叶丹滢石鑫袁绍彦刘奇祥
Owner KINGFA SCI & TECH CO LTD
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